Abundance and size distribution of transparent exopolymer particles (TEP) in a coccolithophorid bloom in the northern Bay of Biscay

The distribution of transparent exopolymer particles (TEP) was investigated during a coccolithophorid bloom in the northern Bay of Biscay (North Atlantic Ocean) in early June 2006. MODIS chlorophyll-a (Chl-a) and reflectance images before and during the cruise were used to localize areas of important biological activity and high reflectance (HR). TEP profiles along the continental margin, determined using microscopic (TEP_micro) and colorimetric (TEP_color) methods, showed abundant (6.1×10⁶–4.4×10⁷ L^?1) and relatively small (0.5–20 μm) particles, leading to a low total volume fraction (0.05–2.2 ppm) of TEP_micro and similar vertical profiles of TEP_color. Estimates of carbon content in TEP (TEP-C) derived from the microscopic approach yielded surface concentration of 1.50 μmol C L^?1. The contribution of TEP-C to particulate organic carbon (POC) was estimated to be 12% (molar C ratio) during this survey. Our results suggest that TEP formation is a probable first step to rapid and efficient export of C during declining coccolithophorid blooms.     

Simulated Antarctic precipitation and surface mass balance at the end of the twentieth and twenty-first centuries

The aim of this work is to assess potential future Antarctic surface mass balance changes, the underlying mechanisms, and the impact of these changes on global sea level. To this end, this paper presents simulations of the Antarctic climate for the end of the twentieth and twenty-first centuries. The simulations were carried out with a stretched-grid atmospheric general circulation model, allowing for high horizontal resolution (60 km) over Antarctica. It is found that the simulated present-day surface mass balance is skilful on continental scales. Errors on regional scales are moderate when observed sea surface conditions are used; more significant regional biases appear when sea surface conditions from a coupled model run are prescribed. The simulated Antarctic surface mass balance increases by 32 mm water equivalent per year in the next century, corresponding to a sea level decrease of 1.2 mm year⁻¹ by the end of the twenty-first century. This surface mass balance increase is largely due to precipitation changes, while changes in snow melt and turbulent latent surface fluxes are weak. The temperature increase leads to an increased moisture transport towards the interior of the continent because of the higher moisture holding capacity of warmer air, but changes in atmospheric dynamics, in particular off the Antarctic coast, regionally modulate this signal.     

The Chemical Evolution of the Universe on its Smallest Scales: Dust in Stars,Disks and Planets

D15 Dust and gas in the inner accretion disk around the Herbig star MWC 147 resolved with infrared spectro‐interferometry D21 The effective temperature of OGLE‐TR‐10 – The Balmer α line D29 Metal Injection into the Intracluster Medium D30 Eigenmodes of circumstellar dust shells D40 Numerical Modelling Approach of Circumstellar Dust Shells Around Pulsating AGB Stars Aiming at Multi Time Scale Processes D45 UV radiation induced CO molecule formation patterns in low density PDRs D46 IR properties of calcite and dolomite at low temperatures D47 Observations and Models of Dusty Giants – Past and Present D51 A multi‐method approach to the outer layers of AGB stars D53 On the convective energy transport in M‐type brown dwarf atmospheres D70 Structure and Dust Composition of the TW Hya Disc D75 Chemical Abundances in the Carina Dwarf Spheroidal Galaxy D76 Kinematic and chemical constraints on the formation of M31's inner halo structures D77 IR band profiles of silicate and oxide dust obtained by laboratory measurements of free‐flying particles D98 Dust particle growth in protoplanetary disks D134 Comparative study of dust cloud modelling for substellar atmospheres D137 Photometric study of neglected binary DV Psc D154 Quantitative Spectroscopy of Deneb D160 Hot subluminous Ostars from the SDSS D166 Simultaneous Observations of Solar Ca II H and Ca II 8662 lines and Numerical Simulation of these lines D182 Present‐day carbon abundances in the solar vicinity D189 Detection of a giant planet around a pulsating extreme horizontal branch star: the oldest known planet? D200 Confirmation of a very young binary brown dwarf candidate with disk in Chamaeleon D208 Galaxy ages and metallicities in the cluster A1314 D217 Charge‐dipole induced dust gelation – fastening the process of dust growth in protoplanetary disks D246 Protoplanetary Disk Structure and Evolution     

Mass-cargo-affine industries and climate change

The impact of low water periods on inland navigation and companies is well known by ship-operators and companies that rely on this mode of transport but it is rarely a topic of climate impact research. As climate change might affect the frequency and intensity of low water periods, quantifying the impact of climate change on companies and the effects of possible adaptation measures is vital. In this study, we present a model for quantifying the impact of low water events on companies which rely on inland navigation and apply that model to three anonymous iron and steel companies along the River Rhine. The deviation of optimal storage, the storage level that evens out risk vs. fixed capital, is used in the model to measure the vulnerability of companies. The results show that, depending on the climate scenario, the companies might have to deal with either one or five additional days of empty storage in the near future (2021–2050) and up to nine more days by the 2071–2100 period. Seasonal analysis shows that, consistent with the change in the river discharge, the biggest deviations from optimal storage level occur in the late summer/early autumn. Analysis of adaptation options shows that companies would need to increase storage capacity by 2.5 % for the 2021–2050 period, and by 25 % by the 2071–2100 period. A reduction of ship sizes is not an adaptation option for the three companies in this study, because these companies already use relatively small vessels. This is however an efficient adaptation option for companies which employ larger vessels for transport. Another adaptation option would be to reduce the share of transportation via inland waters, but the feasibility of this option depends on the availability and cost of other modes of transport.     

Sources of fluids and gases expelled at cold seeps offshore Georgia, eastern Black Sea

Four seep sites located within an ∼20 km² area offshore Georgia (Batumi seep area, Pechori Mound, Iberia Mound, and Colkheti Seep) show characteristic differences with respect to element concentrations, and oxygen, hydrogen, strontium, and chlorine isotope signatures in pore waters, as well as impregnation of sediments with petroleum and hydrocarbon potential. All seep sites have active gas seepage, near surface authigenic carbonates and gas hydrates. Cokheti Seep, Iberia Mound, and Pechori Mound are characterized by oil-stained sediments and gas seepage decoupled from deep fluid advection and bottom water intrusion induced by gas bubble release. Pechori Mound is further characterized by deep fluid advection of lower salinity pore fluids. The Pechori Mound pore fluids are altered by mineral/water reactions at elevated temperatures (between 60 and 110 °C) indicated by heavier oxygen and lighter chlorine isotope values, distinct Li and B enrichment, and K depletion. Strontium isotope ratios indicate that fluids originate from late Oligocene strata. This finding is supported by the occurrence of hydrocarbon impregnations within the sediments. Furthermore, light hydrocarbons and high molecular weight impregnates indicate a predominant thermogenic origin for the gas and oil at Pechori Mound, Iberia Mound, and Colkheti Seep. C₁₅₊ hydrocarbons at the oil seeps are allochtonous, whereas those at the Batumi seep area are autochthonous. The presence of oleanane, an angiosperm biomarker, suggests that the hydrocarbon source rocks belong to the Maikopian Formation. In summary, all investigated seep sites show a high hydrocarbon potential and hydrocarbons of Iberia Mound, Colkheti Seep, and Pechori Mound are predominantly of thermogenic origin. However, only at the latter seep site advection of deep pore fluids is indicated.     

Use of sedimentary diatoms from multiple lakes to distinguish between past changes in trophic state and climate: evidence for climate change in northern Germany during the past 5,000 years

Fossil diatoms from lake sediments have been used to infer both past trophic state and climate conditions. In Europe, climate reconstructions focused on northern and alpine regions because these areas are climatically sensitive and anthropogenic impact was low. In contrast, anthropogenic impact was often high in the central European lowlands, such as northern Germany, beginning in the Neolithic Age, ~3700 BC. Since that time, trophic state change was the main factor that affected diatom assemblages in central European lowland lakes. Therefore, it was considered difficult or impossible to identify climate changes in the region using sedimented diatoms. We used diatom assemblage changes, diatom-inferred total phosphorus concentrations and the relative abundance of planktonic diatoms from sediments of three lakes that differ in their location, size, morphology, catchment area and current trophic state to test whether we could distinguish between trophic state and climate signals over the past 5,000 years in northern Germany. In this study, changes in trophic state and climate were well differentiated. In the study lakes, relative abundance of planktonic diatoms seems to be linked to the length of lake mixing phases. Planktonic diatom abundance decreased during years with shorter mixing duration, and these shorter mixing times probably reflect colder winters. The diatom-inferred periods of short mixing phases from 1000 BC to AD 500 and from AD 1300 to 1800 coincide well with two known cooling phases in Europe and the North Atlantic region.     

The MEMIN research unit: Scaling impact cratering experiments in porous sandstones

Abstract– The MEMIN research unit (Multidisciplinary Experimental and Modeling Impact research Network) is focused on analyzing experimental impact craters and experimental cratering processes in geological materials. MEMIN is interested in understanding how porosity and pore space saturation influence the cratering process. Here, we present results of a series of impact experiments into porous wet and dry sandstone targets. Steel, iron meteorite, and aluminum projectiles ranging in size from 2.5 to 12 mm were accelerated to velocities of 2.5–7.8 km s^?1, yielding craters with diameters between 3.9 and 40 cm. Results show that the target’s porosity reduces crater volumes and cratering efficiency relative to nonporous rocks. Saturation of pore space with water to 50% and 90% increasingly counteracts the effects of porosity, leading to larger but flatter craters. Spallation becomes more dominant in larger‐scale experiments and leads to an increase in cratering efficiency with increasing projectile size for constant impact velocities. The volume of spalled material is estimated using parabolic fits to the crater morphology, yielding approximations of the transient crater volume. For impacts at the same velocity these transient craters show a constant cratering efficiency that is not affected by projectile size.     

Hydrogeochemical and multi-tracer investigations of arsenic-affected aquifers in semi-arid West Africa

The semi-arid Sahel regions of West Africa rely heavily on groundwater from shallow to moderately deep(100 m b.g.l.)crystalline bedrock aquifers for drinking water production.Groundwater quality may be affected by high geogenic arsenic(As)concentrations(10μg/L)stemming from the oxidation of sulphide minerals(pyrite,arsenopyrite)in mineralised zones.These aquifers are still little investigated,especially concerning groundwater residence times and the influence of the annual monsoon season on groundwater chemistry.To gain insights on the temporal aspects of As contamination,we have used isotope tracers(noble gases,~3H,stable water isotopes(~2 H,~(18)O))and performed hydrochemical analyses on groundwater abstracted from tube wells and dug wells in a small study area in southwestern Burkina Faso.Results revealed a great variability in groundwater properties(e.g.redox conditions,As concentrations,water level,residence time)over spatial scales of only a few hundred metres,characteristic of the highly heterogeneous fractured underground.Elevated As levels are found in oxic groundwater of circum-neutral pH and show little relation with any of the measured parameters.Arsenic concentrations are relatively stable over the course of the year,with little effect seen by the monsoon.Groundwater residence time does not seem to have an influence on As concentrations,as elevated As can be found both in groundwater with short(50 a)and long(10~3 a)residence times as indicated by ~3He/~4He ratios spanning three orders of magnitude.These results support the hypothesis that the proximity to mineralised zones is the most crucial factor controlling As concentrations in the observed redox/pH conditions.The existence of very old water portions with residence times10~3 years already at depths of50 m b.g.l.is a new finding for the shallow fractured bedrock aquifers of Burkina Faso,suggesting that overexploitation of these relatively low-yielding aquifers may be an issue in the future.     

Major and trace element geochemistry of superficial sediments and suspended particulate matter of shallow saline lakes in Eastern Austria

General geochemical parameters of water, superficial sediments, and suspended particulate matter (SPM) were determined from small shallow saline lakes (soda ponds) as well as from lake Neusiedlersee in eastern Austria. Additionally, instrumental neutron activation analysis (INAA) was used to determine the distribution of major, rare earth and other trace elements in superficial sediments and SPM. Chemical results show remarkable differences in salinity and ionic strength between the investigated ponds. Anthropogenic effects, such as drawdown of ground water level and a loss of lake water due to drainage, are clearly reflected in obtained chemical and geological data. Due to a strong dependence of the complexation and scavenging behavior of the rare earth elements (REE) on ionic strength, a significant difference between REE concentrations in soda ponds with different anthropogenic impact was found. The content and composition of authigenic evaporitic minerals in superficial sediments and SPM clearly differ with a fluctuating water level and salt concentration. Furthermore, we determined the distribution of major and trace elements in superficial sediments of a nearby fluvial system. Our results show a clear correlation between REE superficial sediment concentrations in anthropogenically degraded soda ponds and fluvial system. Therefore, we assume that REE concentrations of sediments and SPM are suitable for the study of geochemical changes of inland saline lakes due to anthropogenic impacts on water balance.