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11.
Rainwater and snow collected from three different sites in France (Vosges Mountains, French Alps and Strasbourg) show more or less similar shapes of their REE distribution patterns. Rainwater from Strasbourg is the most REE enriched sample, whereas precipitations from the two mountainous, less polluted catchments are less REE enriched and have concentrations close to seawater. They are all strongly LREE depleted.Different water samples from an Alpine watershed comprising snow, interstitial, puddle and streamwater show similar REE distributions with LREE enrichment (rainwater normalized) but MREE and HREE depletion. In this environment, where water transfer from the soil to the river is very quick due to the low thickness of the soils, it appears that REE in streamwater mainly originate from atmospheric inputs. Different is the behaviour of the REE in the spring- and streamwaters from the Vosges Mountains. These waters of long residence time in the deep soil horizons react with soil and bedrock REE carrying minerals and show especially significant negative Eu anomalies compared to atmospheric inputs. Their Sr and Nd isotopic data suggest that most of the Sr and Nd originate from apatite leaching or dissolution. Soil solutions and soil leachates from the upper soil horizons due to alteration processes strongly depleted in REE carrying minerals, have REE distribution patterns close to those of lichens and throughfall. Throughfall is slightly more enriched especially in light REE than filtered rainwater probably due to leaching of atmospheric particles deposited on the foliage and also to leaf excretion.Data suggest that Sr and Nd isotopes of the soil solutions in the upper soil horizons originate from two different sources: 1) An atmospheric source with fertilizer, dust and seawater components and 2) A source mainly determined by mineral dissolution in the soil. These two different sources are also recognizable in the Sr and Nd isotopic composition of the tree’s throughfall solution. The atmospheric contributions of Sr and Nd to throughfall and soil solution are of 20 to 70 and 20%, respectively. In springwater, however, the atmospheric Sr and REE contribution is not detectable.  相似文献   
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The Regab pockmark is a large cold seep area located 10 km north of the Congo deep sea channel at about 3160 m water depth. The associated ecosystem hosts abundant fauna, dominated by chemosynthetic species such as the mussel Bathymodiolus aff. boomerang, vestimentiferan tubeworm Escarpia southwardae, and vesicomyid clams Laubiericoncha chuni and Christineconcha regab. The pockmark was visited during the West African Cold Seeps (WACS) cruise with RV Pourquoi Pas? in February 2011, and a 14,000‐m2 high‐resolution videomosaic was constructed to map the most populated area and to describe the distribution of the dominant megafauna (mussels, tubeworms and clams). The results are compared with previous published works, which also included a videomosaic in the same area of the pockmark, based on images of the BIOZAIRE cruise in 2001. The 10‐year variation of the faunal distribution is described and reveals that the visible abundance and distribution of the dominant megafaunal populations at Regab have not changed significantly, suggesting that the overall methane and sulfide fluxes that reach the faunal communities have been stable. Nevertheless, small and localized distribution changes in the clam community indicate that it is exposed to more transient fluxes than the other communities. Observations suggest that the main megafaunal aggregations at Regab are distributed around focused zones of high flux of methane‐enriched fluids likely related to distinct smaller pockmark structures that compose the larger Regab pockmark. Although most results are consistent with the existing successional models for seep communities, some observations in the distribution of the Regab mussel population do not entirely fit into these models. This is likely due to the high heterogeneity of this site formed by the coalescence of several pockmarks. We hypothesize that the mussel distribution at Regab could also be controlled by the occurrence of zones of both intense methane fluxes and reduced efficiency of the anaerobic oxidation of methane possibly limiting tubeworm colonization.  相似文献   
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This work presents new 87Sr/86Sr and δ88/86SrSRM987 isotopic values of thirteen mineral, vegetal and animal reference materials. Except for UB‐N, all our results are consistent with previously published data. Our results highlight intermediate precisions among the best presently published and a non‐significant systematic shift with the calculated δ88/86SrSRM987 mean values for the three most analysed reference materials in the literature (i.e., IAPSO, BCR‐2 and JCp‐1). By comparison with the literature and between two distinct digestions, a significant bias of δ88/86SrSRM987 values was highlighted for two reference materials (UB‐N and GS‐N). It has also been shown that digestion protocols (nitric and multi‐acid) have a moderate impact on the δ88/86SrSRM987 isotopic values for the Jls‐1 reference materials suggesting that a nitric acid digestion of carbonate can be used without significant bias from partial digestion of non‐carbonate impurities. Different δ88/86SrSRM987 values were measured after two independent Sr/matrix separations, according to the same protocol, for a fat‐rich organic reference material (BCR‐380R) and have been related to a potential post‐digestion heterogeneity. Finally, the δ88/86SrSRM987 value differences measured between animal‐vegetal and between coral‐seawater reference materials agree with the previously published results, highlighting an Sr isotopic fractionation along the trophic chain and during carbonate precipitation.  相似文献   
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High-pressure crystal structures and compressibilities have been determined by x-ray methods for MgAl2O4 spinel and its isomorph magnetite, Fe3O4. The measured bulk moduli, K, of spinel and magnetite (assuming K′=4) are 1.94±0.06 and 1.86±0.05 Mbar, respectively, in accord with previous ultrasonic determinations. The oxygen u parameter, the only variable atomic position coordinate in the spinel structure (Fd3m, Z=8), decreases with pressure in MgAl2O4, thus indicating that the magnesium tetrahedron is more compressible than the aluminum octahedron. In magnetite the u parameter is unchanged, and both tetrahedron and octahedron display the 1.9 Mbar bulk modulus characteristic of the entire crystal. This behavior contrasts with that of nickel silicate spinel (γ-Ni2SiO4), in which the u parameter increases with pressure because the silicon tetrahedron is relatively incompressible compared to the nickel octahedron.  相似文献   
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We reconstruct palaeoclimate and palaeoceanography of the Ísafjarðardjúp fjord system from two cores – one from the inner fjord and one near the fjord mouth – while separating the potential overprinting of relative sea‐level (RSL) and local fjord hydrographic changes on these records. The inner fjord core (B997‐339) reflects local fjord hydrography; the outer fjord core (MD99‐2266) reflects the regional oceanic signal. Glacial marine conditions ended at ca. 10 200 cal. a BP, indicated by both ice‐rafted debris records. The other proxy records show spatial and temporal variability within the fjord system. At the inner fjord site (B997‐339) foraminiferal assemblages and the δ18O record indicate lowered RSL between ca. 10 600 and 8900 cal. a BP and document the onset of fjord water overturning at ca. 8900 cal. a BP, which obscured the climate record. At the fjord mouth (MD99‐2266) mass accumulation rates suggest lowered RSL between ca. 10 200 and 5500 cal. a BP and local freshwater and/or reduced salinities of the Irminger Current water masses affected the δ18O signal between ca. 10 200 and 7900 cal. a BP. At MD99‐2266, foraminiferal fauna record the Holocene Thermal Maximum between ca. 8000 and 5700 cal. a BP and the onset of modern oceanic circulation at ca. 7000 cal. a BP. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   
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Current global warming projections suggest a possible increase in wildfire and drought, augmenting the need to understand how drought following wildfire affects the recovery of stream channels in relation to sediment dynamics. We investigated post‐wildfire geomorphic responses caused by storms during a prolonged drought following the 2013 Springs Fire in southern California (USA), using multi‐temporal terrestrial laser scanning and detailed field measurements. After the fire, a dry‐season dry‐ravel sediment pulse contributed sand and small gravel to hillslope‐channel margins in Big Sycamore Creek and its tributaries. A small storm in WY 2014 generated sufficient flow to mobilize a portion of the sediment derived from the dry‐ravel pulse and deposited the fine sediment in the channel, totaling ~0.60 m3/m of volume per unit length of channel. The sediment deposit buried step‐pool habitat structure and reduced roughness by over 90%. These changes altered sediment transport characteristics of the bed material present before and after the storm; the ratio of available to critical shear stress (τoc) increased by five times. Storms during WY 2015 contributed additional fine sediment from tributaries and lower hillslopes and hyperconcentrated flow transported and deposited additional sediment in the channel. Together these sources delivered sediment on the order of six times that in 2014, further increasing τo/τc. These storms during multi‐year drought following wildfire transformed channel dynamics. The increased sediment transport capacity persisted during the drought period characterized by the longer residence time of relatively fine‐grained post‐fire channel sedimentation. This contrasts with wetter years, when post‐fire sediment is transported from the fluvial system during the same season as the post‐fire sediment pulse. Results of this short‐term study highlight the complex and substantial effects of multi‐year drought on geomorphic responses following wildfire. These responses influence pool habitat that is critical to longer‐term post‐wildfire riparian ecosystem recovery. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   
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