Helium-uranium dating of corals from Middle Pleistocene Barbados reef tracts

By He-U dating of corals from elevated Pleistocene reef tracts on Barbados, we have extended back to the Middle Pleistocene the high sea stand chronology previously deduced by Th²³⁰-U dating. Six samples from the first major reef tract complex older than the 200,000-yr complex gave ages of 350,000 ± 25,000 yr B.P. Two corals from the crest of Second High Cliff, an unusually large escarpment occurring approximately midway in the terrace sequence, gave concordant ages of 480,000 and 500,000 yr. Unrecrystallized corals from older reefs gave ages ranging back to 650,000 yr.The results date episodes of high sea stands at 350,000 and 500,000 yr B.P.     

Place Meanings and Participatory Planning Intentions

Interest in integrating human connections and natural areas into resource management decision making has steadily increased. While efforts to validate place meaning dimensions have identified meanings beyond established place dependence and identity concepts, further research to identify tangible and intangible meanings of nature-based recreation areas is needed. This study sought to examine place meanings as a second-order construct consisting of ecological integrity, economic dependency, place dependence, family identity, community identity, and place identity and to determine the influence of place meanings on participatory planning intentions (PPI). Data were collected from Florida Fish and Wildlife Conservation area visitors. Confirmatory factor analysis revealed that six factors were reliable and valid, representing place meanings as an overarching concept. Structural equation modeling showed a significant association between place meanings and PPI. These findings demonstrated the importance of understanding place meanings that influence behavioral intentions, which is relevant to understanding participation in planning processes.     

Carbon isotopic fractionation between CO2 vapour,silicate and carbonate melts: an experimental study to 30 kbar

The carbon isotopic fractionation between CO₂ vapour and sodamelilite (NaCaAlSi₂O₇) melt over a range of pressures and temperatures has been investigated using solid-media piston-cylinder high pressure apparatus. Ag₂C₂O₄ was the source of CO₂ and experimental oxygen fugacity was buffered at hematite-magnetite by the double capsule technique. The abundance and isotopic composition of carbon dissolved in sodamelilite (SM) glass were determined by stepped heating and the ¹³C of coexisting vapour was determined directly by capsule piercing. CO₂ solubility in SM displays a complex behavior with temperature. At pressures up to 10 kbars CO₂ dissolves in SM to form carbonate ion complexes and the solubility data suggest slight negative temperature dependence. Above 20 kbars CO₂ reacts with SM to form immiscible Na-rich silicate and Ca-rich carbonate melts and CO₂ solubility in Na-enriched silicate melt rises with increasing temperature above the liquidus. Measured values for carbon isotopic fractionation between CO₂ vapour and carbonate ions dissoived in sodamelilite melt at 1200°–1400° C and 5–30 kbars average 2.4±0.2, favouring¹³C enrichment in CO₂ vapour. The results are maxima and are independent of pressure and temperature. Similar values of 2 are obtained for the carbon isotopic fractionation between CO₂ vapour and carbonate melts at 1300°–1400° C and 20–30 kbars.     

A late Lake Minong transgression in the Lake Superior basin as documented by sediments from Fenton Lake, Ontario

The evolution of the early Great Lakes was driven by changing ice sheet geometry, meltwater influx, variable climate, and isostatic rebound. Unfortunately none of these factors are fully understood. Sediment cores from Fenton Lake and other sites in the Lake Superior basin have been used to document constantly falling water levels in glacial Lake Minong between 9,000 and 10,600 cal (8.1–9.5 ka) BP. Over three meters of previously unrecovered sediment from Fenton Lake detail a more complex lake level history than formerly realized, and consists of an early regression, transgression, and final regression. The initial regression is documented by a transition from gray, clayey silt to black sapropelic silt. The transgression is recorded by an abrupt return to gray sand and silt, and dates between 9,000 and 9,500 cal (8.1–8.6 ka) BP. The transgression could be the result of increased discharge from Lake Agassiz overflow or the Laurentide Ice Sheet, and hydraulic damming at the Lake Minong outlet. Alternatively ice advance in northern Ontario may have blocked an unrecognized low level northern outlet to glacial Lake Ojibway, which switched Lake Minong overflow back to the Lake Huron basin and raised lake levels. Multiple sites in the Lake Huron and Michigan basins suggest increased meltwater discharges occurred around the time of the transgression in Lake Minong, suggesting a possible linkage. The final regression in Fenton Lake is documented by a return to black sapropelic silt, which coincides with varve cessation in the Superior basin when Lake Agassiz overflow and glacial meltwater was diverted to glacial Lake Ojibway in northern Ontario.     

Improved magnetic anomalies of the Antarctic lithosphere from satellite and near-surface data

The Antarctic magnetic anomaly map compiled marine and airborne surveys collected south of 60°S through 1999 and used Magsat data to help fill in the regional gaps between the surveys. Ørsted and CHAMP satellite magnetic observations with greatly improved measurement accuracies and temporal and spatial coverage of the Antarctic, have now supplanted the Magsat data. We combined the new satellite observations with the near-surface survey data for an improved magnetic anomaly map of the Antarctic lithosphere. Specifically, we separated the crustal from the core and external field components in the satellite data using crustal thickness variations estimated from the terrain and the satellite-derived free-air gravity observations. Regional gaps in the near-surface surveys were then filled with predictions from crustal magnetization models that jointly satisfied the near-surface and satellite crustal anomalies. Comparisons in some of the regional gaps that also considered newly acquired aeromagnetic data demonstrated the enhanced anomaly estimation capabilities of the predictions over those from conventional minimum curvature and spherical harmonic geomagnetic field models. We also noted that the growing number of regional and world magnetic survey compilations involve coverage gaps where these procedures can contribute effective near-surface crustal anomaly estimates.     

Post-Palaeozoic evolution of weathered landsurfaces in Uganda by tectonically controlled deep weathering and stripping

A model for the evolution of weathered landsurfaces in Uganda is developed using available geotectonic, climatic, sedimentological and chronological data. The model demonstrates the pivotal role of tectonic uplift in inducing cycles of stripping, and tectonic quiescence for cycles of deep weathering. It is able to account for the development of key landforms, such as inselbergs and duricrust-capped plateaux, which previous hypotheses of landscape evolution that are based on climatic or eustatic controls are unable to explain. Development of the Ugandan landscape is traced back to the Permian. Following late Palaeozoic glaciation, a trend towards warmer and more humid climates through the Mesozoic enabled deep weathering of the Jurassic/mid-Cretaceous surface in Uganda during a period of prolonged tectonic quiescence. Uplift associated with the opening South Atlantic Ocean terminated this cycle and instigated a cycle of stripping between the mid-Cretaceous and early Miocene. Deep weathering on the succeeding Miocene to recent (African) surface has occurred from Miocene to present but has been interrupted in the areas adjacent to the western rift where development of a new drainage base level has prompted cycles of stripping in the Miocene and Pleistocene.     

Heavy metal contamination of an arid river environment: Gruben River, Namibia

The dispersal of metalliferous pollution from several spoil heaps produced during 20th century copper mining in the Gruben River valley, Namibia is examined. The Gruben River flows through an extremely arid environment with an average rainfall of ˜25 mm p.a. The potential for physical and chemical remobilisation of Cu, Zn and Ni is assessed by examining the spatial and temporal distribution of metal-contaminated sediment deposited within the confines of the channel. The relationships between metal content, grain size, geomorphic environment and the downstream distribution of metals are discussed. The phase-specific heavy metal concentrations of sediments, collected as part of the downstream sampling programme, are also examined using progressively more aggressive sequential acid extractions. In addition, metal concentrations are compared with Dutch guidelines for soil contamination to ascertain the extent of environmental risk.Total metal concentrations show that the Gruben valley is highly contaminated, particularly with respect to Cu and Ni concentrations, which exceed Dutch target values for Cu (36 ppm) in 94.7% and Ni (35 ppm) in 90.5% of samples, respectively. Zn concentrations are much lower with only 6.3% of the samples exceeding the target value (140 ppm). As might be expected, the metal–sediment concentrations of Cu are the most highly elevated, with a peak value of 10,500 ppm being recorded from material collected from suspended sediment transported during a minor flow event that occurred in March 1999. Lower energy and fine-grained sedimentary environments are shown to be clearly associated with higher metal concentrations. Sequential extractions of metals show that of the three principal elements considered in this study, only a negligible proportion of Cu (0.41%) is held in the exchangeable phase. Ni and Zn were below detection limits. Although the total metal concentrations in the Gruben River valley sediments are extremely high and are in themselves a concern, the small percentage of metals held in the exchangeable phase and the low potential for remobilisation under the arid conditions would suggest that they pose only a minor risk to the environment.     

World Cities in the Pacific Rim: A New Global Test of Regional Coherence

A new evaluation of the Pacific Rim concept is presented. The originality of this test for regional coherence is to be found in the basic units being analysed: cities instead of states. Based on a theoretical framework that identifies world city and world city network formation in terms of the office networks of advanced producer service firms, we use a principal components analysis to analyse a data set of 28 Pacific Rim cities and 46 global service firms. This identifies five main groupings of cities in terms of similar mixes of corporate service firms: a western Rim group; a group of ‘old Commonwealth’ cities; a market communist group of cities; Tokyo as a global city; and US cities as a specific separate group. These results confirm numerous earlier studies that were sceptical of the existence of a coherent Pacific Rim region. However, the particular approach adopted here allows us to identify the Pacific Rim generically as a particularly pernicious construct. We conclude that the Pacific Rim is a geographical chaotic conception.