Marine sediment contamination of an industrial site at Port of Bagnoli, Gulf of Naples, Southern Italy

For almost one century an important steel plant has been active at the Bagnoli industrial area (Naples, Southern Italy). The environmental survey of near shore and offshore sediments has been carried out as fundamental part of a clean up project. The characteristics of the area, supposed type of pollution, national and international protocols in force were taken into consideration in designing sampling schemes and selecting analytical parameters. For this work, sediment grain size, PAHs, PCBs, trace elements, total hydrocarbons and organic matter were considered. Factor analysis evidenced two main types of pollution in the proximity of the industrial plant, both probably attributable to the activity of the industrial site. The first one, due to Cd, Pb, Zn and Mn seems determined by localised activities at the southern part of the plant. The second one, due to Fe and Mn, appears directly linked to the whole contaminated area.     

Test of the upper mantle low velocity layer in Siberia with surface waves

The existence of the upper mantle low velocity layer (LVL) below 100 km depth in cratonic areas is tested with surface waves dispersion curves. Given the ambient noise we find that a pronounced LVL (80 km thick and 2% velocity reduction or 40 km thick and 5% velocity reduction) can be distinguished from a constant velocity model by comparison of the fundamental mode group velocities, whereas a thin LVL (less than 40 km thick) with small velocity contrast (less than 2%) cannot be resolved. The fundamental modes of Love and Rayleigh waves have similar properties and, in general, the phase velocity differences are smaller than the standard error. Phase velocity alone cannot discriminate between the models, and the group velocity is in general more sensitive to the velocity structure than the phase velocity. The higher modes at short periods could potentially determine a LVL but in reality it is difficult to obtain sufficiently accurate measurements. We invert the synthetic dispersion curves by the non-linear Hedgehog inversion method. A pronounced LVL (more than 40 km thick and with a strong velocity contrast of about 5%) is detectable by the non-linear inversion but for a thin LVL with a strong velocity contrast it is not possible to resolve both velocity and thickness. In the inversions all solutions include a LVL for models with a pronounced LVL, whereas the solution space includes models with and without a LVL for models with a zero or positive gradient velocity–depth structure.We invert also real data with travel path across the Siberian craton with the Hedgehog method. Almost all solutions include a LVL in the depth range of 80–150 km with a velocity contrast up to 2% to the surrounding intervals. Hence, the LVL appears to be a common feature of the Siberian upper mantle, although a constant velocity at the same depth range cannot be totally excluded. Despite low resolution at large depth, a pronounced asthenospheric LVL below a depth of about 225 km is a constant characteristic of the set of solutions.     

A test of the integrity of metal records in sediment cores based on the documented history of metal contamination in Lac Dufault (Québec, Canada)

There is an important volume of published information on Lac Dufault (Québec) which describes the history of metal inputs over 70 years and the changes that occurred in the lake as a result of this contamination. We used this abundant source of chronological markers to test the hypothesis that lake sediments can provide true historical records of trace metal loading from metal mining. Sediment cores were obtained from the deepest zone of the lake (19 m). The sediments were dated using ²¹⁰Pb and ¹³⁷Cs and they were analyzed for total elemental concentrations (Ca, Cd, Cu, Fe, P, Pb, S, Zn). Metal profiles in the sediment core preserved the distinct signatures of different mine exploitations documented in the lake watershed. In particular, the core recorded: the beginning of industrialization in 1926; increasing sedimentation rates associated with perturbations in the lake watershed; the maximum of sediment [Cu] and the contemporary exploitation of ore bodies rich in Cu; the maximum of sediment [Fe] and the contemporary production of pyrite by a mining operation; the low sediment [Cu] and [Zn] in the 1950s and the low contemporary production of these metals by mining operations; the maximum of sediment [Cd] and the contemporary production of Cd by a subsequent mining operation. Anomalies in the distribution of ²¹⁴Pb activities in sediments reflected the intensity of acid mine drainage (AMD). There is good evidence that the lake resisted acidification from this AMD for the last thirty years. Overall, our results support the thesis that profiles of sedimentary Cd, Cu, Zn, Pb and Fe levels reflect the past history of metal input to Lac Dufault.     

1980–1990: Ten years of geochemical investigation at Phlegrean Fields (Italy)

A systematic geochemical investigation on the thermal manifestations of the volcanic area of Phlegrean Fields started in 1980, with the aim of obtaining useful information about the changes possibly occurring at the same time of vertical ground movements, termed as “bradyseismic”, which frequently interested this area.The attention was initially given to the fumaroles and the boiling pools of Solfatara and Pisciarelli, then subsequently extended to thermal springs, dug wells, and crater lakes.Analytical data pertaining to a period preceding the last crisis of 1982–1984 were then available, as well as other data collected during the previous crisis of 1970; a comprehensive picture of the variations observed before, during and after the acceleration of vertical movement has been drawn.According to the results obtained, the intrusion of a magmatic body as the trigger of the observed ground deformation is considered unrealistic. The whole area appears now in a quiet stage, and no further perturbation is expected without previous significant tectonic activity; chemical precursors appear suitable for an early detection of changes occurring at depth, to forecast possible consequences to be expected in the surface environment.     

A low magnitude seismic sequence near Isernia (Molise,Central Italy) in January 1986

Following the increase in seismic activity which occurred near Isernia (Molise, Central Italy) in January 1986, a digital seismic network of four stations with three-component, short-period seismometers, was installed in the area by the Osservatorio Vesuviano. The temporary network had an average station spacing of about 8–10 km and, in combination with permanent local seismic stations, allowed the accurate determination of earthquake locations during an operating period of about one month. Among the 1517 detected earthquakes, 170 events were selected with standard errors on epicentre and depth not greater than respectively 0.5 and 1.5 km. The most frequent focal depths ranged between 4 and 8 km, while the epicentres distribution covered a small area NE of Isernia of about 10 km². A main rupture zone could not be clearly identified from the spatial distribution of the earthquakes, suggesting a rupture mechanism involving heterogeneous materials. The activity was characterized by low energy levels, the largest earthquake, on January 18, 1986, havingM _D =4.0. The time sequence of events and pattern of seismic energy release revealed a strong temporal clustering of events, similar to the behaviour commonly associated with seismic swarms.     

Innovative monitoring tools for the complex spatial dynamics of river chemistry: case study for the Alpine region

Chemical reactions in aqueous geochemical systems are driven by nonequilibrium conditions, and their dynamics can be deduced through the distributional analysis (identification of probability laws) of complex compositional indices. In this perspective, compositional data analysis offers the possibility to investigate the behavior of the composition as a whole instead of isolated chemical species, with the awareness that multispecies systems are characterized by the simultaneous interactions among all their parts. We addressed this problem using D???1 isometric log-ratio coordinates describing the D compositional dataset of the river chemistry of the Alpine region (D number of variables), thus working in the \({{\mathbb{R}}^{D - 1}}\) statistical sample space. The D???1 coordinates were chosen using the decreasing variance criterion so that each one could provide information about different space–time properties for the investigated geochemical system. Coordinates dominated by heterogeneity appear to be able to capture regime shifts only on a long-time period and monitor processes on a very wide scale. On the other hand, coordinates characterized by lower variability present multimodality, thus capturing the presence of alternative states in the analyzed spatial domain also for the current time. Further developments are needed to determine the ranges of conditions for which variability and other statistics can be useful indicators of regime shifts on different time–space scales in geochemical systems.     

Shaking table tests on a masonry building monitored using smart bricks: Damage detection and localization

The seismic behavior of unreinforced masonry buildings is typically characterized by premature brittle collapse mechanisms that can cause serious consequences for the protection of human lives and for the preservation of historical and cultural heritage. Structural health monitoring can be a powerful tool enabling a quick post-earthquake assessment of the structure's performance, but its applications are still scarce as a consequence of the severe limitations affecting off-the-shelf sensing technologies, in terms of local nature of the measurements, costs, as well as long-term behavior, installation, and maintenance. To overcome some of these limitations, the authors have recently proposed a new sensing technology, called “smart brick,” that is a durable clay brick doped with stainless steel microfibers, working as a smart strain sensor for masonry buildings. This paper presents the first full-scale application of smart bricks, used for detecting and localizing progressive earthquake-induced damage in an unreinforced masonry building subjected to shaking table tests. Smart bricks are employed to detect changes in load paths on masonry walls, comparing strain measurements acquired after each step of the seismic sequence with those referring to the undamaged structure. Experimental results are interpreted using a 3D finite element model built to reproduce the shaking table tests. Overall, the results demonstrate that the smart bricks can effectively reveal local permanent changes in structural conditions following a progressive damage, therefore being apt for earthquake-induced damage detection and localization.