The Kinetics of the Interaction Between Iron(III)-Ethylenediaminetetraacetate and Peroxynitrite

The kinetics of the formation of the purple-colored species between Fe^III-EDTA and peroxynitrite were studied as a function of pH (10.4–12.3) at 22°C in aqueous solutions using a stopped-flow technique. A purple-colored species was immediately formed upon mixing, which had an absorbance maximum at 520 nm. The increase in absorbance with time could be fit empirically by a power function with two parameters a and b. The power equation determined was absorbance = a*t ^b , where a increased linearly with pH and the concentration of peroxynitrite, while b almost remained constant with a value of ~0.25. The molar extinction coefficient ε_520 nm for the colored species was determined as 13 M⁻¹cm⁻¹, which is much lower than ε_520 nm = 520 M⁻¹ cm⁻¹ for the [Fe^III(EDTA)O₂]³⁻, a purple species observed in the Fe^III–EDTA–H₂O₂ system. The results of kinetics and spectral measurements of the present study are briefly discussed and compared with those of the reaction between Fe(III)-EDTA and hydrogen peroxide.     

Torsional wave under initial stress

Summary In this paper, the frequency equation for phase velocity of torsional wave in a rod of circular cross section under initial tension has been obtained. The graphs are plotted to compare the velocity with that in the absence of initial tension. Some analytical informations have been obtained for instability of the body under initial compression.     

Quantifying sediment transport across an undisturbed prairie landscape using cesium-137 and high resolution topography

Soil erosion is a global environmental problem, and anthropogenic fallout radionuclides offer a promising tool for describing and quantifying soil redistribution on decadal time scales. To date, applications of radioactive fallout to trace upland sediment transport have been developed primarily on lands disturbed by agriculture, grazing, and logging. Here we use ¹³⁷Cs to characterize and quantify soil erosion at the Konza Prairie Long-Term Ecological Research (LTER) site, an undisturbed grassland in northeastern Kansas. We report on the small scale (< 10 m) and landscape scale (10 to 1000 m) distribution of fallout ¹³⁷Cs, and show significant variability in the concentrations and amounts of ¹³⁷Cs in soils at our site. ¹³⁷Cs soil concentrations and amounts typically vary by 10% to 30% on small scales, which most likely represents the spatial heterogeneity of the depositional processes. Landscape scale variability of soil ¹³⁷Cs was significantly higher than small scale variability. Most notably, soils collected on convex (divergent) landforms had ¹³⁷Cs inventories of 2500 to 3000 Bq m^− 2, which is consistent with the expected atmospheric inputs to the study area during the 1950s and 1960s. Concave landforms, however, had statistically lower inventories of 1800 to 2300 Bq m^− 2. The distribution of ¹³⁷Cs on this undisturbed landscape contrasts significantly with distributions observed across disturbed sites, which generally have accumulations of radioactive fallout in valley bottoms. Because the upslope contributing area at each sampling point had a significant negative correlation with the soil inventory of ¹³⁷Cs, we suggest that overland flow in convergent areas dominates soil erosion at Konza on time scales of decades. Very few points on our landscape had ¹³⁷Cs inventories significantly above that which would be predicted from direct deposition of ¹³⁷Cs on the soil surface; we conclude therefore that there is little net sediment storage on this undisturbed landscape.     

Treatment of arsenic rich waters by the HDS process

Arsenic contaminated waters are not uncommon; indeed from naturally occurring contaminated waters through to those that are a direct consequence of human activities such as mining, all are affecting the quality of water resources worldwide. The ever increasing demands on natural water resources mean that the effective control of this toxic contaminant is paramount and this is reflected in the ever increasing global legislation.There are currently three mechanisms by which arsenic is commercially treated in effluents. These are physical separation processes such as reverse osmosis, precipitation/adsorption processes, some of which are bacterially assisted, and a whole variety of ion exchange processes, again with some bacterial enhancement. The choice of treatment is not only driven by cost but by the chemistry of the water and the water quality standard to be met.In this study a very high arsenic enriched groundwater, containing in excess of 25,000 µg/L arsenic, was treated by a typical treatment method through a continuously operated pilot plant. In the treatment, iron III salts were added to the influent in order to form precipitates with the arsenic and to form an adsorptive surface that would assist with treatment of the enriched water. This addition of iron III salts for the removal of arsenic is common practice in the water treatment industry as the resulting iron III arsenates are highly stable.However, results from the pilot plant show that the process was further enhanced by the addition of small amounts of hydrogen peroxide. Hydrogen peroxide is a powerful oxidising reagent and assists in ensuring the complete conversion of any arsenic III to arsenic V that was then effectively removed in the pilot plant. After treatment residual arsenic levels of 10 µg/L were obtained compared to 68 µg/L without oxidation reagent addition.     

Scour Downstream of Grade Control Structures under the Influence of Upward Seepage

The installation of free falling jet grade control structures has become a popular choice for river bed stabilization. However, the formation and development of scour downstream of the structure may lead to failure of the structure itself. The current approaches to scour depth prediction are generally based on studies conducted with the absence of upward seepage. In the present study, the effects of upward seepage on the scour depth were investigated. A total of 78 tests without and with the application of upward seepage were carried out using three different sediment sizes, three different tailwater depths, four different flow discharges, and four different upward seepage flow discharge rates. In some tests, the three-dimensional components of the flow velocity within the scour hole were measured for both the cases with and without upward seepage. The scour depth measured for the no-seepage results compared well with the most accurate relationship found in the literature. It was found that generally the upward seepage reduced the downward velocity components near the bed, which led to a decrease in the maximum scour depth. A maximum scour depth reduction of 49% was found for a minimum tailwater depth, small sediment size, and high flow discharge. A decay of the downward velocity vector within the jet impingement was found due to the upward seepage flow velocity. The well known equation of D’Agostino and Ferro was modified to account for the effect of upward seepage, which satisfactorily predicted the experimental scour depth, with a reasonable average error of 10.7%.     

Transverse canyon incision and sedimentary basin excavation driven by drainage integration,Aravaipa Creek,AZ, USA

Drainage reorganization events have the potential to drive incision and erosion at high rates normally attributed to tectonic or climatic forcing. It can be difficult, however, to isolate the signal of transient events driven by drainage integration from longer term tectonic or climatic forcing. We exploit an ideal field setting in Aravaipa Creek Basin of southeastern Arizona, USA, to isolate just such a signal. Aravaipa Creek Basin underwent a period of transient incision that formed Aravaipa Canyon, evacuating a significant volume of sedimentary basin fill and Tertiary bedrock from the previously internally drained basin. We use digital terrain analyses to reconstruct the pre-incision landscapes of both Aravaipa Creek Basin and the adjacent Lower San Pedro Basin, which we use to quantify the magnitude of incision and erosion since the drainage basins integrated. Terrestrial cosmogenic nuclide burial dates from ¹⁰Be and ²⁶Al concentrations in latest stage basin fill in Aravaipa Creek enable us to calculate long-term incision and erosion rates from 3 Myr to the present. A ¹⁰Be concentration–depth profile from the Lower San Pedro Basin confirms that the San Pedro River incised into its high stand deposits prior to 350 000–400 000 years ago. Combining our landscape reconstructions with these age constraints, we determine that the transient rates of incision that created Aravaipa Canyon were 150 m/Myr or more, but that the background rate of erosion since integration is an order of magnitude lower, between 10 and 20 m/Myr. These results support our growing understanding that tectonic and climatic forcings need not apply for all episodes of rapid, transient incision and erosion during landscape evolution. © 2018 John Wiley & Sons, Ltd.     

Seismic assessment in southern Baromura hill,northeast India,considering geophysical aspects

This paper aims to assess the geophysical signatures like morphology and structure of a fault line, which is situated in a part of southern Baromura hill of Tripura, northeast India. In this work manual observations and technical applications were adopted for understanding the morphological and structural characters of the fault line. As tectonic mapping is one of the main objectives of this study, the remote sensing technique was used to prepare a tectonic map of the study area. Geothermal range of the area was measured by unsupervised classification of Landsat TM thermal infrared band (band 6). The classified thermal band was overlaid by another classified shortwave infrared band (band 7 of Landsat TM), which explains the structural evidences of the study area. In addition, an automated digital elevation model (DEM) was prepared to assess the morphological characters of the study area particularly near the confluence of R. Maharani and R. Gumti. To analyse the structural condition of the faulted zone, resistivity characters of the rocks were measured by “vertical electrical sounding” (VES) method. The electrical resistivity character of this area strongly supports that a displacement occurred in this place. Finally an attempt was made to explain the character of faulting on the basis of morphological signatures and structural evidences for future disaster management planning.