What is the Parent of CH in the Coma of Comet C/1995 O1 (Hale-Bopp)?

The ratio of CH₄/CO in comets is an important indicator of the region of their formation. However, it is difficult to measure the quantity of CH⁺. The Giotto Ion Mass Spectrometer experiment observed a quantity of CH⁺ which seemed inconsistent with the amount of CH⁺. Thus, it was proposed that a source of the CH⁺ was a distributed source in the dust. We tested this hypothesis by observing the CH emission strength in comet Hale-Bopp as a function of dustiness. We see no strong correlation between the dust and the gas. Thus, for Hale-Bopp,dust is unlikely to be a dominant source of CH. This revised version was published online in July 2006 with corrections to the Cover Date.     

The influence of flushing rates, terrestrial input and low salmon escapement densities on paleolimnological reconstructions of sockeye salmon (Oncorhynchus nerka) nutrient dynamics in Alaska and British Columbia

Recent advances in paleolimnology have enabled reconstructions of past sockeye salmon (Oncorhynchus nerka) dynamics using a number of proxy-indicators, including diatoms and stable isotopes. Thus far, studies have focused on nursery lakes with high escapement densities and low flushing rates, ensuring that levels of salmon-derived nutrients (SDN) are high and are incorporated into the food chain. This study examines three oligotrophic sockeye salmon nursery lakes in Alaska (Afognak and Saltery lakes) and British Columbia (Hobiton Lake) to determine if sockeye salmon populations can be tracked in nursery systems with lower salmon escapement densities, higher flushing rates and/or higher terrestrial input. We adopted a multi-proxy approach using diatoms, stable isotopes (¹⁵N), organic carbon to nitrogen (C/N) ratios and pollen to draw inferences from ²¹⁰Pb-dated sediment cores. ¹⁵N showed little response to historic variation in sockeye salmon populations, even in Saltery Lake, which has a very high escapement density, and in Afognak Lake, in which average escapement is known to have increased. Dilution effects due to high flushing rates were likely partly responsible for the low ¹⁵N and minimal variation throughout the cores, although very high terrestrial input in Hobiton Lake also dampened the salmon signal. Small changes in diatom species assemblages, however, were evident in all three lakes and may be in response to fluctuating loads of salmon-derived nutrients. Most notably, increases of mesotrophic diatom taxa, such as Asterionella formosa and Aulacoseira subarctica, corresponded to increased salmon production in Alaskan lakes as a result of enhancement (fertilization) activities and climatic changes. Changes in the relative abundance of Cyclotella pseudostelligera in Hobiton Lake may also be in response to a significant decline in sockeye salmon populations off the west coast of Vancouver Island in the 1970s. Other factors, however, such as logging and lake fertilization may also have influenced diatom species composition. These results confirm that, while salmon-derived nutrients may be of key importance in juvenile salmonid development in some lakes, this may not be the case in all systems, especially those in which flushing rates are high. Further, in these systems, diatom communities appear to respond more sensitively to fluctuations in salmon populations (and therefore nutrients) than stable isotope methods, provided that other changes in trophic status are minor.     

Longitudinal variability of methane and ammonia bands on jupiter: II. Temporal variations

A set of spectra was obtained of the Jovian Equatorial Zone central meridian 6190 Å CH₄ and 6450 Å NH₃ bands in February 1980, a year after the data reported by W.D. Cochran and A.L. Cochran ((1980) Icarus42, 102–110). These new data confirm the results of the previous study, and also permit a search for temporal, as well as longitudinal, variability of these molecular absorption bands. The new data set shows a correlation of NH₃ and CH₄ equivalent widths, as well as a lack of any strong correlation of red continuum reflectivity with equivalent width. These trends were also exhibited by the 1979 data. Longitude regions of larger or smaller than average equivalent width seem still to be evident a year later, with some slight drift in longitude. An increase in the average CH₄ and NH₃ equivalent width over the entire planet was detected during the one year interval. This is easily understood as the result of a global decrease in the mean altitude of the NH₃ cloud.     

New chronological and geochemical constraints on the genesis and geological evolution of Ponza and Palmarola Volcanic Islands (Tyrrhenian Sea, Italy)

A new geochronological and geochemical study of the volcanic rocks of the Ponza and Palmarola Islands, Pontine Archipelago, has been carried out. This archipelago is located along the boundary between the Italian continental shelf and the opening Tyrrhenian basin. It is a key area to study volcanism related to the opening of the Tyrrhenian Sea. Ponza is the oldest felsic magmatic manifestation in the central Tyrrhenian area. Previous studies suggested that Ponza volcanic activity began before 5 Ma. Twenty-five new K–Ar ages constrain the volcanic activity (rhyolitic hyaloclastites and dykes) to the last 4.2 Ma, with two episodes of quiescence between 3.7 and 3.2 Ma and between 2.9 and 1.0 Ma. A new volcanic episode dated at 3.2–2.9 Ma has been identified on the central and southern Ponza, with emplacement of pyroclastic units. At 1.0 Ma, a trachytic episode ended the volcanic activity. The near island of Palmarola exhibits rhyolitic hyaloclastites and domes dated between 1.6 and 1.5 Ma, indicating that the island was entirely built during the Early Pleistocene in a short span of time of ca. 120 ka. Although only 6–8 km apart, the two islands display significantly different geochemical signatures. Ponza rhyolites show major and trace element compositions representative of orogenic magmas of subduction/collision zones: high-K calc-alkaline and metaluminous rhyolites (Agpaitic Index [AI] and Alumina Saturation Index [ASI] <1), high LILE/HFSE (Th/Ta=16–21) and LREE/HFSE ratios (La/Nb>3), and Nb–Ta negative anomalies. In Palmarola, the orogenic character is also present, but much less marked than in Ponza: rhyolites have a peralkaline character (AI>1), lower LILE/HFSE (Th/Ta=11–15), low LREE/HFSE ratios (La/Nb=1–2) close to those of anorogenic lavas, and the Nb–Ta negative anomalies are almost absent. Y/Nb ratios indicate different magmatic sources, one similar to island-arc or active continental margin basalts for Ponza rhyolites, and the others probably involving an OIB type component for Palmarola rhyolites and Ponza trachytes. Palmarola volcanics represent a transitional magmatism: although a preserved collisional geochemical imprint, they show geochemical features approaching those of anorogenic lavas erupted in a within-plate context. The change of magmatism evidenced in this study can be related to the tectonic evolution of the area. Indeed, Hf, Ta and Rb contents suggest that the oldest Pliocene rhyolites of Ponza would emplace in a syn- to late-collisional setting, while the younger Pleistocene rhyolites of Palmarola would be emplaced in a post-collisional setting in which the orogenic character (Th/Ta) decreases and mantle influence (Nb/Ta) increases. Geochemical modeling strongly suggests that the Palmarola rhyolites represent the waning stages of a subduction-related magmatism. The K–Ar datings allow us to estimate precisely the transition of magmatism to last less than 1.3 Ma. The transitional magmas may be the result of the upwelling of asthenospheric mantle inducing melting of a metasomatized lithospheric mantle and the mixing between these two sources. This upwelling could occur during the extension of the Tyrrhenian basin, caused by the slab retreat and steepening, or during a process of slab break-off starting in the Pliocene.     

Understanding carbon trading: Effects of delegating CO2 responsibility on organizations’ trading behaviour

The establishment of a carbon market assumes that there is an effective means of transforming price information into technical carbon reduction measures. However, empirical evidence reveals that the links between price information and carbon management strategies are far from obvious. To understand how delegating CO₂ responsibility affects CO₂ trading behaviour, this article proposes a neo-institutionalist approach to answering the question of why companies became sellers, buyers or a combination of both during phase I of the European Emissions Trading Scheme (EU ETS). Original data from a survey on companies that participated in this scheme were collected and analysed. It was assumed that the trading scheme offered two ways to delegate decisions regarding emissions trading: decoupling from technical knowledge and financialization (i.e. delegating to financial departments) or coupling using technicalization (i.e. delegating to manufacturing departments). The results support the hypothesis that a company that adopts a decoupling strategy is more likely to buy certificates to fulfil their emissions targets. Adopting a coupling strategy indicates that a company is more likely to become a seller, all else equal. Professional identity is the theoretical basis for this relationship. Delegating carbon management to different departments represents either a stronger coupling or a stronger decoupling from core technological processes.

Policy relevance

The transaction data from phase I of the EU ETS open new questions and possibilities regarding the reasons that drive selling and buying in companies. It is important to look not only at the traditional sources of transaction costs, but rather also at the reasons for these tensions. One important source is the professional education of the people in charge of the EU ETS. Tailored information that directly addresses the different professional backgrounds of managers working in both financial departments and more technical departments might help to lower these types of transaction costs. In today's context, important emitter countries, such as China and Korea, have launched their own emissions markets, copying many aspects of the EU ETS. For the positive development of these markets and as a way of establishing a global emissions market, these new schemes should learn from the EU ETS experience.     

Assessing physical vulnerability in large cities exposed to flash floods and debris flows: the case of Arequipa (Peru)

Understanding the physical vulnerability of buildings and infrastructure to natural hazards is an essential step in risk assessment for large cities. We have interpreted high spatial resolution images, conducted field surveys, and utilized numerical simulations, in order to assess vulnerability across Arequipa, south Peru, close to the active El Misti volcano. The emphasis of this study was on flash floods and volcanic or non-volcanic hyperconcentrated flows, which recur on average every 3.5 years across the city. We utilized a geographic information system to embed vulnerability and hazard maps as a step to calculate risk for buildings and bridges along the Río Chili valley and two tributaries. A survey of ~1,000 buildings from 46 city blocks, different in age, construction materials, and land usage, provided architectural and structural characteristics. A similar survey of twenty bridges across the three valleys was based on structural, hydraulic, and strategic parameters. Interpretation of high spatial resolution (HSR) satellite images, which allows for quick identification of approximately 69 % of the structural building types, effectively supplemented field data collection. Mapping vulnerability has led us to pinpoint strategic areas in case of future destructive floods or flows. Calculated vulnerability is high if we examine structural criteria alone. We further consider physical setting with the most vulnerable city blocks located on the lowermost terraces, perpendicular or oblique to the flow path. Statistical analysis conducted on 3,015 city blocks, considering nine criteria identified from HSR images, indicated that building-type heterogeneity and the shape of the city blocks, along with building and street network density, are the most discriminant parameters for assessing vulnerability.     

Echyridella menziesii (Bivalvia: Hyriidae) as a predator of zooplankton of different sizes; are large non-indigenous Daphnia a potential food source?

Interactions between two recent invaders to New Zealand, the cladocerans Daphnia galeata and D. pulex, and native filter-feeding freshwater mussels, are unknown. We examined predation rates of the common native mussel Echyridella menziesii (kākahi, kāeo) on non-native Daphnia (comparatively large zooplankton in New Zealand), relative to two common native species, the smaller cladoceran Bosmina meridionalis and rotifer Brachionus calyciflorus. Controlled laboratory experiments were conducted in which each zooplankton species was exposed to bivalve predation for a two-hour period. Comparing treatments to non-mussel controls, removal rates of non-indigenous D. pulex and native B. calyciflorus were statistically significant. Nevertheless, kākahi removal rates may not be ecologically significant for daphnids (1.7% D. galeata and 7.4% D. pulex). Kākahi removed 8.8% of B. meridionalis and 30.2% of B. calyciflorus, suggesting that small, feeble zooplankton species (particularly rotifers) are most susceptible to predation, and potentially function as an energy source for native freshwater mussels.