Mercury speciation in surface and deep waters of the Mediterranean Sea

Mercury speciation and its distribution in surface and deep waters of the Mediterranean Sea were studied during two oceanographic cruises on board the Italian research vessel URANIA in summer 2003 and spring 2004 as part of the Med Oceaneor and MERCYMS projects. The study included deep water profiles of dissolved gaseous Hg (DGM), reactive Hg (RHg), total Hg (THg), monomethyl Hg (MeHg) and dimethyl Hg (DMeHg) in open ocean waters. Average concentrations of measured Hg species were characterized by seasonal and spatial variations. Overall average THg concentrations ranged between 0.41 and 2.65 pM (1.32 ± 0.48 pM) and were comparable to those obtained in previous studies of the Mediterranean Sea. A significant fraction of Hg was present as “reactive” Hg (average 0.33 ± 0.32 pM). Dissolved gaseous Hg (DGM), which consists mainly of Hg⁰, represents a considerable proportion of THg (average 20%, 0.23 ± 0.11 pM). The portion of DGM typically increased towards the bottom, especially in areas with strong tectonic activity (Alboran Sea, Strait of Sicily, Tyrrhenian Sea), indicating its geotectonic origin. No dimethyl Hg was found in surface waters down to the depth of 40 m. Below this depth, its average concentration was 2.67 ± 2.9 fM. Dissolved fractions of total Hg and MeHg were measured in filtered water samples and were 0.68 ± 0.43 pM and 0.29 ± 0.17 pM for THg and MeHg respectively. The fraction of Hg as MeHg was in average 43%, which is relatively high compared to other ocean environments. The concentrations reported in this study are among the lowest found in marine environments and the quality of analytical methods are of key importance. Speciation of Hg in sea water is of crucial importance as THg concentrations alone do not give adequate data for understanding Hg sources and cycling in marine environments. For example, photoinduced transformations are important for the presence of reactive and elemental mercury in the surface layers, biologically mediated reactions are important for the production/degradation of MeHg and DGM in the photic zones of the water column, and the data for DGM in deep sea indicate the natural sources of Hg in geotectonicaly active areas of the Mediterranean Sea.     

Geoarchaeological evidence on a Late Bronze Age earthquake,Ohrid Basin (North Macedonia)

Geoarchaeological investigations on the northeastern shore of Lake Ohrid revealed 3.5 m thick deepwater lacustrine sediments overlying terrestrial vegetation macrofossils, worked wood and abundant potsherds dated to the Late Bronze Age (LBA). Distinct contact of deepwater sediment with the sub-aerial weathered limestone bedrock point to a sudden increase in lake level. According to radiocarbon data, catastrophic flooding occurred shortly after 1214 yr bc. Because the area is located in a highly active seismic zone, we propose that this event was caused by tectonically induced, metre-scale coseismic subsidence related to faults bordering the Ohrid alluvial plain. Moreover, this event coincides well with a dramatic switch in the habitation and settlement strategy in the region. More important, however, is the finding that the age of the proposed massive tectonic event and change in habitation lies within the interval of the proposed ‘earthquake storm’ in the eastern Mediterranean dated to 1225–1175 bc. As the Ohrid-Korça zone belongs to the same tectonic province, a relationship between the abovementioned earthquakes and the proposed event can be expected. This research therefore might provide the first direct evidence of a large-scale earthquake event linkable to the LBA collapse of Europe's first urban civilisation in the Aegean.     

Some Aspects of Meteoric Head Echo Velocity Determination

Velocity determination of 131 head echoes recorded during Perseid meteor shower observations by the Canadian 2 MW radar, has been performed under the assumption of either their constant velocity or of its linear change with time. Even though the constant velocities concentrated at 60 km s-1 generally accepted for the Perseids, a substantial number of echoes had velocities either lower than 60 km s-1 or greater than this value. The inclusion of variable velocity into considerations led to surprising result that a great portion of the head echoes accelerated (3 possibly decelerating echoes in comparison with 33 accelerating cases on the level of relative standard deviations of output parameters not exceeding 10%). It seems that the allocation of the ionization responsible for the head echo is not entirely identical with the instantaneous meteoroid position. As a consequence, the velocity derived from the measured head echo coordinates can differ from the velocity of parent body. We are not able to explain this finding at present. This revised version was published online in July 2006 with corrections to the Cover Date.     

Dust particle and solar radiation

Influence of the solar radiation (electromagnetic and corpuscular - solar wind) on the motion of the interplanetary dust particle is investigated. The ratio time of inspiralling toward the Sun: time of inspiralling neglecting the change of mass of the particle is presented as a function of initial eccentricities.     

Variations of Magnetic Bright Point Properties with Longitude and Latitude as Observed by Hinode/SOT G-band Data

Small-scale magnetic fields can be observed on the Sun in high-resolution G-band filtergrams as magnetic bright points (MBPs). We study Hinode/Solar Optical Telescope (SOT) longitude and latitude scans of the quiet solar surface taken in the G-band in order to characterise the centre-to-limb dependence of MBP properties (size and intensity). We find that the MBP’s sizes increase and their intensities decrease from the solar centre towards the limb. The size distribution can be fitted using a log–normal function. The natural logarithm of the mean (μ parameter) of this function follows a second-order polynomial and the generalised standard deviation (σ parameter) follows a fourth-order polynomial or equally well (within statistical errors) a sine function. The brightness decrease of the features is smaller than one would expect from the normal solar centre-to-limb variation; that is to say, the ratio of a MBP’s brightness to the mean intensity of the image increases towards the limb. The centre-to-limb variations of the intensities of the MBPs and the quiet-Sun field can be fitted by a second-order polynomial. The detailed physical process that results in an increase of a MBP’s brightness and size from Sun centre to the limb is not yet understood and has to be studied in more detail in the future.     

On the stability of the zodiacal cloud

The problem of the stability of the zodiacal cloud is scrutinized. The central idea of the paper sticks in the theoretical treatment of the action of the solar electromagnetic radiation on small interplanetary dust particles (IDPs). It is suggested that the virtual problem of the (in-)stability of the zodiacal cloud originated from the physically incorrect application of the Poynting-Robertson effect on IDPs. Real particles are not of spherical shape and so the braking acceleration is not proportional to -v/c. Depending on the shape (and other optical properties) of the particle, also spiralling outward from the Sun may occur.     

VIDEO AND PHOTOGRAPHIC SPECTROSCOPY OF 1998 AND 2001 LEONID PERSISTENT TRAINS FROM 300 TO 930 nm

Spectra of persistent meteor trains were observed at wavelength between 300 and 930 nm. Two obtained train spectra during the 1998 and 2001 Leonid meteor showers are reported here. During the 1998 Leonids, one train was detected by a photographic camera with a spectrograph covering 370–640 nm region. On the other hand, during the 2001 Leonids, video observations were carried out using image intensified cameras in ultraviolet (UV), visible and near infrared (near-IR) wavelengths. Temperatures in persistent trains have been measured by atmospheric O₂ A(0,1) band at the wavelength near 864.5 nm. From a video spectrum obtained just 7 s after parent fireball’s flare, a rotational temperature of 250 K at altitude of 88.0±0.5 km was estimated. We can say that the cooling time scale of train strongly depends on the initial mass of its fireball at least for Leonids. Based on cooling constant calculated from our results, we estimated a temperature of ∼ ∼130 K as a final exothermic temperature at early stage of persistent trains.     

Observational Evidence for Rising Penumbral Flux Tubes?

On 13 May 2000 parts of a penumbra were observed in an active region NOAA 8990 with the La Palma Stokes Polarimeter attached to the Swedish Vacuum Solar Telescope. The stratification over the solar atmosphere of different physical parameters is retrieved from these data by using the Stokes inversion based on response functions. The results confirm the previous findings of the penumbral structure. In general, the magnetic field becomes weaker and more horizontal with increasing distance from the umbra and the line-of-sight velocities are increasing towards the outer boundary of the penumbra. The results also suggest the existence of the unresolved fine structure of the penumbra. The stratifications of the temperature and of the magnetic field strength indicate the presence of rising flux tubes, which were predicted theoretically by Schlichenmaier, Jahn and Schmidt (1998, Astron. Astrophys. 337, 897).     

Diffuse Interstellar Band at 862 nm as a Reddening Tracer for GAIA

We investigate the plausibility of using diffuse interstellar band at862 nm for tracing interstellar extinction with the ESA's astrometric space mission GAIA. For this purpose we perform numerical tests to simulate the conditions of real observations, covering a wide range of stellar parameters and different amounts of interstellar extinction. Our simulations indicate that with the present Radial Velocity Spectrometer setup the uncertainty in color excess of σ_E(B-V)≤ 0.05 can be achieved only for the interstellar reddening tracers brighter than V ∼ 13. None of the plausible tracers can provide accurate color excesses (σ _E(B-V) ≤ 0.05) at the distances beyond 2 kpc. We therefore conclude that with the currently planned instrumentation onboard GAIA this method can not be used as a stand-alone approach for probing interstellar extinction on the Galactic distance scales within the framework of the GAIA mission. This revised version was published online in July 2006 with corrections to the Cover Date.