Die Kristallstruktur des Minerals Eclarit, (Cu,Fe) Pb9Bi12S28

Zusammenfassung Die Kristallstruktur des zuerst vonPaar, Chen undMeixner beschriebenen neuen Minerals wurde an der Originalprobe bestimmt. Für die prinzipielle Lösung der Struktur war eine Kombination von direkten und Pattersonmethoden erforderlich. Anhand von 2774 kristallographisch unabhängigen Röntgenreflexen (davon 1828 beobachtet) wurde die Struktur bis zu einem gewichtetenR-Wert von 10.7% isotrop verfeinert. Das Mineral ist orthorhombisch, RaumgruppePnma mit den Gitterkonstantena ₀=54.76Å,b ₀=4.030 Å,c ₀=22.74 Å undZ=4. Die Kristallstruktur ist durch galenitähnliche Bereiche, deren [110] Richtung parallel zurb ₀-Achse verläuft, gekennzeichnet. Die gegenseitige Anordnung dieser Bereiche ist teils kobellit-, teils cosalitähnlich. Die galenitähnlichen Bereiche sind vorwiegend wismuthhaltig (Koordination 3+2+1), während die Ph-Atome in einer trigonal-prismatischen Koordination mit 2 zusätzlichen Schwefelatomen vorwiegend als Bindeglieder dazwischen liegen.

---

The crystal structure of eclarite, (Cu,Fe)Pb₉Bi₁₂S₂₈

Summary The crystal structure of the new mineral eclarite, first described byPaar, Chen andMeixner was determined using the original material. It was necessary to apply a combination of direct and Patterson methods. The structure was refined for 2774 independent reflections (1828 observed) with isotropic temperature factors to a weightedR-value of 10.7%. Eclarite crystallizes in the orthorhombic space groupPnma with lattice parametersa ₀=54.76 Å,b ₀=4.030 Å,c ₀=22.75 Å,Z=4. The structure is characterized by galena-like building units with [110] (galena) parallel to theb-axis. These units are linked to each other partly as in kobellite, partly as in cosalite structures. Bi prefers to occupy the metal positions in the galena-like units, coordinated by 3+2+1S, whereas Pb occupies preferably the positions coordinated trigonal prismatic with two additional S. The latter groups serve to connect the galena-like units.

---

---

Mit 3 Abbildungen

---

Herrn Professor Dr.Josef Zemann zum 60. Geburtstag gewidmet.     

Eddy energy dissipation rate and puff diffusion during calms

The paper considers a puff diffusion in its inertial stage when particle separation obeys the laws of the inertial subrange and depends only on eddy energy dissipation rate . The can be determined in the surface layer by the turbulent kinetic energy equation. Similarity equations connect with diffusion measure .A simple analytical model has been deduced to estimate pollutants diffusion during calms.     

Some possibilities of predicting radio wave absorption in the lower ionosphere

Summary An attempt is made to show possible ways of predicting radio wave absorption in the midlatitude lower ionosphere using relations between absorption and the intensity of solar ionizing radiation and/or common solar activity indices, and between absorption and f₀F2.

---

aa mu nuau nu a¶rt;u ¶rt;um u u a mu ¶rt; nu u umum uuu uu (uu uu u¶rt;au amumu) u ¶rt; nu u f₀F2.

     

Effects of the imf sector structure in the midlatitude troposphere and stratosphere

Summary The data on geopotential heights and temperatures at 7 pressure levels between 1000-10 hPa above Berlin(52.5 °N, 13.4 °E) are analysed for the winters of 1963–1973. No demonstrable effect of the interplanetary magnetic field sector boundary crossing (IMF SBC) is found in the lower and middle stratosphere, but there is a demonstrable effect in the middle troposphere at the 500 hPa level. This effect is less important than the IMF SBC effect in the tropospheric vorticity area index and seems to be of a different type.

---

auum ¶rt;a nnmua m u mnam a 7 nm ¶rt;au ¶rt; 1000-10 a a¶rt; u(52,5 °.., 13,4 °.¶rt;.) ¶rt; u 1963–1973. ua ¶rt;aam m nu mau nam aum n( ) ¶rt;a amu u u ¶rt; mam, ma m a¶rt; ¶rt; mn a 500 a. mm m a, m u¶rt; na¶rt;u aumu am, u am m ¶rt; muna.

     

The relation between the heat flow field and the distribution ofP n -wave velocities for the European continent

Summary The dependence of P_n-wave velocities on the heat flow, temperature at the crustmantle boundary and the thickness of the Earth's crust in Europe was investigated in relation to the problem of lateral inhomogeneities in the upper mantle. A map was constructed of the distribution of P_n-wave velocities on the territory of Europe. The relations these investigations yielded, were compared with the results of laboratory experiments and all the results are discussed from the physical point of view. The conclusion drawn is that that temperature and pressure effect provide a sufficient explanation of the observed regional changes of P_n-wave velocities for the European continent.

---

auum ¶rt;auu mu n¶rt; ¶rt; nmu uua (P_n) u mn nm, mnam a nmu amuu u m a mumuu n a u¶rt;aa u numa ¶rt;¶rt;m amuu. mumuu n a maa a uu m P_n- a nmu uua. u¶rt;u umam ¶rt;a mama aam u¶rt;au uuu m n¶rt; amuu u u ¶rt;au u mnam mmmm mama n¶rt;aa am. ¶rt;a ¶rt;, m ua uu m P_n- a n mum ¶rt;mam um uuu mnam u ¶rt;au a nmu uua.

     

The effect of quartz on the magnetic anisotropy of quartzite

Summary The magnetic susceptibility of quartz single crystals is diamagnetic (–14×10 ^–6 in SI units) and exhibits only very small anisotropy (mostly less than 1%); thus the susceptibility of the quartz matrix in quartzite can be regarded as virtually isotropic. Owing to the influence of the negative and isotropic susceptibility of the quartz matrix, the degree of anisotropy of quartzite, as inferred from model calculations, is higher than that of the ferrimagnetic fraction. This influence is very strong if the mean susceptibility of quartzite is in the vicinity of zero.

---

uma aa m ¶rt;uaaumu (nuuum–14 × 10 ^–6 um ) u a aumnuu ( 1%). m aum, m nuuum a a auma m m numa namuu umn. amamu ¶rt;uau ¶rt;m, m n nuu uu muam u umn nuuumu a a mn aumnmu auma , mn aumnmu aum auu. m uu au m¶rt;a, ¶rt;a ¶rt;a nuuum ua .

     

Anomalous induction across Europe

Summary Using real induction vector data, collected at 958 European observation sites, together with our data from the Bohemian Massif and the West Carpathians, we have generated a contour map of the transfer function TF1 (corresponding to transfer function A in Wiese's relation). Only the zero contour is retained and shown on the map. It clearly marks the main anomalous induction zones, related to internal structural inhomogeneities, across Europe.     

Total ozone response to major geomagnetic storms and changes in meteorological situations

Summary The total ozone response to strong major geomagnetic storms (A_p≥60) in winter along the 50° N latitudinal circle is studied. The results add to the recent results of Laštovička et al. (1992) obtained for European middle latitudes (∼50°N) and to the results of Mlch (1994). A significant response of total ozone is only observed in winter under high solar activity/E-phase of QBO conditions (E-max) and seems to be caused by geomagnetic storm-induced changes of atmospheric dynamics. There are two sectors along latitude 50°N, which are sensitive to forcing by geomagnetic storms both in total ozone and the troposphere — north-eastern Atlantic-European and eastern Siberia-Aleutian sectors. The total ozone response under E-max conditions manifests itself mainly as a large decrease in the longitudinal variation of ozone after the storm, which means an increase of ozone in Europe. The observed effects in total ozone consist in redistribution, not production or loss of ozone.     

Influence of the IMF sector boundaries on cosmic rays and tropospheric vorticity

Summary The effect of the IMF sector boundary crossing (IMF SBC) in the vorticity area index (VAI) — the well-known dip in the VAI after IMF SBC — is found to be independent of the IMF SBC effect in the cosmic ray flux. This finding refutes a recent suggestion by Lundstedt [1] that the IMF SBC effect in VAI is caused by a decrease in cosmic ray flux, but supports the concept of the IMF SBC effects in the ionosphere and atmosphere developed by Latovika [2–4]. Cosmic rays seem to affect the troposphere in another way.

---

¶rt;mu nu mau nam aum n ( ) a u¶rt; na¶rt;u aumu () — um uu n — a¶rt; auu m ma nm uu . mm mam nam ¶rt;a n¶rt;u ¶rt;m¶rt;a [1], m m a nuu nma uu , n¶rt;¶rt;uam nu m u u am, aum amu [2–4]. am m uu u m um a mn ¶rt;u a.