Towards ground truthing exploration in the central Arctic Ocean: a Cenozoic compaction history from the Lomonosov Ridge

The Integrated Ocean Drilling Program's Expedition 302, the Arctic Coring Expedition (ACEX), recovered the first Cenozoic sedimentary sequence from the central Arctic Ocean. ACEX provided ground truth for basin scale geophysical interpretations and for guiding future exploration targets in this largely unexplored ocean basin. Here, we present results from a series of consolidation tests used to characterize sediment compressibility and permeability and integrate these with high‐resolution measurements of bulk density, porosity and shear strength to investigate the stress history and the nature of prominent lithostratigraphic and seismostratigraphic boundaries in the ACEX record. Despite moderate sedimentation rates (10–30 m Myr^?1) and high permeability values (10^?15–10^?18 m²), consolidation and shear strength measurements both suggest an overall state of underconsolidation or overpressure. One‐dimensional compaction modelling shows that to maintain such excess pore pressures, an in situ fluid source is required that exceeds the rate of fluid expulsion generated by mechanical compaction alone. Geochemical and sedimentological evidence is presented that identifies the Opal A–C/T transformation of biosiliceous rich sediments as a potential additional in situ fluid source. However, the combined rate of chemical and mechanical compaction remain too low to fully account for the observed pore pressure gradients, implying an additional diagenetic fluid source from within or below the recovered Cenozoic sediments from ACEX. Recognition of the Opal A–C/T reaction front in the ACEX record has broad reaching regional implications on slope stability and subsurface pressure evolution, and provides an important consideration for interpreting and correlating the spatially limited seismic data from the Arctic Ocean.     

Granulite facies metasomatism: zoned calc-silicate boudins from the Rauer Group,East Antarctica

Calc-silicate boudins from the Rauer Group, East Antarctica, were metamorphosed under granulite facies conditions during late Proterozoic (ca. 1,000 Ma) M3 metamorphism. Boudin cores contain low to moderate a_{CO 2} assemblages including wollastonite, grossularandradite (grandite) garnet, clinopyroxene, scapolite, plagioclase, quartz±calcite. Petrological and stable isotopic evidence suggests that these core assemblages resulted from pre-peak M3 infiltration of water-rich fluids; there is no evidence for a pervasive fluid phase under peak M3 conditions. The boudins are separated from the surrounding Fe-rich pelites and semi-pelites by a series of concentric, high-variance reaction zones developed under peak M3 conditions. Variations in mineral assemblage, mineral composition and whole rock composition across these zones suggest that they formed by diffusional masstransfer, controlled principally by a chemical potential gradient in Ca across the original calc-silicate-paragneiss lithological boundary. As a consequence of the nearcomplete decarbonation of the calc-silicatesbefore the M3 peak, development of the diffusion-controlled reaction zones did not liberate significant CO₂ during granulite facies metamorphism. Similar calcite-poor, low a_{CO 2} calc-silicate horizons in other granulite facies terrains are unlikely to have been important local fluid sources during deep crustal metamorphism.     

Distinguishing groundwater flow paths in different fractured-rock aquifers using groundwater chemistry: Dandenong Ranges, southeast Australia

Major ion geochemistry is used to qualitatively interpret groundwater residence times within an aquifer, and the extent of mixing between aquifers with distinctive mineralogy. In conjunction with hydraulic heads and stable isotope geochemistry, flow paths and inter-aquifer exchange are defined in a fractured-rock aquifer system in the Dandenong Ranges, southeast Australia. Stable isotopes indicate modern seasonal recharge throughout the system. At high elevations in the sub-catchment, which includes both marine Silurian-Devonian sedimentary and Tertiary basalt aquifers, Cl is derived primarily from cyclic salts, and differences in mineralogy result in groundwater from the basalt aquifer having higher TDS contents (123–262 mg/L) and (Ca+Mg)/Na ratios (0.9–1.3) than groundwater from the sedimentary aquifer (TDS: 55–79 mg/L; (Ca+Mg)/Na: 0.1–0.2). At low elevations, in areas of local groundwater discharge, the more regional flow system in the Silurian-Devonian sediments contains additional Cl from water–rock interaction and has distinctly higher TDS contents (517–537 mg/L). Differences in groundwater chemistry between the aquifers and between shallower and deeper flow systems highlights areas of inter-aquifer mixing. This is particularly important for aquifer vulnerability where groundwater quality in the deeper aquifer may be impacted by surface activities.

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Resumen Se ha utilizado geoquímica de iones mayores para interpretar cualitativamente los tiempos de residencia del agua subterránea dentro de un acuífero, y el grado de mezcla entre acuíferos con mineralogía característica. De manera conjunta con presiones hidráulicas y geoquímica de isótopos estables, se han definido trayectorias de flujo e intercambio entre acuíferos en un sistema de acuífero de roca fracturada en las Sierras Dandenong, sureste de Australia. Los isótopos estables indican recarga estacional moderada a través del sistema. A elevaciones altas en la sub-cuenca que incluye acuíferos sedimentarios Silúrico-Devónicos y acuíferos basálticos Terciarios, Cl se deriva principalmente de sales cíclicas. Las diferencias en mineralogía resultan en agua subterránea del acuífero basáltico que tiene mayores contenidos TDS (123–262 mg/L) y mayor relación (Ca+Mg)/Na (0.9–1.3) que el agua subterránea de los acuíferos sedimentarios (TDS:55–79 mg/L; (Ca+Mg)/Na: 0.1–0.2). A elevaciones bajas, en áreas de recarga local de agua subterránea, el sistema de flujo más regional en los sedimentos Silúrico-Devónicos contiene Cl adicional que se deriva de la interacción roca-agua y típico contenido TDS más alto (517–537 mg L). Las diferencias en la química del agua subterránea entre los acuíferos y entre los sistemas de flujo más profundo y más somero resalta áreas de mezcla entre acuíferos. Esto es particularmente importante para la vulnerabilidad del acuífero donde la calidad del agua subterránea en el acuífero más profundo puede ser impactada por las actividades superficiales.

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Résumé Les ions majeurs sont utilisés pour interpréter quantitativement les temps de résidence des eaux souterraines dans les aquifères, et létendue des zones de mélange entre les aquifères de différentes minéralogies. En regard de la répartition des charges hydrauliques et des informations données par les isotopes stables, les écoulements et les échanges inter-aquifères sont définis dans un aquifère fracturé dans le Dandenong Ranges, SE de lAustralie. Les isotopes stables indiquent des recharges modernes et saisonnières à travers le système aquifère. A haute altitude dans le sous-bassin versant, qui inclut des sédiments du Siluro-Dévonien et des basaltes du Tertiaire, le chlore est dabord dérivé des sels cycliques, et des différences minéralogiques dans les eaux souterraines sont observées selon laquifère : basalte tertiaire (TDS: 123–262 mg/L; Ca+Mg/Ca: 0.9 à 1.3) et sédiments primaires (TDS: 55–79 mg/L; Ca+Mg/Ca: 0.1–0.2). Aux basses altitudes, dans les zones locales de décharge des eaux souterraines, les écoulements les plus régionaux possèdent des teneurs plus élevées en Chlore en provenance des interactions eau—roche, et des TDS plus élevées (515–537 mg/L). Des différences dans la chimie des eaux souterraines entre les aquifères et entre les systèmes découlement de surface et les écoulements profonds mettent en lumière les zones de mélange inter-aquifère. Ceci est particulièrement important pour la définition de la vulnérabilité où la qualité des eaux souterraines en profondeur peuvent subir les impacts des activités de surface.

     

Hydrogeochemistry of the Goulburn Valley region of the Murray Basin, Australia: implications for flow paths and resource vulnerability

Groundwater in the Goulburn region of the Murray Basin (Australia) contains solutes derived mainly from evapotranspiration of rainfall-derived marine aerosols, silicate dissolution, and ion exchange. ¹⁴C data indicate that groundwater in the Shepparton Formation recharges vertically across the region, whereas groundwater in the Calivil–Renmark Formation shows a greater component of lateral flow. The overall pattern of geochemical and stable isotope variations implies that long-term vertical groundwater flow into the Calivil–Renmark Formation has occurred over thousands of years. Elevated C, N, and F concentrations, together with variable Cl/Br ratios and ¹⁸O values, suggest that short-term (years to decades) flow of surface water into the Calivil–Renmark Formation also occurs locally. The high degree of vertical flow implies that the high-quality groundwater resources of the Calivil–Renmark Formation are vulnerable to surface contamination. Groundwater in both the Shepparton and Calivil–Renmark Formations yields ¹⁴C ages of up to 20 ka that imply that, overall, recharge rates are low and that, consequently, the groundwater resource in both formations could be impacted by over abstraction.

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Resumen Las aguas subterráneas de la región de Goulburn, en la cuenca del río Murray (Australia), contienen solutos procedentes principalmente de la evaporación de agua de lluvia, disolución de silicatos e intercambio iónico. Aunque la variabilidad espacial de la hidrogeoquímica es reducida, el contenido total de sales disueltas en las aguas subterráneas de la formación no confinada de Shepparton es generalmente mayor que el del acuífero inferior confinado de la Formación Calivil–Renmark. Los datos de ¹⁴C, ³H y geoquímica sugieren que la recarga del acuífero de la Formación Shepparton es por infiltración (vertical) en toda la región, mientras que la Formación Calivil–Renmark tiene una mayor proporción de aportes laterales. Sin embargo, a escala local se produce recarga vertical en la Formación Calivil–Renmark, hecho que indica que este recurso es vulnerable a la contaminación. Las aguas subterráneas de ambas formaciones tienen edades de hasta 20.000 años, según datos de ¹⁴C, lo que implica que las tasas de recarga son bajas y, en consecuencia, que podría haber impactos asociados a la sobreexplotación del recurso. Las aguas subterráneas recientes de la región se caracterizan por relaciones molares muy variables de Cl/Br (de 50 a 1.200), reflejando la química de una precipitación semiárida que se ve modificada posteriormente por disolución de halita, asociada con terrenos secos y riego con aguas salinas. Las aguas subterráneas más profundas presentan relaciones más uniformes de Cl/Br (entre 500 y 800), y probablemente reflejan que la recarga se produjo en condiciones climáticas más húmedas que las actuales.

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Résumé Les eaux souterraines de la région de Goulburn dans le bassin de Murray (Australie) contiennent des solutés provenant essentiellement de lévaporation des pluies, de la dissolution de silicates et déchanges dions. Alors quil y a peu de variations spatiales du chimisme des eaux souterraines, les concentrations en sels dissous totaux des eaux souterraines de laquifère libre de la formation de Shepparton sont en général plus élevées que celles des eaux souterraines de laquifère captif sous-jacent de la formation de Calivil-Renmark. Des données de carbone-14, de tritium et de géochimie indiquent que laquifère de la formation de Shepparton est rechargé verticalement dans toute la région, tandis que laquifère de la formation de Calivil-Renmark présente une plus forte composante découlement latéral. Toutefois, localement, il se produit une recharge verticale de laquifère de la formation de Calivil-Renmark, ce qui indique que cette ressource est vulnérable à la contamination. Les eaux souterraines des formations de Shepparton et de Calivil-Renmark présentent toutes deux des âges carbone-14 de plus de 20 ka, ce qui implique des taux de recharge très faibles et, par conséquent, que leur ressource peut être affectée par des prélèvements excessifs. Les eaux souterraines récentes dans cette région sont caractérisées par un rapport molaire Cl/Br très variable (de 50 à 1200), qui reflète le chimisme de pluies en région semi-aride modifié en conséquence par la dissolution de la halite associée à la salinité due aux terres sèches et à lirrigation. Les eaux souterraines plus profondes possèdent des rapports Cl/Br plus uniformes (de lordre de 500 à 800) et reflètent probablement des eaux de recharge sous des conditions climatiques plus humides que les conditions actuelles.

     

Response of Coastal Groundwater Table to Offshore Storms

Large groundwater table fluctuations were observed in a coastal aquifer during an offshore storm. The storm induced significant changes of the mean shoreline elevation, characterized by a pulse-like oscillation. This pulse propagated in the aquifer, resulting in the water table fluctuations. A general analytical solution is derived to quantify this new mechanism of water table fluctuation. The solution is applied to field observations and is found to be able to predict reasonably well the observed storm-induced water table fluctuations. Based on the analytical solution, the damping characteristics and phase shift of the oscillation as it propagates inland are examined.     

Evaluation of temporal consistency of snow depth drivers of a Rocky Mountain watershed in southern Alberta

Collecting spatially representative data over large areas is a challenge within snow monitoring frameworks. Identifying consistent trends in snow accumulation properties enables increased sampling efficiency by minimizing field collection time and/or remote sensing costs. Seasonal snowpack depth estimations during mid-winter and melt onset conditions were derived from airborne Lidar over the West Castle Watershed in the southern Canadian Rockies on three dates. Each dataset was divided into five sets of snow depth driver classes: elevation, aspect, topographic position index, canopy cover and slope. Datasets were quality controlled by eliminating snow depth values above the 99th percentile value, which had a negligible effect on average snow depths. Consistent trends were observed among driver classes with peak snow accumulation occurring within the treeline ecotone, north-facing aspects, open canopies, topographic depressions and areas with low slope angle. Although mid-winter class trends for each driver were similar and watershed-scale snow depth distributions were significantly correlated (0.76, p < .01), depth distributions within the same driver class of the three datasets were not correlated due to recent snowfall events, redistribution and settling processes. Trends in driver classes during late season melt onset were similar to mid-winter conditions but watershed scale distribution correlation results varied with seasonality (0.68 mid-winter 2014 and melt onset 2016; 0.65 mid-winter 2017 and melt onset 2016, p < .1). This is due to the differing stages of accumulation or ablation and the upward migration in the 0°C isotherm during spring, when snow depth can be declining in valley bottoms while still increasing at higher elevations. The observed consistency in depth driver controls can be used to guide future integrated snow monitoring frameworks.     

The stratigraphic and geographic distribution of giant craters and remobilised sediment mounds on the mid Norway margin,and their relation to long term fluid flow

Large craters associated with mounds of remobilised sediment have been recently mapped on the mid Norway margin in the Møre Basin. These craters and mounds may be linked to the long term migration of fluids upwards from the lower levels of the Møre Basin which exploit hydrothermal vent complexes emplaced in the late Paleocene and early Eocene. All of the craters are located on a regionally correlative seismic surface that is correlated with the basal shear plane of Slide W, a slide located at the base of the Plio-Pleistocene Naust Formation. The Craters are positioned in the western area of the Møre Basin at the foot of the continental slope on the crests and flanks of Miocene domes, where Oligocene biosiliceous ooze subcrops on the basal shear surface of Slide W. Not all of the craters are filled by Slide W. Mounds are emplaced above those craters which are filled by Slide W on the top surface of Slide W. Stratal relationships show that the mounds were emplaced on the paleo-seabed. We present and discuss two models that illustrate processes that may have been involved in the formation of craters and remobilisation of sediments. In one model, an eruption of fluid from beneath remobilises ooze into ooze mounds in a single event triggering slope failure, whereas in the other model the emplacement of Slide W and later slides loads low density ooze causing it to undergo liquefaction, a process which may have been facilitated by the trapping of continuous long term fluid migrating from beneath, causing the ooze to remobilise into ooze mounds in two or more events.     

Constraining groundwater flow,residence times,inter-aquifer mixing,and aquifer properties using environmental isotopes in the southeast Murray Basin,Australia

Environmental isotopes (particularly δ¹⁸O, δ²H, and δ¹³C values, ⁸⁷Sr/⁸⁶Sr ratios, and a¹⁴C) constrain geochemical processes, recharge distribution and rates, and inter-aquifer mixing in the Riverine Province of the southern Murray Basin. Due to methanogenesis and the variable δ¹³C values of matrix calcite, δ¹³C values are highly variable and it is difficult to correct ¹⁴C ages using δ¹³C values alone. In catchments where δ¹³C values, ⁸⁷Sr/⁸⁶Sr ratios, and major ion geochemistry yield similar a¹⁴C corrections, ∼15% of the C is derived from the aquifer matrix in the silicate-dominated aquifers, and this value may be used to correct ages in other catchments. Most groundwater has a¹⁴C above background (∼2 pMC) implying that residence times are <30 ka. Catchments containing saline groundwater generally record older ¹⁴C ages compared to catchments that contain lower salinity groundwater, which is consistent with evapotranspiration being the major hydrogeochemical process. However, some low salinity groundwater in the west of the Riverine Province has residence times of >30 ka probably resulting from episodic recharge during infrequent high rainfall episodes. Mixing between shallower and deeper groundwater results in ¹⁴C ages being poorly correlated with distance from the basin margins in many catchments; however, groundwater flow in palaeovalleys where the deeper Calivil–Renmark Formation is coarser grained and has high hydraulic conductivities is considerably more simple with little inter-aquifer mixing. Despite the range of ages, δ¹⁸O and δ²H values of groundwater in the Riverine Province do not preserve a record of changing climate; this is probably due to the absence of extreme climatic variations, such as glaciations, and the fact that the area is not significantly impacted by monsoonal systems.