Spring thermal resources for grapevine in Kőszeg (Hungary) deduced from a very long pictorial time series (1740–2009)

Since 1740 until now, the Book of Vine Branches encompasses beautiful pictorial representations of shoots and sprouts, collected every year on April 24th in the vineyards of the Hungarian town of K?szeg. A long time series (1740–2009) of sprouts phenological development coded with the BBCH scale is obtained through paintings visual inspection. Consequently, a model relating sprouts development with thermal resources accumulation is developed on the base of Wien daily air temperature series for the 1857–2009 period. Thermal resources is obtained with the Normal Heat Hours approach, a response curve method that takes into account the nonlinear response of phenological development to temperature. The model, calibrated and validated on the 1930–2009 period, shows an overestimation of thermal resources when applied to the 1857–1929, due to the more advanced phenology of that phase. Since this advance can be ascribed to genetics and management instead of more favorable thermal conditions, model outputs previous to 1930 are decreased by a constant factor. Finally, the 1740–2009 time series of grapevine spring thermal resources is obtained applying the model to the complete phenological time series. The analysis of the series highlights a first phase (1740–1780) characterized by high and stable availability of thermal resources during the 1740–1780, a second phase (1781–1820) with the lowest level of resources, a phase of intermediate availability (1821–1929) and a final present phase (1930–2009) with renewed high availability. The adopted method overcomes the lack of correlation for the post 1960 period shown by previous works.     

A New TanSat XCO_2 Global Product towards Climate Studies

The 1st Chinese carbon dioxide(CO2)monitoring satellite mission,TanSat,was launched in 2016.The 1st TanSat global map of CO2 dry-air mixing ratio(XCO2)measurements over land was released as version 1 data product with an accuracy of 2.11 ppmv(parts per million by volume).In this paper,we introduce a new(version 2)TanSat global XCO2 product that is approached by the Institute of Atmospheric Physics Carbon dioxide retrieval Algorithm for Satellite remote sensing(IAPCAS),and the European Space Agency(ESA)Climate Change Initiative plus(CCI+)TanSat XCO2 product by University of Leicester Full Physics(UoL-FP)retrieval algorithm.The correction of the measurement spectrum improves the accuracy(?0.08 ppmv)and precision(1.47 ppmv)of the new retrieval,which provides opportunity for further application in global carbon flux studies in the future.Inter-comparison between the two retrievals indicates a good agreement,with a standard deviation of 1.28 ppmv and a bias of?0.35 ppmv.     

The hydrochemical facies and anomalous fluoride content in the Serra Geral aquifer system,southern Brazil: a GIS approach with tectonic and principal component analysis

Groundwater with high fluoride content and water mixture patterns were studied in Serra Geral aquifer system (SGAS) using three aspects, principal component analysis (PCA), tectonic scenery and hydrochemical interpretation from 309 groundwater chemical data information from deep wells. A four-component model is suggested and explains 81% of total variance in the PCA. Six hydrochemical facies were identified. These facies suggest two different fluoride sources. Tectonic approach shows the relationship between defined hydrochemical facies and regional fracture control. The applied methodology reveals a minimum level to understand hydrochemical mixtures. The fluoride enrichment mechanisms into the groundwater are comprised in advance to guide the future uses of SGAS to the public supply.     

Deformation features within an active normal fault zone in carbonate rocks: The Gubbio fault (Central Apennines, Italy)

The Gubbio fault is an active normal fault defined by an important morphological scarp and normal fault focal mechanism solutions. This fault truncates the inherited Miocene Gubbio anticline and juxtaposes Mesozoic limestones in the footwall against Quaternary lacustrine deposits in the hanging wall. The offset is more than 2000 m of geological throw accumulated during a poly-phased history, as suggested by previous works, and has generated a complex zone of carbonate-rich fault-related structures. We report the results of a multidisciplinary study that integrates detailed outcrop and petrographic analysis of two well-exposed areas along the Gubbio fault zone, geochemical analysis (fluid inclusions, stable isotopes, and trace elements) of calcite-sealed fault-related structures and fault rocks, and biostratigraphic controls. Our aims are: (i) the characterization of the deformation features and their spatial–temporal relationships, and (ii) the determination of the P/T conditions and the fluid behaviour during deformation to achieve a better understanding of fluid–rock interaction in fault zones.We show that few of the observed structures can be attributed to an inherited shortening phase while the most abundant structures and fault rocks are related to extensional tectonics. The outcropping extensional patterns formed at depths less than 2.5–3 km, in a confined fluid system isolated from meteoric water, and the fault structures are the response to a small amount of cumulated displacement, 12–19% of the total geological throw.     

Observations of shocked H2 and [FeII] line profiles in orion bullet wakes

New observations of H₂ velocity profiles in the Orion bullet wakes are extremely difficult to reconcile with existing steady-state shock models. We have observed [FeII] 1.644µm velocity profiles of selected bullets and H₂ 1-0 S(1) 2.122µm velocity profiles for a series of positions along and across the corresponding bow-shock wakes. Integrated [FeII] velocity profiles of the brightest bullets are consistent with theoretical bow shock predictions. Observations of broad, singly-peaked H₂ 1-0 S(1) profiles in the most clearly resolved bullet wakes challenge our understanding of molecular shocks. It may be necessary to model the effects of instabilities and turbulence in the Orion bullet wakes in order to fit our observations.     

Distributions of dissolved vitamin B12 and Co in coastal and open-ocean environments

Distributions of dissolved vitamin B₁₂ and total dissolved Co were measured to gain an understanding of the cycling of these interdependent micronutrients in six marine settings including; an upwelling location, a semi-enclosed bay, two urban coastal systems, and two open ocean locations. Along the coast of Baja California, Mexico, concentrations of B₁₂ and dissolved Co varied from 0.2 to 11 pM and 180 to 990 pM, respectively. At a nearby upwelling station, vitamin B₁₂ and Co concentrations ranged from 0.3 to 7.0 pM and 22 to 145 pM, and concentrations did not correlate with upwelling intensity. Concentrations of B₁₂ were highest within Todos Santos Bay, a semi-enclosed bay off the coast of Baja California, Mexico, during a dinoflagellate bloom, ranging from 2 to 61 pM, while Co concentrations varied between 61 and 194 pM. In the anthropogenically impacted Long Island Sound, NY, U.S.A., B₁₂ levels were between 0.1 and 23 pM and Co concentrations varied from 60 to 1900 pM. However, anthropogenic inputs were not evident in B₁₂ levels in the San Pedro Basin, located outside Los Angeles, Ca, U.S.A., where concentrations of B₁₂ were 0.2–1.8 pM, approximating observed open ocean B₁₂ concentrations. In the Southern Ocean and North Atlantic Ocean, B₁₂ levels were 0.4–4 pM and 0.2–2 pM, respectively. Total Co concentrations in the Southern Ocean and North Atlantic tended to be low; measuring 26–59 pM and 15–80 pM, respectively. These low Co concentrations may limit B₁₂ synthesis and its availability to B₁₂-requiring phytoplankton because the total dissolved Co pool is not necessarily entirely bioavailable.     

Stratigraphic evolution from the early Albian to late Campanian of the Potiguar Basin,Northeast Brazil: An approach in seismic scale

Five 3rd-order depositional sequences are interpreted from the early Albian to late Campanian interval in the Potiguar Basin. An integrated analysis of seismic interpretations, well logs, cores and biostratigraphic data provides a stratigraphic framework composed by stratigraphic surfaces, systems tracts and sequences. Depositional Sequence 1 and 2 are, respectively, Albian and early to mid-Cenomanian aged and are composed by the falling stage, low stand, transgressive and high stand systems tracts. Depositional Sequence 3 is late Cenomanian to mid-Turonian aged and is composed by the transgressive and high stand systems tracts. Depositional sequences 4 and 5 are, respectively, late Turonian to mid-Santonian and late Santonian to mid-Campanian aged and are composed only by transgressive and high stand systems tracts. The lack of falling stage and low stand systems tracts in depositional sequences 3, 4 and 5, as well the increasing in transgressive and highstand systems tracts thickness as depositional sequences get younger, are reflection of an overall transgressive trend of a 2nd-order sequence. The interpretation proposed in this paper correlates onshore with offshore deposits within a seismic scale (3rd-order) sequence stratigraphy framework. This approach allows a better understanding of the Açu Formation, the primary oil-bearing formation of the Potiguar Basin. The Açu Formation is part of depositional sequences 1, 2 and 3 and is characterized by lateral and vertical variations of depositional systems instead of being associated to a specific depositional system. This sequence stratigraphy analysis can be used as a low-resolution framework for future high-resolution (4th-order scale) studies.     

Antioxidant response of the seagrass Posidonia oceanica when epiphytized by the invasive macroalgae Lophocladia lallemandii

The aim was to evaluate the antioxidant defences and the occurrence of oxidative damage in Posidonia oceanica under a stress situation due to the epiphytism of the invasive macroalgae Lophocladia lallemandii. P. oceanica leaves were collected in the absence (control station) and in the presence of the epiphytic algae L. lallemandii and the antioxidant enzyme activities, markers of oxidative damage, and hydrogen peroxide production were determined. Antioxidant enzyme - catalase, glutathione peroxidase and superoxide dismutase - activities were significantly higher in Posidonia epiphytized by L. lallemandii. Malondialdehyde, protein carbonyl derivates, and glutathione levels were also higher in L. lallemandii epiphytized P. oceanica leaves compared to control samples. The production of hydrogen peroxide was also significantly increased when Posidonia was epiphytized by L. lallemandii. The invasion of P. oceanica meadows by L. lallemandii appeared to induce oxidative stress in the seagrass as evidenced by increased levels of oxidative stress markers and antioxidant defences.