Geochemistry of low-molecular weight hydrocarbons in hydrothermal fluids from Middle Valley, northern Juan de Fuca Ridge

Hydrothermal vent fluids from Middle Valley, a sediment-covered vent field located on the northern Juan de Fuca Ridge, were sampled in July, 2000. Eight different vents with exit temperatures of 186-281 °C were sampled from two areas of venting: the Dead Dog and ODP Mound fields. Fluids from the Dead Dog field are characterized by higher concentrations of ΣNH₃ and organic compounds (C₁-C₄ alkanes, ethene, propene, benzene and toluene) compared with fluids from the ODP Mound field. The ODP Mound fluids, however, are characterized by higher C₁/(C₂ + C₃) and benzene:toluene ratios than those from the Dead Dog field. The aqueous organic compounds in these fluids have been derived from both bacterial processes (methanogenesis in low temperature regions during recharge) as well as from thermogenic processes in higher temperature portions of the subsurface reaction zone. As the sediments undergo hydrothermal alteration, carbon dioxide and hydrocarbons are released to solution as organic matter degrades via a stepwise oxidation process. Compositional and isotopic differences in the aqueous hydrocarbons indicate that maximum subsurface temperatures at the ODP Mound are greater than those at the Dead Dog field. Maximum subsurface temperatures were calculated assuming that thermodynamic equilibrium is attained between alkenes and alkanes, benzene and toluene, and carbon dioxide and methane. The calculated temperatures for alkene-alkane equilibrium are consistent with differences in the dissolved Cl concentrations in fluids from the two fields, and confirm that subsurface temperatures at the ODP Mound are hotter than those at the Dead Dog field. Temperatures calculated assuming benzene-toluene equilibrium and carbon dioxide-methane equilibrium are similar to observed exit temperatures, and do not record the hottest subsurface conditions. The difference in subsurface temperatures estimated using organic geochemical thermometers reflects subsurface cooling processes via mixing of a hot, low salinity vapor with a cooler, seawater salinity fluid. Because of the disparate temperature dependence of alkene-alkane and benzene-toluene equilibria, the mixed fluid records both the high and low temperature equilibrium conditions. These calculations indicate that vapor-rich fluids are presently being formed in the crust beneath the ODP Mound, yet do not reach the surface due to mixing with the lower temperature fluids.     

The use of selected research methods to describe the pore space of dolomite from copper ore mine,Poland

Basic knowledge of the characteristics of copper-bearing rock such as dolomite is essential to locate those areas of the deposit which have different structural and textural properties. Those regions can be important in terms of the assessment of the possibilities of gas accumulating in them as well as in terms of gasogeodynamic hazard. To better understand those threats, it is necessary to locate, monitor and analyse those areas in detail. This article characterises the structural and textural parameters of dolomite from the Polkowice–Sieroszowice copper mine in Poland. The study involved five samples from various areas of the mine. A number of research methods were selected. Reflected and transmitted light microscopy (MS), computer microtomography (Micro-CT), gas adsorption porosimetry (LPNA), mercury porosimetry (MIP), helium and quasi-fluid pycnometry (Pycno. He, DryFlo). Each of the methods examined a different scope of the pore size, which enabled to achieve a full view of the porous nature of those rocks. We determined their porosity (open, closed, total), surface area as well as mean size and volume of the pores. Also, we studied the character and the pore size distribution from a few nm to a few mm. Comprehensive dolomite properties analyses showed that these rocks are characterised by high structural variability. They have mesopores and macropores but few micropores. The analyses presented in this paper are determined by a large petrographic diversity of the deposits containing dolomite. This article is an example of a comprehensive approach to the rock analysis in copper ore mines.     

PGE fractionation in seafloor hydrothermal systems: examples from mafic- and ultramafic-hosted hydrothermal fields at the slow-spreading Mid-Atlantic Ridge

The distribution of platinum group elements (PGEs) in massive sulfides and hematite–magnetite±pyrite assemblages from the recently discovered basalt-hosted Turtle Pits hydrothermal field and in massive sulfides from the ultramafic-hosted Logatchev vent field both on the Mid-Atlantic Ridge was studied and compared to that from selected ancient volcanic-hosted massive sulfide (VHMS) deposits. Cu-rich samples from black smoker chimneys of both vent fields are enriched in Pd and Rh (Pd up to 227 ppb and Rh up to 149 ppb) when compared to hematite–magnetite-rich samples from Turtle Pits (Pd up to 10 ppb, Rh up to 1.9 ppb). A significant positive correlation was established between Cu and Rh in sulfide samples from Turtle Pits. PGE chondrite-normalized patterns (with a positive Rh anomaly and Pd and Au enrichment), Pd/Pt and Pd/Au ratios close to global MORB, and high values of Pd/Ir and Pt/Ir ratios indicate mafic source rock and seawater involvement in the hydrothermal system at Turtle Pits. Similarly shaped PGE chondrite-normalized patterns and high values of Pd/Pt and Pd/Ir ratios in Cu-rich sulfides at Logatchev likely reflect a similar mechanism of PGE enrichment but with involvement of ultramafic source rocks.     

Flood-type trend analysis for alpine catchments

ABSTRACT

In many places, magnitudes and frequencies of floods are expected to increase due to climate change. To understand these changes better, trend analyses of historical data are helpful. However, traditional trend analyses do not address issues related to shifts in the relative contributions of rainfall versus snowmelt floods, or in the frequency of a particular flood type. We present a novel approach for quantifying such trends in time series of floods using a fuzzy decision tree for event classification and applied it to maximal annual and seasonal floods in 27 alpine catchments for the period 1980–2014. Trends in flood types were studied with Sen’s slope and double mass curves. Our results reveal a decreasing number of rain-on-snow and an increasing number of short rainfall events in all catchments, with flash floods increasing in smaller catchments. Overall, the results demonstrate the value of incorporating a fuzzy flood-type classification into flood trend analyses.     

Aquatic fungi growing on dead fragments of submerged plants

The authors investigated the dead fragments of 22 species of submerged plants in the water from three limnological and trophical different water bodies (spring, river and pond). A total of 184 species of aquatic fungi, including 119 zoosporic and 65 conidial species were found on the fragments investigated plants. The most common fungus species were Aphanomyces laevis, Saprolegnia litoralis, Pythium rostratum (zoosporic fungi) and Acrodictys elaeidicola, Anguillospora longissima, Angulospora aquatica, Lemonniera aquatica, Mirandina corticola, Tetracladium marchalianum, Tetracladium maxiliformis, Trinacrium subtile (conidial fungi).

Most fungus species were observed on the specimens of Elodea canadensis (33 fungus species), Hippuris vulgaris f. submersa (33), Myriophyllum spicatum (34) and Potamogeton crispus (33), fewest on Ceratophyllum demersum (24), Fontinalis dalicarlica and Potamogeton nitens (each 25).

The most fungi were growing in the water from River Supraśl (107), the fewest in the water from Pond Dojlidy (99). Some aquatic fungus species were observed in the water of only one of the three water bodies – in Pond Dojlidy (30), in Spring Jaroszówka (32) and in the River Supraśl (39) species. Seventy-five species growing only on fragments of single submerged plants. A number of zoosporic and conidial species (22 and four, respectively) appeared new to Polish waters. Out of these 119 zoosporic species, some are known as parasites or necrotrophs of fish.     

Vertical Structure in the Marine Atmospheric Boundary Layer and its Implication for the Inertial Dissipation Method

The structure of the marine atmospheric boundarylayer and the validity ofMonin–Obukhov similarity theory over the seahave been investigated using longterm measurements. Three levels of turbulencemeasurements (at 10 m, 18 mand 26 m) at Östergarnsholm in themiddle of the Baltic Sea have beenanalysed. The results show that turbulentparameters have a strong dependenceon the actual height due to wave influence.The wind profile and thus thenormalised wind gradient are very sensitiveto wave state. The lower part of theboundary layer can be divided into three heightlayers, a wave influenced layerclose to the surface, a transition layer andan undisturbed ordinary surfacelayer; the depth of the layers is determinedby the wave state. This heightstructure can, however, not be found for thenormalised dissipation, which is onlya function of the stability, except duringpronounced swell where the actualheight also has to be accounted for. Theresults have implications for the heightvariation of the turbulent kinetic energy(TKE) budget. Thus, the imbalancebetween production and dissipation willalso vary with height according to thevariation of wave state. This, in turn,will of course have strong implicationsfor the inertial dissipation method, inwhich a parameterisation of the TKEbudget is used.     

Consistent global responses of marine ecosystems to future climate change across the IPCC AR5 earth system models

Climate Dynamics - We analyze for the first time all 16 Coupled Model Intercomparison Project Phase 5 models with explicit marine ecological modules to identify the common mechanisms involved in...     

A three-tiered approach to participatory vulnerability assessment in the Solomon Islands

Greater recognition of the seriousness of global environmental change has led to an increase in research that assesses the vulnerability of households, communities and regions to changing environmental or economic conditions. So far, however, there has been relatively little attention given to how assessments can be conducted in ways that help build capacity for local communities to understand and find their own solutions to their problems. This paper reports on an approach that was designed and used to work with a local grass roots organization in the Solomon Islands to promote inclusivity and participation in decision-making and to build the capacity of the organization to reduce the vulnerability of communities to drivers of change. The process involved working collaboratively with the organization and training its members to conduct vulnerability assessments with communities using participatory and deliberative methods. To make best use of the learning opportunities provided by the research process, specific periods for formal reflection were incorporated for the three key stakeholders involved: the primary researchers; research assistants; and community members. Overall, the approach: (1) promoted learning about the current situation in Kahua and encouraged deeper analysis of problems; (2) built capacity for communities to manage the challenges they were facing; and (3) fostered local ownership and responsibility for problems and set precedents for future participation in decision-making. While the local organization and the communities it serves still face significant challenges, the research approach set the scene for greater local participation and effort to maintain and enhance livelihoods and wellbeing. The outcomes highlight the need for greater emphasis on embedding participatory approaches in vulnerability assessments for communities to benefit fully from the process.