The presence of anomalous trace element levels in present day Jamaican soils and the geochemistry of Late-Miocene or Pliocene phosphorites

High levels of Cd and Zn in Jamaican soils observed in geochemical surveys are related to the presence of phosphorites of possible Late-Miocene or Pliocene age. The trace element and REE geochemistry of the phosphorites, together with SEM studies, indicate a guano origin for the phosphorites. No specific host minerals for Cd could be identified in the fossiliferous phosphorite which is characterized by uniquely high levels of Cd, Zn, Ag, Be, U and Y. However, in the soil Cd is present in lithiophorite and a complex history of pedological development is preserved in the aluminous–goethite present in the soil. The unique guano signature is preserved in the soil despite the fact that guanos themselves have either not been observed or have been destroyed by continuing karst and soil development. The phosphorite geochemical signature can be traced in the data of a 1988 island-wide soil geochemical survey, identifying areas where the Palaeo-environment that supported bird ‘rookeries’ existed in the Late-Miocene or Pliocene.     

Waveform Shaping of Sonar Transducers for Improving the Vertical Resolution in Sub-bottom Sediments Profiling

Vertical resolution is of fundamental importance in sonar exploration and is directly related to the duration of the acoustic pulse generated by the transducer. The shorter the radiated pulse, the higher the vertical resolution. Many sub-bottom profiling sonar systems use piezoelectric transducers because they are reversible and well understood. Piezoelectric projectors are normally resonant transducers, which are intrinsically narrowband. A piezoelectric transducer is usually driven by a tone-burst. However, it is possible to use Fourier techniques to find a pre-compensated electrical driving function so that the transducer radiates a prescribed wider band acoustic waveform. This technique can be applied to synthesize zero-phase cosine-magnitude, Gaussian, and bionic pulses, with a conventional sandwich transducer. Zero-phase cosine-magnitude waveforms provide minimum length pulses (and therefore maximum resolution) within a prescribed frequency band.The aim of this paper is to illustrate the synthesis of wideband acoustic pulses using an underwater piezoelectric projector. The conventional acoustic waveform radiated when a Tonpiltz transducer is transiently excited using a “click” and allows its frequency response function to be measured. This function is used to design the electrical signal which then drives the transducer so that it radiates the shortest pulse compatible with its mechanical response. The significant resolution enhancement of the waveform shaping process is illustrated by its application to a sediment wedge model.     

Code of Practice For Ocean Mining: An International Effort to Develop a Code For Environmental Management of Marine Mining

A code of practice for ocean mining has been developed by the International Marine Minerals Society. The code provides general guiding Principles for development of marine mineral resources and delineates Operating Guidelines for application, as appropriate, at specific mining sites. In total 11 operating guidelines are provided to serve as benchmarks for industry and targets for regulatory agencies and other stakeholders. They include the following commitments: •To sustainable development, •To environmentally responsible corporate ethics, •To the development of effective community partnership, •To implementation of environmental risk management, •To the integration of environmental management into all phases of development, •To the establishment of corporate environmental performance targets, •To timely environmental improvements and upgrading, •To responsible rehabilitation of operations sites and decommissioning of facilities, and •To accurate and timely, reporting and documentation, archiving, and performance review.     

Eastern and Western Poor Cod (Trisopterus minutus capelanus) Populations in the Mediterranean Sea: Evidence from Allozyme and Minisatellite Loci

Abstract. Nine allozyme and two minisatellite loci were used to investigate potential genetic differentiation among three samples of Mediterranean poor cod, Trisopterus minutus capelanus, from the Gulf of Lion, the Tuscan Archipelago and the Aegean Sea. Both types of markers showed consistent results, with F_ST values of 0.0262 and 0.0296 (P < 0.0015, after Bonferroni correction for multiple tests) for allozymes and minisatellites, respectively. Allele frequency heterogeneity tests between pairs of samples showed a clear separation between the two western Mediterranean samples (Gulf of Lion, Tuscan Archipelago) and the eastern one (Aegean Sea). The results indicate that at least two reproductively isolated populations of poor cod occur in the Mediterranean.     

Petroleum hydrocarbons in sediments of Southampton water estuary

The sediments of Southampton Water were analysed for petroleum hydrocarbons to determine the fate of petrochemical refinery waste in the estuary. Much of the petroleum hydrocarbons appears to be removed by adsorption onto estuarine sediments close to source. Surface sediment concentrations range from 3·1mg/g dry weight near a refinery to 0·5 mg/g dry weight at locations distant from the refinery.The absence of any change with depth in total hydrocarbon concentrations from some sediment cores and the presence of distinct ‘oil’ horizons in others suggests that mixing of sediments in the area is very random. Sedimentation rates in areas where a distinct oil horizon was observed ranged from 1 to 3cm a year.     

Morphodynamics of intertidal bars on a megatidal beach, Merlimont, Northern France

The morphology, bedforms and hydrodynamics of Merlimont beach, in northern France, characterised by intertidal bars and a spring tidal range of 8.3 m, were surveyed over a 10-day experiment with variable wave conditions that included a 2-day storm with significant wave heights of up to 2.8 m. The beach exhibited two pronounced bar-trough systems located between the mean sea level and low neap tide level. Waves showed a cross-shore depth modulation, attaining maximum heights at high tide. The mean current was characterised dominantly by strong tide-induced longshore flows significantly reinforced by wind forcing during the storm, and by weaker, dominantly offshore, wave-induced flows. Vertical tidal water-level variations (tidal excursion rates) showed a bimodal distribution with a peak towards the mid-tide position and low rates near low and high water. The two bar-trough systems in the mid-tide zone remained stable in position during the experiment but showed significant local change. The absence of bar migration in spite of the relatively energetic context of this beach reflects high macro-scale bar morphological lag due to a combination of the large vertical tidal excursion rates in the mid-tide zone, the cross-shore wave structure, and the pronounced dual bar-trough system. The profile exhibited a highly variable pattern of local morphological change that showed poor correlation with wave energy levels and tidal excursion rates. Profile change reflected marked local morphodynamic feedback effects due mainly to breaks in slope associated with the bar-trough topography and with trough activity. Change was as important during low wave-energy conditions as during the storm. Strong flows in the entrenched troughs hindered cross-shore bar mobility while inducing longshore migration of medium-sized bedforms that contributed in generating short-term profile change. The large size and location of the two pronounced bars in the mid-tide zone of the beach are tentatively attributed respectively to the relatively high wave-energy levels affecting Merlimont beach, and to the cross-shore increase in wave height hinged on tidal modulation of water depths. These two large quasi-permanent bars probably originated as essentially breakpoint bars and are different from a small bar formed by swash and surf processes in the course of the experiment at the mean high water neap tide level, which is characterised by a certain degree of tidal stationarity and larger high-tide waves.     

Probing molecular-level transformations of dissolved organic matter: insights on photochemical degradation and protozoan modification of DOM from electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry

Molecular-level characterization of natural organic matter (NOM) has been elusive due to the inherent complexity of natural organic mixtures and to the fact that individual components are often polar and macromolecular. Electrospray ionization (ESI) is a “soft” ionization technique that ionizes polar compounds from aqueous solution prior to injection into a mass spectrometer. The highest resolution and mass accuracy of compounds within NOM have been achieved when ESI is combined with an ultrahigh-resolution mass spectrometer such as the Fourier transform ion cyclotron resonance mass spectrometer (FT-ICR MS). With this technique, individual molecules within a variety of natural organic mixtures can be detected and their elemental composition can be determined. At low mass-to-charge (m/z) ratio, the resolution is high enough to assign exact molecular formulas allowing specific components of these mixtures to be identified. In addition to molecular identification, we can now use ESI FT-ICR MS to examine molecular-level changes in different organic mixtures as a function of relevant geo-processes, such as microbial alterations and photochemistry. Here we present the results from the application of ESI FT-ICR MS to two geochemical questions: (1) the effect of photoirradiation on the molecular composition of fulvic acids and (2) the role of protozoan grazers in the modification of DOM in aquatic systems.     

Barotropic tidal mixing effects in a coupled climate model: Oceanic conditions in the Northern Atlantic

Impacts of mixing driven by barotropic tides in a coupled climate model are investigated by using an atmosphere–ocean–ice–land coupled climate model, the GFDL CM2.0. We focus on oceanic conditions of the Northern Atlantic. Barotropic tidal mixing effects increase the surface salinity and density in the Northern Atlantic and decrease the RMS error of the model surface salinity and temperature fields related to the observational data.