Cambro-Ordovician palaeomagnetic and geochronologic data from southern Victoria Land, Antarctica: revision of the Gondwana apparent polar wander path

We present new palaeomagnetic and isotopic data from the southern Victoria Land region of the Transantarctic Mountains in East Antarctica that constrain the palaeogeographic position of this region during the Late Cambrian and Early Ordovician. A new pole has been determined from a dioritic intrusion at Killer Ridge (⁴⁰Ar/³⁹Ar biotite age of 499 ± 3 Ma) and hornblende diorite dykes at Mt. Loke (21°E, 7°S, A 95 = 8°, N = 6 VGPs). The new Killer Ridge/Mt. Loke pole is indistinguishable from Gondwana Late Cambrian and Early Ordovician poles. Previously reported palaeomagnetic poles from southern Victoria Land have new isotopic age constraints that place them in the Late Cambrian rather than the Early Ordovician. Based upon the new palaeomagnetic and isotopic data, new Gondwana Late Cambrian and Early Ordovician mean poles have been calculated.     

Estimating historical in-lake alkalinity generation from sulfate reduction and its relationship to lake chemistry as inferred from algal microfossils

Sediment cores were used to estimate in-lake alkalinity generation resulting from sulfate reduction relative to inferred changes in lakewater pH and trophic status over the last century in three Connecticut lakes. Despite being situated in geological settings with crystalline bedrock and thin, poorly buffered soils, and being impacted with high rates of acidic precipitation, none of the study lakes have declined in inferred pH based on scaled chrysophyte and diatom remains. In fact, the pH of one of the lakes, Coventry Lake, has significantly increased over the last century. Over the last 44 to 69 years the amount of sulfur stored in the sediments from each lake increased from ~two to three times resulting in mean rates of alkalinity generation ranging from 78 to 145 meq m^–2 yr^–1, significantly higher than the 45 to 48 meq m^–2 yr^–1 of hydrogen ions falling directly on the lake surfaces. In-lake alkalinity generation resulting from sulfate reduction has been sufficient to neutralize all of the acid falling directly onto the lake surfaces, as well as between 9% and 25% of the acid deposited onto the surrounding watersheds. Despite the increased importance of in-lake alkalinity generation, our findings support the hypothesis that significant amounts of alkalinity are also being generated in the catchments of the study lakes. The bulk of the increases in stored sulfur in all three lakes were as Fe sulfides and not in the form of organic sulfur, suggesting that the increases were the result of dissimilatory bacterial reduction of sulfate. As a result of the large increases in storage of Fe sulfides the ratio of total iron to chromium reducible sulfur (Fe:CRS) has declined in all cores over time. Despite the overall decline in Fe:CRS in recent sediments, values are still largely above 3 in more recent sediments of two of the lakes. However, values of Fe:CRS have dropped below 1 in surface sediments of Uncas Lake, suggesting that in-lake loading of phosphorus may be responsible for a recent shift in the algal flora towards a slightly more eutrophic condition.     

The regional setting of the Woodlawn deposit

The Woodlawn zinc‐lead‐copper deposit is one of a number of stratabound volcanogenic base‐metal deposits in the eastern part of the Lachlan Fold Belt. These deposits are commonly bandned and chemically zoned. They are copper‐rich at the base and lead‐zinc‐(barium)‐rich at the top. Alternatively, discrete copper‐rich, lead‐zinc‐rich and barium‐rich bodies may be developed. Oxide facies variants have been recognised at a number of localities. The deposits were formed in or adjacent to volcanic rifts during the Late Silurian. The Woodlawn deposit is located within the Captains Flat‐Goulburn Synclinorial Zone within a sequence of quartz‐feldspar porphyry, agglomerate, tuff, tuffaceous shale and black shale.     

Proper elements for highly inclined asteroidal orbits

Based on Williams' work and rewritten in action angle variables, a method for the calculation of proper elements is here presented. The averaging over the long periodic terms is performed by the semi numerical method developed by Henrard (1990); no series expansion in eccentricity or inclination of the asteroid is used which allows calculating proper elements for highly inclined orbits. Conversely, the theory is truncated at the first degree in the eccentricity and the inclination of the perturbing planets. A few tests about accuracy and consistency are presented.     

A spatial and temporal drought risk assessment of three major tree species in Britain using probabilistic climate change projections

Probabilistic climate data have become available for the first time through the UK Climate Projections 2009, so that the risk of change in tree growth can be quantified. We assessed the drought risk spatially and temporally using drought probabilities calculated from the weather generator data and tree species vulnerabilities using Ecological Site Classification model across Britain. We evaluated the drought impact on the potential yield class of three major tree species (Picea sitchensis, Pinus sylvestris, and Quercus robur), which cover around 59 % (400,700 ha) of state-managed forests, across the lowlands and uplands. We show that drought impacts result mostly in reduced tree growth over the next 80 years when using B1, A1B, and A1FI IPCC emissions scenarios, but varied spatially. We found a maximum reduction of 94 % but also a maximum increase of 56 % in potential stand yield class in the 2080s from the baseline climate (1961–1990). Furthermore, potential production over the state-managed forests for all three species in the 2080s is estimated to decrease due to drought by 42 % in the lowlands and by 32 % in the uplands in comparison to the baseline climate. Our results reveal that potential tree growth and forest production on the state-managed forests in Britain is likely to reduce, and indicate where and when adaptation measures are required. Moreover, this paper demonstrates the value of probabilistic climate projections for an important economic and environmental sector.     

Internal and forced variability along a section between Greenland and Portugal in the CLIPPER Atlantic model

Numerical models are used to estimate the meridional overturning and transports along the paths of two hydrographic cruises, carried out in 1997 and 2002 from Greenland to Portugal. We have examined the influence of the different paths of the two cruises and found that it could explain 0.4 to 2 Sv of difference in overturning (the precise value is model-dependent). Models show a decrease in the overturning circulation between 1997 and 2002, with different amplitudes. The CLIPPER ATL6 model reproduces well the observed weakening of the overturning in density coordinates between the cruises; in the model, the change is due to the combination of interannual and high-frequency forcing and internal variability associated with eddies and meanders. Examination of the -coordinate overturning reveals model–data discrepancies: the vertical structure in the models does not change as much as the observed one. The East Greenland current variability is mainly wind-forced in the ATL6 model, while fluctuations due to eddies and instabilities explain a large part of the North Atlantic Current variability. The time-residual transport of dense water and heat due to eddy correlations between currents and properties is small across this section, which is normal to the direction of the main current.     

Internal gravity waves in a stably stratified boundary layer

Often, a combination of waves and turbulence is present in the stably stratified atmospheric boundary layer. The presence of waves manifest itself in the vertical profiles of variances of fluctuations and in low-frequency contributions to the power spectra. In this paper we study internal waves by means of a linear stability analysis of the mean profiles in a stably stratified boundary layer and compare the results with observed vertical variance profiles of fluctuating wind and temperature along a 200 m mast. The linear stability analysis shows that the observed mean flow is unstable for disturbances in a certain frequency and wavenumber domain. These disturbances are expected to the detectable in the measurements. It is shown that indeed the calculated unstable frequencies are present in the observed spectra. Furthermore, the shape of the measured vertical variance profiles, which increase with height, is explained well by the calculated vertical structure of the amplitude of unstable Kelvin-Helmholtz waves, confirming the contribution of waves to the variances. Because turbulence and waves have quite distinct transport properties, estimates of diffusion from measurements of variances would strongly overestimate this diffusion. Therefore it is important to distinguish between them.     

Impact of global change on the biogeochemistry and ecology of an Arctic freshwater system

Lakes and streams in the foothills near Tookik Lake, Alaska, at 68°N have been studied since 1975 to predict physical, chemical and biological impacts of future global change. Experimental manipulations include whole lake and continuous stream fertilization as well as removal and addition of predators (copepods, lake trout, grayling, sculpin). Based on our evidence the following scenario is likely. Warming thaws the upper layers of permafrost and streams and lakes become enriched with phosphorus. Streams respond quickly with higher production of diatoms but animal grazers keep biomass changes to a minimum. Fish productivity also increases. If phosphorus levels are too high, mosses become the dominant primary producer and sequester all of the nutrients. Growth of Arctic grayling under the present conditions only occurs in summers with higher than average stream flow. The present population would be stressed by warmer temperatures. When higher phosphorus levels reach lakes and cause slight europhication, the number of trophic levels will increase, especially within the microbial food web. Warmer lake temperatures increase stratification and, combined with eutrophication, could decrease oxygen in the hypolimnion. Oxygen levels will also decrease in winter under the ice cover. Eventually this habitat change will eliminate the lake trout, a top predator. Removal of lake trout results in a striking increase in abundance and productivity of smaller fish, including small lake trout, and the emergence of burbot as an alternate top predator. Large species of zooplankton will become virtually extinct.     

Preliminary study on the preservation of giant clam (Tridacnidae) shells from the Balobok Rockshelter archaeological site,south Philippines

Tridacnidae shells, a valuable archive of past environments, are common in the Balobok Rockshelter archaeological site on Sanga‐Sanga Island in the south Philippines. This site was occupied during the mid‐Holocene (ca. 5000–8800 ¹⁴C yr B.P.), a period of Neolithic cultural expansion in the Philippines. This paper focuses on the preservation of two shell specimens, Hippopus hippopus and Tridacna maxima, unearthed from two mid‐Holocene layers within the rockshelter. The shells' mineralogy and microstructure (prismatic and crossed‐lamellar) were studied using micro‐Fourier transform infrared spectroscopy and scanning electron microscopy to determine if the samples were suitable as paleoenvironmental records. Both shells are still aragonitic but aragonite crystals of both microstructure types are partly dissolved. This dissolution, characteristic of meteoric water alteration, precludes their utility in paleoenvironmental geochemical studies. Nevertheless, these shells are abundant in archaeological sites in the region and may be better preserved in other depositional contexts; more studies on Philippine Tridacnidae shell diagenesis are needed. © 2011 Wiley Periodicals, Inc.