Probabilistic risk assessment of common booster biocides in surface waters of the harbours of Gran Canaria (Spain)

The presence of booster biocides in the aquatic environment has been associated with a risk to non-target species due to their proven toxicity. The aim of the present study was to determine the spatial and temporal distribution of common booster biocides in different harbours of the island of Gran Canaria (Spain) and evaluate, by means of a probabilistic risk assessment (PRA), the ecological risk posed by these compounds. With these objectives, a monitoring campaign was conducted between January 2008 and May 2009, collecting a total of 182 seawater samples. Four common booster biocides (TCMTB, diuron, Irgarol 1051 and dichlofluanid) were monitored. Diuron levels ranged between 2.3 and 203 ng/L and Irgarol 1051 between 2.4 and 146.5 ng/L. The ecological risk associated with these levels was always low, however, with probabilities of exceeding the 10th percentile of autotroph toxicity below 3.5%.     

SLA–chlorophyll-a variability and covariability in the Algero-Provençal Basin (1997–2007) through combined use of EOF and wavelet analysis of satellite data

Data reduction and signal decomposition techniques have been applied to a large bio-physical remotely sensed dataset covering the decade 1997–2007. The aim was the estimation of the spatial (basin and sub-basin scales) and temporal (seasonal and interannual) variability of sea level anomalies and chlorophyll-a concentration in the Algero-Provençal Basin, as well as the study of their covariability. Empirical orthogonal functions, wavelet analysis, singular value decomposition and correlation maps have been successfully used to individuate the patterns of (co)variability of the investigated fields. The seasonal variability of the phytoplanktonic biomass is divided in two distinct modes, timewise and spacewise separated. Positive interannual events are related to anomalies in 1999 and 2005, while the main (negative) anomaly is that of summer 2003, associated to the European 2003 heatwave. The analysis of the sea level anomalies shows a minimum in the formation of anticyclonic Algerian eddies during that period. The largest anticorrelation between sea level anomalies and phytoplanktonic biomass is found in the central zone of the basin, suggesting a clear biological response to the shoaling/deepening of the isopycnae and so to the nutrient injection into the euphotic layer. The analysis suggests that the driver of the variability of the nutricline depth in this central area is the displacement (seasonal) of the North Balearic Front and the formation/action of the frontal eddies.     

Polymorphism of As4S3 (tris-(μ2-sulfido)-tetra-arsenic): accurate structure refinement on natural α- and β-dimorphites and inferred room temperature thermodynamic properties

An accurate structure refinement, using single-crystal X-ray diffraction data, on natural α- and β-dimorphites collected at Solfatara di Pozzuoli, in the Phlegraean Fields, near Naples and at Vesuvius (Italy) is reported. Theoretical calculations at various levels of sophistication have been used to calculate molecular vibrational frequencies and gas-phase specific heats, to analyze the crystal packing, and to estimate lattice energies of both phases. All computational methods contribute to demonstrate that the β-phase is the thermodynamically stable one at room temperature.     

Fluid flow and pore pressure development throughout the evolution of a trough mouth fan,western Barents Sea

Using a combination of geophysical and geotechnical data from Storfjorden Trough Mouth Fan off southern Svalbard, we investigate the hydrogeology of the continental margin and how this is affected by Quaternary glacial advances and retreats over the continental shelf. The geotechnical results show that plumites, deposited during the deglaciation, have high porosities, permeabilities and compressibilities with respect to glacigenic debris flows and tills. These results together with margin stratigraphic models obtained from seismic reflection data were used as input for numerical finite element models to understand focusing of interstitial fluids on glaciated continental margins. The modelled evolution of the Storfjorden TMF shows that tills formed on the shelf following the onset of glacial sedimentation (ca. 1.5 Ma) acted as aquitards and therefore played a significant role in decreasing the vertical fluid flow towards the sea floor and diverting it towards the slope. The model shows that high overpressure ratios (up to λ ca. 0.6) developed below the shelf edge and on the middle slope. A more detailed model for the last 220 kyrs accounting for ice loading during glacial maxima shows that the formation of these aquitards on the shelf focused fluid flow towards the most permeable plumite sediments on the slope. The less permeable glacigenic debris flows that were deposited during glacial maxima on the slope hinder fluid evacuation from plumites allowing high overpressure ratios (up to λ ca. 0.7) to develop in the shallowest plumite layers. These high overpressures likely persist to the Present and are a critical precondition for submarine slope failure.     

Community structure of infaunal macrobenthos around vestimentiferan thickets at the San Clemente cold seep,NE Pacific

The San Clemente cold seep lies within 100–200 km of other reducing habitats in the NE Pacific, offering an opportunity to compare diversity and species overlap among reducing habitats (i.e. whale‐, kelp‐, and wood‐falls) at similar depths within a single region. Video observations from the research submersible Alvin at the San Clemente seep (1800 m depth) indicated clumps (‘thickets’) of vestimentiferans distributed as meter‐scale patches interspersed with vesicomyid clam beds and black sediments. Sediment‐core samples were collected at distances of 0 to 80–200 m along randomly oriented transects radiating outward from vestimentiferan thickets to evaluate changes in macrofaunal community structure from thickets into the background community. Macrofaunal abundance was elevated at distances of 0–1 m compared to 80–200 m (i.e. the ‘background’ community). The tube‐building frenulate worms Siboglinum spp., along with peracarid crustaceans, dominated sediments within 1 m of vestimentiferan thickets. Species diversity was depressed within 1 m of thickets but with high rates of species accumulation, suggesting that seep sites greatly increase sediment heterogeneity and facilitate colonization by non‐background macrofaunal species. Stable isotope data indicate chemosynthetic nutrition for some dominant macrofaunal species within 1 m of tubeworm thickets. The macrofaunal community near vestimentiferan thickets in San Clemente seep contains intermediate levels of species richness and diversity compared to other deep‐sea seep areas in the northeast Pacific. There was low species overlap between the San Clemente seep macrofauna and communities in reducing habitats near wood‐, whale‐, and kelp‐falls at similar depths within the region, suggesting that seeps harbor a distinct infaunal community.     

Low reproductive success for copepods during a bloom of the non‐aldehyde‐producing diatom Cerataulina pelagica in the North Adriatic Sea

Egg production rates and/or hatching success in the copepods Acartia clausi, Calanus helgolandicus and Temora longicornis were negatively affected by a late spring (May–June 2003) phytoplankton bloom in the North Adriatic Sea, dominated mainly by the large diatom Cerataulina pelagica. Highest total concentrations of 3.3·10⁴ cells·ml^?1 were located in the vicinity of the Po River, which also corresponded to the area where the highest numbers of phaeophorbides were measured (0.779, 0.528 and 0.419 μg·l^?1, respectively, compared to an average of the remaining stations of 0.183 ± 0.049 SD), suggesting some grazing on the bloom. Phytoplankton biomass in terms of carbon was dominated by diatoms, representing on average 42% of total phytoplankton carbon and more than 80% at several stations. Cerataulina pelagica, Cyclotella spp., Chaetoceros spp. and small unidentified centric diatoms dominated the diatom community numerically but C. pelagica was by far the dominant diatom in terms of carbon due to its large cell size. This species represented more than 60% of the diatom biomass at nine of the 14 stations sampled, and was absent only at one station, which was the most offshore station sampled during the cruise. Although polyunsaturated aldehydes (PUAs) were not detected, other oxylipins which are hydroxy and keto derivatives of eicosapentaenoic and docosahexaenoic acids that affect copepod reproduction were found in these samples. Hence, we can attribute the negative impact of diatoms not only to PUAs, as previously believed, but also to these compounds. This is the first direct evidence of the presence of oxylipins other than PUAs in marine blooms dominated by diatoms.     

Conjugate Points in the Gravitational n-Body Problem

In an effort to understand the nature of almost periodic orbits in the n-body problem (for all time t) we look first to the more basic question of the oscillatory nature of solutions of this problem (on a half-line, usually taken as R ⁺). Intimately related to this is the notion of a conjugate point(due to A. Wintner) of a solution. Specifically, by rewriting the mass unrestricted general problem of n-bodies in a symmetric form we prove that in the gravitational Newtonian n-body problem with collisionless motions there exists arbitrarily large conjugate points in the case of arbitrary (positive) masses whenever the cube of the reciprocal of at least one of the mutual distances is not integrable at infinity. The implication of this result is that there are possibly many Wintner oscillatorysolutions in these cases (some of which may or may not be almost periodic). As a consequence, we obtain sufficient conditions for all continuable solutions (to infinity) to be either unbounded or to allow for near misses (at infinity). The results also apply to potentials other than Newtonian ones. Our techniques are drawn from results in systems oscillation theory and are applicable to more general situations. Dedicated to the memory of Robert M. (Bob) Kauffman, formerly Professor of the University of Alabama in Birmingham