Measurements of winds on Mars with Hubble Space Telescope images in 2003 opposition

The winds of Mars at the water cloud level are measured by tracking cloud features in sequential high-resolution Hubble Space Telescope UV images for 5 days during the perihelion season in 2003. Global circulation model (GCM) predictions are in general agreement with the observations for the zonal wind component, but reveal significant differences for the meridional component.     

Dissolved metals and associated constituents in abandoned coal-mine discharges,Pennsylvania, USA. Part 1: Constituent quantities and correlations

Complete hydrochemical data are rarely reported for coal-mine discharges (CMD). This report summarizes major and trace-element concentrations and loadings for CMD at 140 abandoned mines in the Anthracite and Bituminous Coalfields of Pennsylvania. Clean-sampling and low-level analytical methods were used in 1999 to collect data that could be useful to determine potential environmental effects, remediation strategies, and quantities of valuable constituents. A subset of 10 sites was resampled in 2003 to analyze both the CMD and associated ochreous precipitates; the hydrochemical data were similar in 2003 and 1999. In 1999, the flow at the 140 CMD sites ranged from 0.028 to 2210 L s⁻¹, with a median of 18.4 L s⁻¹. The pH ranged from 2.7 to 7.3; concentrations (range in mg/L) of dissolved (0.45-μm pore-size filter) SO₄ (34–2000), Fe (0.046–512), Mn (0.019–74), and Al (0.007–108) varied widely. Predominant metalloid elements were Si (2.7–31.3 mg L⁻¹), B (<1–260 μg L⁻¹), Ge (<0.01–0.57 μg L⁻¹), and As (<0.03–64 μg L⁻¹). The most abundant trace metals, in order of median concentrations (range in μg/L), were Zn (0.6–10,000), Ni (2.6–3200), Co (0.27–3100), Ti (0.65–28), Cu (0.4–190), Cr (<0.5–72), Pb (<0.05–11) and Cd (<0.01–16). Gold was detected at concentrations greater than 0.0005 μg L⁻¹ in 97% of the samples, with a maximum of 0.0175 μg L⁻¹. No samples had detectable concentrations of Hg, Os or Pt, and less than half of the samples had detectable Pd, Ag, Ru, Ta, Nb, Re or Sn. Predominant rare-earth elements, in order of median concentrations (range in μg/L), were Y (0.11–530), Ce (0.01–370), Sc (1.0–36), Nd (0.006–260), La (0.005–140), Gd (0.005–110), Dy (0.002–99) and Sm (<0.005–79). Although dissolved Fe was not correlated with pH, concentrations of Al, Mn, most trace metals, and rare earths were negatively correlated with pH, consistent with solubility or sorption controls. In contrast, As was positively correlated with pH.     

Oxygen and sulfur isotope systematics of sulfate produced by bacterial and abiotic oxidation of pyrite

To better understand reaction pathways of pyrite oxidation and biogeochemical controls on δ¹⁸O and δ³⁴S values of the generated sulfate in acid mine drainage (AMD) and other natural environments, we conducted a series of pyrite oxidation experiments in the laboratory. Our biological and abiotic experiments were conducted under aerobic conditions by using O₂ as an oxidizing agent and under anaerobic conditions by using dissolved Fe(III)_aq as an oxidant with varying δ¹⁸O_H2O values in the presence and absence of Acidithiobacillus ferrooxidans. In addition, aerobic biological experiments were designed as short- and long-term experiments where the final pH was controlled at ∼2.7 and 2.2, respectively. Due to the slower kinetics of abiotic sulfide oxidation, the aerobic abiotic experiments were only conducted as long term with a final pH of ∼2.7. The δ³⁴S_SO4 values from both the biological and abiotic anaerobic experiments indicated a small but significant sulfur isotope fractionation (∼−0.7‰) in contrast to no significant fractionation observed from any of the aerobic experiments. Relative percentages of the incorporation of water-derived oxygen and dissolved oxygen (O₂) to sulfate were estimated, in addition to the oxygen isotope fractionation between sulfate and water, and dissolved oxygen. As expected, during the biological and abiotic anaerobic experiments all of the sulfate oxygen was derived from water. The percentage incorporation of water-derived oxygen into sulfate during the oxidation experiments by O₂ varied with longer incubation and lower pH, but not due to the presence or absence of bacteria. These percentages were estimated as 85%, 92% and 87% from the short-term biological, long-term biological and abiotic control experiments, respectively. An oxygen isotope fractionation effect between sulfate and water (ε¹⁸O_SO4-H2O) of ∼3.5‰ was determined for the anaerobic (biological and abiotic) experiments. This measured value was then used to estimate the oxygen isotope fractionation effects between sulfate and dissolved oxygen in the aerobic experiments which were −10.0‰, −10.8‰, and −9.8‰ for the short-term biological, long-term biological and abiotic control experiments, respectively. Based on the similarity between δ¹⁸O_SO4 values in the biological and abiotic experiments, it is suggested that δ¹⁸O_SO4 values cannot be used to distinguish biological and abiotic mechanisms of pyrite oxidation. The results presented here suggest that Fe(III)_aq is the primary oxidant for pyrite at pH < 3, even in the presence of dissolved oxygen, and that the main oxygen source of sulfate is water-oxygen under both aerobic and anaerobic conditions.     

Bank conditions and erosion along selected reservoirs

This analysis was done as the preliminary step in an ongoing study of reservoir bank erosion processes that are active in the northern U.S. The objectives of this analysis were to observe and document bank characteristics, conditions, and changes along reservoirs with eroding banks, to estimate the amounts of historical bank recession and to discuss its possible causes. Aerial photographs were used to observe the historical bank changes and estimate bank recession. Site reconnaissance, discussions with on-site personnel, and published reports were used to evaluate possible relationships between the local erosion and bank conditions. As part of this analysis linear regressions were done to determine if the estimated recession rates correlate with selected bank and climatic conditions and with physical characteristics of the reservoirs. The regression results, however, were generally not useful because they suggested relationships that are contrary to field observations and published results. Dominant bank erosion processes were wind-wave erosion, capillary wave erosion during high-water periods, groundwater-induced sliding, freeze-thaw processes, rain splash and rainwash, and boat waves. However, because of the complexity of the interrelationships of these and many other bank erosion processes and the variability of the processes at and between sites, it would be necessary to make site-specific measurements and observations year-round to evaluate the processes that are active along a particular bank.     

A Reappraisal of Rb, Y, Zr, Pb and Th Values in Geochemical Reference Material BHVO-1

The geochemical reference material BHVO-1 was analysed by a variety of techniques over a six year period. These techniques included inductively coupled plasma-mass spectrometry and atomic emission spectroscopy (ICP-MS and ICP-AES, respectively), laser ablation ICP-MS and spark source mass spectroscopy. Inconsistencies between the published consensus values reported by Gladney and Roelandts (1988, Geostandards Newsletter) and the results of our study are noted for Rb, Y, Zr, Pb and Th. The values reported here for Rb, Y, Zr and Pb are generally lower, while Th is higher than the consensus value. This is not an analytical artefact unique to the University of Notre Dame ICP-MS facility, as most of the BHVO-1 analyses reported over the last ten to twenty years are in agreement with our results. We propose new consensus values for each of these elements as follows: Rb = 9.3 ± 0.2 μg g-1 (compared to 11 ± 2 μg g-1), Y = 24.4 ± 1.3 μg g-1 (compared to 27.6 ± 1.7 μg g-1), Zr = 172 ± 10 μg g-1 (compared to 179 ± 21 μg g-1), Pb = 2.2 ± 0.2 μg g-1 (compared to 2.6 ± 0.9 μg g-1) and Th = 1.22 ± 0.02 μg g-1 (compared to 1.08 ± 0.15 μg g-1).     

Spatial and Temporal Patterns Associated with Permitted Tree Removal in Austin,Texas, 2002–2011

A wide-ranging set of physical, urban, demographic, socioeconomic, and policy characteristics determines the spatial distribution of urban forests. Information on the characteristics surrounding tree removals on both public and private properties has received less attention in the literature. The purpose of this research was to analyze the spatiotemporal trends and geographic patterns of tree removals in Austin, Texas, between 2002 and 2011 in an effort to understand how site-specific characteristics influence urban tree removal and affect the overall distribution of Austin's urban forest. We examined permitted tree removals using a geographic information system (GIS) as well as spatial and statistical analyses. Specifically, we evaluated the degree to which variables related to various physical, urban, and socioeconomic conditions predicted tree removals. The results indicate that permitted tree removals and their associated characteristics in Austin have varied over the ten-year study period. Permitted tree removals increased over the study period and took place in the urban core and along the urban periphery. Permitted tree removals were more likely to be undertaken by college graduates and owner-occupants and to occur in more densely populated areas, closer to major streets, and on properties with older structures. The results of this research provide urban forest professionals with information on the location and intensity of permitted tree removals and the significant characteristics driving urban tree loss.     

Connection of the stratospheric QBO with global atmospheric general circulation and tropical SST. Part II: interdecadal variations

The interdecadal variation of the association of the stratospheric quasi-biennial oscillation (QBO) with tropical sea surface temperature (SST) anomalies (SSTA) and with the general circulation in the troposphere and lower stratosphere is examined using the ERA40 and NCEP/NCAR reanalyses, as well as other observation-based analyses. It is found that the relationship between the QBO and tropical SSTA changed once around 1978–1980, and again in 1993–1995. During 1966–1974, negative correlation between the QBO and NINO3.4 indices reached its maximum when the NINO3.4 index lagged the QBO by less than 6?months. Correspondingly, the positive correlations were observed when the NINO3.4 index led the QBO by about 11–13?months or lagged by about 12–18?months. However, maximum negative correlations were shifted from the NINO3.4 index lagging the QBO by about 0–6?months during 1966–1974 to about 3–12?months during 1985–1992. During 1975–1979, both the negative and positive correlations were relatively small and the QBO and ENSO were practically unrelated to each other. The phase-based QBO life cycle composites also confirm that, on average, there are two phase (6–7?months) delay in the evolution of the QBO-associated anomalous Walker circulation, tropical SST, atmospheric stability, and troposphere and lower stratosphere temperature anomalies during 1980–1994 in comparison with those in 1957–1978. The interdecadal variation of the association between the QBO and the troposphere variability may be largely due to the characteristic change of El Ni?o-Southern Oscillation. The irregularity of the QBO may play a secondary role in the interdecadal variation of the association.     

Hydraulic Effects of Shales in Fluvial-Deltaic Deposits: Ground-Penetrating Radar, Outcrop Observations, Geostatistics, and Three-Dimensional Flow Modeling for the Ferron Sandstone, Utah

Ground-penetrating radar (GPR) surveys, outcrop measurements, and cores provide a high-resolution 3D geologic model to investigate the hydraulic effects of shales in marine-influenced lower delta-plain distributary channel deposits within the Cretaceous-age Ferron Sandstone at Corbula Gulch in central Utah, USA. Shale statistics are computed from outcrop observations. Although slight anisotropy was observed in mean length and variogram ranges parallel and perpendicular to pale of low , the anisotropy is not statistically significant and the estimated mean length is 5.4 m. Truncated Gaussian simulation was used to create maps of shales that are placed on variably dipping stratigraphic surfaces interpreted from high-resolution 3D GPR surveys, outcrop interpretations, and boreholes. Sandstone permeability is estimated from radar responses calibrated to permeability measurements from core samples. Experimentally designed flow simulations examine the effects of variogram range, shale coverage fraction, and trends in shale coverage on predicted upscaled permeability, breakthrough time, and sweep efficiency. Approximately 1500 flow simulations examine three different geologic models, flow in the 3 coordinate directions, 16 geostatistical parameter combinations, and 10 realizations for each model. ANOVA and response models computed from the flow simulations demonstrate that shales decrease sweep, recovery, and permeability, especially in the vertical direction. The effect on horizontal flow is smaller. Flow predictions for ideal tracer displacements at Corbula Gulch are sensitive to shale-coverage fraction, but are relatively insensitive to twofold variations in variogram range or to vertical trends in shale coverage. Although the hydraulic effects of shale are statistically significant, the changes in flow responses rarely exceed 20%. As a result, it may be reasonable to use simple models when incorporating analogous shales into models of reservoirs or aquifers.     

Humpback whale song or humpback whale sonar? A reply to Au et al

Au et al.'s arguments against the hypothesis that humpback whale songs function as long-range sonar are based on questionable assumptions rather than on empirical data. Like other echolocating mammals (e.g., bats), singing humpback whales: 1) localize targets in the absence of visual information; 2) possess a highly innervated peripheral auditory system; and 3) modulate the temporal and spectral features of their sounds based on environmental conditions. The sonar equation is inadequate for determining whether humpback whale songs generate detectable echoes from other whales because it does not account for temporal variables that can strongly affect the detectability of echoes. In particular, the sonar equation ignores the fact that much of the noise encountered by singing humpback whales is spectrally and temporally predictable, and that audition in mammals is a dynamic and plastic process. Experiments are needed to test the hypothesis that singing humpback whales listen for and respond to echoes generated by their songs