3D Subsurface Characterization of Banded Iron Formation Mineralization using Large-Scale Gravity Data: A Case Study in Parts of Bharatpur,Dausa and Karauli Districts of Rajasthan,India

Our study interprets large-scale gravity data to delineate concealed banded iron formation (BIF) iron mineralization in India's Rajasthan province. The study area belongs to the Bharatpur, Dausa, and Karauli districts of Rajasthan. We measured 1462 gravity readings to understand the rock types, depth and geometry of the different rock formations in the proposed study area. We also collected representative lithologies from more than 100 locations in the study area and calculated their density values. The measured gravity datasets are investigated via qualitative (e.g., Bouguer anomaly, first derivative and second derivative) and quantitative (radially averaged power spectrum, 3D Euler deconvolution, and 3D inversion) approach. The qualitative methods suggest a general NE–SW orientation of the BIFs, controlled by the general trend of the study area's structural setting. The lithological contact between the Bhilwara and Vindhyan Supergroups is demarcated by a NE–SW trending steep gravity gradient zone. In this area, representative lithologies yield high densities (about 3.746 gm/cc), and the samples identified as BIF represent exploration targets for iron ore. We have also developed our own in-house 3D gravity inversion code in this study. A model space inversion algorithm is converted into a data space using the identity relationship. It makes inversion algorithm very user-friendly on conventional desktop computers. The outcomes from the 3D inversion suggest that the concealed iron ore thickens to the west. This interpretation is also in good correlation with Euler 3D deconvolution of the gravity data.

     

Tissemouminites: A new group of primitive achondrites spanning the transition between acapulcoites and winonaites

The Northwest Africa (NWA) 090 meteorite, initially classified as an acapulcoite, presents petrological, chemical, and isotopic characteristics comparable to a group of seven primitive winonaites: Dhofar 1222, NWA 725, NWA 1052, NWA 1054, NWA 1058, NWA 1463, and NWA 8614. Five of these samples were previously classified as acapulcoites or ungrouped achondrites before being reclassified as winonaites based on their oxygen isotopic compositions. These misclassifications are indicative of the particular compositional nature of these primitive achondrites. All contain relict chondrules and a lower closure temperature of metamorphism of 820 ± 20 °C compared to other typical winonaites, as well as mineral elemental compositions similar to those of acapulcoites. The oxygen isotopic signature of these samples, δ¹⁷O of 1.18 ± 0.17‰, δ¹⁸O of 3.18 ± 0.30‰, and Δ¹⁷O of −0.47 ± 0.02, is in fact resolvable from both acapulcoites and winonaites. We investigate the relationship between these eight primitive achondrites, typical winonaites, and acapulcoites, to redefine petrological, mineralogical, and geochemical criteria of primitive achondrite classification. Distinguishing between winonaites, acapulcoites, and this group of eight primitive achondrites can be unambiguously done using a combination of several mineralogical and chemical criteria. A combination of olivine fayalite content and FeO/MnO ratio, as well as plagioclase potassium content allow us to separate these three groups without the absolute necessity of oxygen isotope analyses. NWA 090 as well as the other seven primitive achondrites, although related to winonaites, are most likely derived from a parent body distinct from winonaites and acapulcoites–lodranites, and define a new group of primitive achondrites that can be referred to as tissemouminites.     

Implication of the Middle Jurassic pholadomyoids of Kachchh in the palaeobiogeography of the Middle East and South Asia: A review

The Kachchh basin is known world over for its rich occurrence of the Middle to Late Jurassic mollusks. The Middle Jurassic sediments in Kachchh range in age from Bajocian (possibly Aalenian) to Callovian. Amongst the Middle Jurassic benthic communities of Kachchh, the pholadomyoid bivalves are one of the dominant groups in both diversity and number. These are represented by 13 genera and 30 constituent species. Distribution of these bivalves was much affected by the evolutionary history of the basin which has been created due to inundation by Tethys sea owing to the opening of Arabian sea sometime in Middle Jurassic. By and large these fauna are typical of the southern Hemisphere and belonged to east African biochore of the Tethyan realm or to the so called Ethiopian faunal province. Analyzing the (palaeo-) autecological behavior of the studied pholadomyoid bivalves and their distribution pattern, an attempt has been made to ascertain the usefulness of these pholadomyoids in evaluating the Middle Jurassic paleobiogeography.     

Evaluation of hydrogeochemical characteristics and the impact of weathering in seepage water collected within the sedimentary formation

A study was conducted by collecting eight seepage water samples that drain through the sedimentary rocks, mainly sandstone and shale, to evaluate the hydrogeochemical characteristics. The collected samples were analyzed for physico-chemical parameters using standard procedures. Three water types were identified in the Piper plot and the hydrogeochemical evolution starts from a Ca–Cl facies (type 1) via mixed Ca–Mg–Cl and Ca–Na–HCO₃ facies (type 2) to Na–Cl facies (type 3). Increasing trend of electrical conductivity (EC) values were observed from type 1 water to type 3 water. Lower ionic concentrations with an average EC value of 35.7 µs/cm in Ca–Cl facies indicate the recharge water by monsoonal rainfall, and ion exchange/weathering process is reflected in the mixing zone. Higher ionic concentration with an average EC value of 399 µs/cm is noted in Na–Cl facies, which indicates the ion exchange during water–rock interaction. Higher log pCO₂ values are also found in this facies, revealing the longer residence time of seepage water in the rock matrix, which release more ions into the water. The relative mobility of elements during weathering suggest that the order of mobility in both sandstone and shale is Na > Ca > Mg > K. It was observed that the hydrogeochemistry of seepage water is mainly controlled by the bedrock geology.     

Prioritization of subwatersheds based on quantitative morphometric analysis in lower Bhavani basin,Tamil Nadu,India using DEM and GIS techniques

Watershed prioritization is one of the most important processes in natural resource management system especially in areas of sustainable watershed development and planning. Morphometric characteristics are the viable entity to understand the hydrological behavior of the subwatershed. For prioritization of subwatershed, morphometric analysis was utilized by using the linear, areal, and relief aspects of the drainage basin. In this context, remote sensing and GIS has been proved to be an efficient tool to identify the morphological features. The Survey of India (SOI) topographical maps, satellite data IRS-LISS III, and Cartosat DEM data were utilized to understand the drainage pattern and also for prioritization of subwatershed areas. The prioritization of subwatershed has been attempted using novel and quantitative approaches based on compound parameter ranking for soil erosion. Lower compound factors were chosen as the most feasible for soil erosion. Based on the observation, eight subwatersheds with a higher degree of the slope were severely prone to soil erosion and remaining 21 subwatersheds occur in low-lying areas that can be developed as sustainable watersheds. The identified subwatershed requires immediate soil remediation and water conservation measures for efficient watershed planning and management. The proposed study might be helpful for resource planners, government agencies, private sectors, and other stake holders to take up soil conservation measures and fixation of water-harvesting structures for better decision making.