Structure of the rift basins in the central Gulf of California: Kinematic implications for oblique rifting

We use structural and seismostratigraphic interpretation of multichannel seismic reflection data to understand the structure and kinematic history of the central Gulf of California. Our analysis reveals that oblique strain in the central Gulf formed two tectono–sedimentary domains during distinct deformation stages. The eastern domain, offshore Sonora, is bounded by the East and West Pedro Nolasco faults that may constitute the southernmost segments of the Tiburón Fault System. Within this domain, the dip-slip Yaqui Fault controlled deposition of 3.9 km of sediments in the half-graben Yaqui Basin. The western domain, offshore Baja California, is bounded by the Guaymas Transform Fault, which controlled the accumulation of 1.45 km of sediments within a half-graben that formed the early Guaymas Basin. The tectono–sedimentary activity offshore Sonoran likely ranges from Late Miocene–Pliocene to Late Pliocene time, while activity in the Guaymas Basin commenced in Late Pliocene time. Extinction of the main faults offshore Sonora was nearly coeval to the initiation of the Guaymas Transform Fault. Our results suggest that oblique strain has been accommodated by strain partition since the onset of rifting in the central Gulf. The Guaymas Basin is now a nascent spreading center, but prior to this, it evolved as a half-graben controlled by the Guaymas Transform Fault; such drastic transition is not constrained, but likely occurred during the Pleistocene time and must be localized < 30 km north of the axial troughs. The faults within the central Gulf transpose the Miocene N–S oriented grabens of Basin and Range style preserved onshore in the conjugate rifted margins.     

Altimetry with GNSS-R interferometry: first proof of concept experiment

The Global Navigation Satellite System Reflectometry (GNSS-R) concept was conceived as a means to densify radar altimeter measurements of the sea surface. Until now, the GNSS-R concept relied on open access to GNSS transmitted codes. Recently, it has been proposed that the ranging capability of the technique for ocean altimetric applications can be improved by using all the signals transmitted in the bandwidth allocated to GNSS, which includes open access as well as encrypted signals. The main objective of this study is to provide experimental proof of this enhancement through a 2-day experiment on the Zeeland Bridge (The Netherlands). In the experiment, we used a custom built GNSS-R system, composed of high gain GPS antennas, calibration subsystem, and an FPGA-based signal processor which implemented the new concepts, an X-band radar altimeter and a local geodetic network. The results obtained indicate that the new approach produces a significant improvement in GNSS-R altimetric performance.     

Assessment of the topsoil heavy metals pollution in the Sarno River basin,south Italy

The Sarno River basin area is one of the most polluted in Europe and it is due to the waste products of the tomato industry, the leather tanneries and the pharmaceutical industry. This area also has been densely populated and urbanized since the Middle Bronze Age, as testified by the presence of numerous archeological sites, including the ancient Pompeii town, and environmental degradation that characterizes the area is absolutely unacceptable. This paper represents a detailed study to assess the potentially harmful element content of topsoils. In total, 283 soil samples were collected and analyzed, after an aqua regia extraction, by a combination of inductively coupled plasma atomic emission and inductively coupled plasma mass spectrometry for 53 elements. Univariate and multivariate analyses were carried out to show the single-element geochemical distribution and the distribution of factor scores of the elemental associations resulting from R-mode factor analysis. Maps showing elements and the association factor score distributions have been obtained using GeoDAS and ArcGIS software. The assessment of the soil contamination was also carried out using the contamination factor and degree of contamination. The results obtained indicate that soil pollution has different anthropogenic sources. Specifically, Cr pollution derives from tanneries discharging wastewaters in the main water bodies of the basin while Cu contamination seems to depend on widespread agricultural practices. Tin, Pb, Hg, Zn, Cd, Sb anomalies are found mainly in urban and industrial areas, sometimes close to roads with high traffic levels while there is a substantial coincidence with background values for other elements (Co, Ni, Se, Tl and V).     

Winter and summer characterization of biogenic enantiomeric monoterpenes and anthropogenic BTEX compounds at a Mediterranean Stone Pine forest site

Measurements of biogenic gases including enantiomeric monoterpenes and isoprene, and anthropogenic gases such as benzene, toluene, ethylbenzene, ortho-, meta- and para- xylene (BTEX) compounds were made by GC-MS in November and December 2008 within a stone pine (Pinus pinea L) forest located on the Southwest coast of Spain (37.10°N, 6.70°W). Mixing ratios of the biogenic species were found to be low (mean circa 10 pptv) consistent with previously observed low wintertime regional forest emission rates. In contrast, anthropogenic species were significantly higher (mean 10–156 pptv), the dominant emissions originating from the city of Huelva and associated petrochemical activities, located 25 km north west of the measurement site. In wintertime the monoterpene (?)-α-pinene was found to be in slight enantiomeric excess over (+)-α-pinene at night but by day the measured ratio was closer to one i.e. racemic. Samples taken the following summer in the same location showed much higher monoterpene mixing ratios and revealed a strong enantiomeric excess of (?)-α-pinene. This indicates a strong seasonal variance in the enantiomeric emission ratio which is not manifested in the day/night temperature cycles in wintertime. Mixing ratios of the xylene isomers (meta- and para-) and ethylbenzene, which are all well resolved on the beta-cyclodextrin column, were exploited to estimate average OH radical exposures to VOCs from the Huelva industrial area. These were compared to empirical estimates of OH based on JNO₂ measured at the site. The deficiencies of each estimation method are discussed.     

Jobs and the Single Parent: An Analysis of Accessibility to Employment in Toronto

Abstract

In this article, we undertake an analysis of accessibility to jobs from the perspective of single-parent household members. Individuals in this demographic segment are of interest due to the fact they often face the double burden of household and employment responsibilities. A case study of the city of Toronto in Canada, an urban area that has seen an increase in absolute and relative numbers of single-parent households in recent years, is presented. Analysis is based on the application of relative accessibility deprivation indicators (RADI), which are calculated using model-based estimates of distance traveled for various population segments, as well as employment data for the city and its surroundings. The results of the analysis indicate that there are substantial differences in the levels of accessibility to jobs between members of single-parent households, in particular females, and members of other types of households.     

Clamshell excavation of a permeable reactive barrier

Nowadays, permeable reactive barriers (PRB) are one of the most widespread techniques for the remediation of contaminated aquifers. Over the past 10 years, the use of iron-based PRBs has evolved from innovative to accepted standard practice for the treatment of a variety of groundwater contaminants (ITRC in: Permeable reactive barriers: lessons learned/new directions. The Interstate Technology and Regulatory Council, Permeable Reactive Barriers Team 2005). Although, a variety of excavation methods have been developed, backhoe excavators are often used for the construction of PRBs. The aim of this study is to describe the emplacement of a full-scale PRB and the benefits deriving from the use of a crawler crane equipped with a hydraulic grab (also known as clamshell excavator) in the excavation phases. The studied PRB was designed to remediate a chlorinated hydrocarbons plume at an old industrial landfill site, in Avigliana, near the city of Torino, in Italy. The continuous reactive barrier was designed to be 120 m long, 13 m deep, and 0.6 m thick. The installation of the barrier was accomplished using a clamshell for the excavation of the trench and a guar-gum slurry to support the walls. The performance of this technique was outstanding and allowed the installation of the PRB in 7 days. The degree of precision of the excavation was very high because of the intrinsic characteristics of this excavation tool and of the use of a concrete curb to guide the hydraulic grab. Moreover, the adopted technique permitted a saving of bioslurry thus minimizing the amount of biocide required.     

Characterisation of ground motion recording stations in the Groningen gas field

The seismic hazard and risk analysis for the onshore Groningen gas field requires information about local soil properties, in particular shear-wave velocity (V_S). A fieldwork campaign was conducted at 18 surface accelerograph stations of the monitoring network. The subsurface in the region consists of unconsolidated sediments and is heterogeneous in composition and properties. A range of different methods was applied to acquire in situ V_S values to a target depth of at least 30 m. The techniques include seismic cone penetration tests (SCPT) with varying source offsets, multichannel analysis of surface waves (MASW) on Rayleigh waves with different processing approaches, microtremor array, cross-hole tomography and suspension P-S logging. The offset SCPT, cross-hole tomography and common midpoint cross-correlation (CMPcc) processing of MASW data all revealed lateral variations on length scales of several to tens of metres in this geological setting. SCPTs resulted in very detailed V_S profiles with depth, but represent point measurements in a heterogeneous environment. The MASW results represent V_S information on a larger spatial scale and smooth some of the heterogeneity encountered at the sites. The combination of MASW and SCPT proved to be a powerful and cost-effective approach in determining representative V_S profiles at the accelerograph station sites. The measured V_S profiles correspond well with the modelled profiles and they significantly enhance the ground motion model derivation. The similarity between the theoretical transfer function from the V_S profile and the observed amplification from vertical array stations is also excellent.     

Instrumental monitoring of the subsidence due to groundwater withdrawal in the city of Murcia (Spain)

This paper presents the results of investigations of the generalized subsidence occurring in and around the city of Murcia, Spain. Based on this research, this is the first integrated investigation of its type performed in Spain. The phenomenon of ground consolidation in the city of Murcia leads to the appearance of severe cracking and settlement in buildings. Subsidence is the result of two factors: on the one hand, the nature of the ground in this area, as it is made of recent deposits of clay and soft limes filled in with clay–lime backfills in the top layers. On the other hand, the increase in groundwater withdrawal during the 1992–95 drought led to a decrease in the water level of a magnitude never before recorded in the city. The risk prevention management suggested convenience of the installation of a measurement network to study and follow the phenomena of the subsidence to quantify it and to calibrate this theoretical model. This network is composed of extensometers and piezometers, the best devices to measure moderate ground movements, which is the case of Murcia. The first phase (Phase I) of this study of ground settlement in the metropolitan area of Murcia involved the installation of a network with 22 extensometers and taking the first measurement series. In a second phase (Phase II), during a period of 4 years, measurements with extensometers were performed to make the analysis and calibration of the theoretical model. Experience and data analysis showed the convenience of installation of new control points with an incremental extensometer and a piezometer in close position with the aim of precisely correlating piezometric levels with the observed subsidence. The third phase (Phase III) started in 2007, a new control technique, based on radar interferometry (InSAR), is being employed to provide information about subsidence in areas not previously monitored.     

The Magnetic Environments of Young Stellar Objects

We report on early results of submillimetre polarimetric measurements towards a sample of young stellar objects. The results allow us to infer the magnetic field structure and show a variety of configurations, providing evidence for axial, helical and pinched (i.e. ‘hourglass’) magnetic field configurations. We find that in some cases the field is curved over large scales, implying that it is influenced by the gas kinematics in the local environment, and that at these scales at least, the magnetic field plays a passive rôle in the star formation process.