Chemical analyses of campbell Island fresh waters

Ten samples of freshwater from Campbell Island were analysed for their main ionic constituents. All show a preponderance of sodium and chloride derived from sea water. Potassium, calcium, and magnesium gave slightly higher concentrations than would be expected if derived solely from sea water. It is con‐eluded that the excess potassium is derived from the underlying rocks and soil, and the excess calcium and magnesium from the sea by fractionation into salt particles.     

Devolution, the governance of regional development and the Trade Union Congress in the North East region of England

The devolution and regionalisation of political and administrative structures following the election of New Labour in 1997 have changed the nature of the state and territorial development and governance in the UK. A regional and sub-national tier has opened up within the existing multi-layered governance system operating at the supra-national, national and local scales. This ‘new institutional space’ is increasingly open to the participation of social institutions--including trade unions--in economic and social governance. Drawing upon empirical analysis of the experience of the Northern Trade Union Congress (NTUC) in the North East region of England, the paper argues that the NTUC--in contrast to its national organisation--is beginning to engage with the emergent institutional structures but its role is inhibited by the centralised strategy and structure of the TUC nationally, its own need for upgrading, capacity building and greater financial resources and the interaction between the North East’s particular legacy of tripartite corporatism and the more pluralist modes of regional development governance emerging in the English regions. Unless such issues are addressed regional trade union centres--such as the NTUC--risk remaining relatively junior partners in the emergent regional governance structures.     

Oxygen compounds in Titan's stratosphere as observed by Cassini CIRS

We have investigated the abundances of Titan's stratospheric oxygen compounds using 0.5 cm⁻¹ resolution spectra from the Composite Infrared Spectrometer on the Cassini orbiter. The CO abundance was derived for several observations of far-infrared nadir spectra, taken at a range of latitudes (75° S-35° N) and emission angles (0°-60°), using rotational lines that have not been analysed before the arrival of Cassini at Saturn. The derived volume mixing ratios for the different observations are mutually consistent regardless of latitude. The weighted mean CO volume mixing ratio is 47±8 ppm if CO is assumed to be uniform with latitude. H₂O could not be detected and an upper limit of 0.9 ppb was determined. CO₂ abundances derived from mid-infrared nadir spectra show no significant latitudinal variations, with typical values of 16±2 ppb. Mid-infrared limb spectra at 55° S were used to constrain the vertical profile of CO₂ for the first time. A vertical CO₂ profile that is constant above the condensation level at a volume mixing ratio of 15 ppb reproduces the limb spectra very well below 200 km. This is consistent with the long chemical lifetime of CO₂ in Titan's stratosphere. Above 200 km the CO₂ volume mixing ratio is not well constrained and an increase with altitude cannot be ruled out there.     

Submerged early Holocene coastal and terrestrial landforms on the inner shelves of Atlantic Canada

Coastal and terrestrial landforms that formed with lowered relative sea levels during the early postglacial period in Atlantic Canada were submerged during the Holocene transgression. However, these landforms are seldom seen on sea floor imagery. Factors that contribute to their destruction include the brevity of sea level lowstands and high wave energy on shallow modern shelves. We identify one situation within which preservation has been relatively good: large coastal lakes that existed for many thousands of years before being connected to the ocean by rising sea level in the mid-Holocene. We describe Bedford Basin, near Halifax, Nova Scotia, and deal more exhaustively with the Bras d'Or Lakes, an inland sea in Cape Breton, Nova Scotia. The preservation of shore platforms, barrier beaches and spits, and fluvial systems, was due to the rapid onset of the transgression and the relatively low wave energy in the subsequent marine phases. The well-preserved early Holocene coastlines are highly favourable targets in the search for evidence of human occupation in the early- to mid-Holocene.     

Road Reduction Filtering for GPS-GIS Navigation

A novel method of map matching using the Global Positioning System (GPS) has been developed for civilian use, which uses digital mapping data to infer the systematic position errors of less than 100m which result largely from 'selective availability' (S/A) imposed by the US military. Selective availability was switched off on the 2nd of May 2000, and is to be replaced with 'regional denial capabilities in lieu of global degradation'. The system tracks a vehicle on all possible roads (road centre-lines) in a computed error region, then uses a method of rapidly detecting inappropriate road centre-lines from the set of all those possible. This is called the Road Reduction Filter (RRF) algorithm. Point positioning is computed using C/A code pseudorange measurements direct from a GPS receiver. The least squares estimation is performed in the software developed for the experiment described in this paper. Virtual differential GPS (VDGPS) corrections are computed and used from a vehicle's previous positions, thus providing an autonomous alternative to DGPS for in-car navigation and fleet management. Height aiding is used to augment the solution and reduce the number of satellites required for a position solution. Ordnance Survey (OS) digital map data was used for the experiment, i.e. OSCAR 1 m resolution road centre-line geometry and Land Form PANORAMA 1:50,000, 50 m-grid digital terrain model (DTM). Testing of the algorithm is reported and results are analysed. Vehicle positions provided by RRF are compared with the 'true' position determined using high precision (cm) GPS carrier phase techniques. It is shown that height aiding using a DTM and the RRF significantly improve the accuracy of position provided by inexpensive single frequency GPS receivers.     

Distance least squares modelling of the cubic sodalite structure and of the thermal expansion of Na8(Al6Si6O24)I2

The Distance Least Squares (DLS) structure modelling technique is used to determine the room-temperature structures of the sodalites Li₈(Al₆Si₆O₂₄)Cl₂, Na₈(Al₆Si₆O₂₄)Cl₂, K₈(Al₆Si₆O₂₄)Cl₂, Na₈(Al₆Si₆O₂₄)Br₂, and Na₈(Al₆Si₆O₂₄)I₂. The technique is also used to calculate the thermal expansion behaviour of Na₈(Al₆Si₆O₂₄)I₂ assuming that the discontinuity in its thermal expansion curve occurred either when the ideal fully-expanded state was achieved (case 1) or when the x-coordinate of the sodium atom became 0.25 (case 2). The results are given as plots of bond lengths and bond angles as a function of temperature. Case 2 was preferred and analysis of the results implied that the driving force for the untwisting of the partially-collapsed sodalite framework was in the framework bonds with the cavity ion bonds resisting the untwisting. Best estimates indicate that the expansion of the Na-O and Na-I bonds are 9% and 27.4% respectively, between room temperature and 810° C, and there is an apparent shortening of the framework bond distances of about 1.5%.     

A macroscale analysis of coastal steepening around the coast of England and Wales

Coastal steepening potentially presents an array of management issues in the form of financial implications of sea defence degradation, increased risk posed to the hinterland as wave attenuation is reduced, 'coastal squeeze' and statutory requirements in the light of the Habitats Directive. The extent to which coastal steepening has occurred throughout England and Wales has been investigated through use of a GIS and dataset based on historical Ordnance Survey map information. Data were collected along 1084 selected profile lines, positioned so as to be geomorphologically representative of the coast. Features recorded from each map year included the positions of mean high water (MHW) and mean low water (MLW), the relative movements of which infer changing intertidal gradients. The results presented in this paper are on a subject and scale not previously published. It is revealed that 61% of the coastline studied has experienced a tendency towards steepening. Of the remainder, 33% has flattened, and 6% has experienced no rotational movement. This tendency towards steepening has been the dominant movement on each of the west, south, and east coasts.     

Vertical profiles of HCN, HC3N, and C2H2 in Titan's atmosphere derived from Cassini/CIRS data

Mid-infrared limb spectra in the range 600-1400 cm⁻¹ taken with the Composite InfraRed Spectrometer (CIRS) on-board the Cassini spacecraft were used to determine vertical profiles of HCN, HC₃N, C₂H₂, and temperature in Titan's atmosphere. Both high (0.5 cm⁻¹) and low (13.5 cm⁻¹) spectral resolution data were used. The 0.5 cm⁻¹ data gave profiles at four latitudes and the 13.5 cm⁻¹ data gave almost complete latitudinal coverage of the atmosphere. Both datasets were found to be consistent with each other. High temperatures in the upper stratosphere and mesosphere were observed at Titan's northern winter pole and were attributed to adiabatic heating in the subsiding branch of a meridional circulation cell. On the other hand, the lower stratosphere was much colder in the north than at the equator, which can be explained by the lack of solar radiation and increased IR emission from volatile enriched air. HC₃N had a vertical profile consistent with previous ground based observations at southern and equatorial latitudes, but was massively enriched near the north pole. This can also be explained in terms of subsidence at the winter pole. A boundary observed at 60° N between enriched and un-enriched air is consistent with a confining polar vortex at 60° N and HC₃N's short lifetime. In the far north, layers were observed in the HC₃N profile that were reminiscent of haze layers observed by Cassini's imaging cameras. HCN was also enriched over the north pole, which gives further evidence for subsidence. However, the atmospheric cross section obtained from 13.5 cm⁻¹ data indicated a HCN enriched layer at 200-250 km, extending into the southern hemisphere. This could be interpreted as advection of polar enriched air towards the south by a meridional circulation cell. This is observed for HCN but not for HC₃N due to HCN's longer photochemical lifetime. C₂H₂ appears to have a uniform abundance with altitude and is not significantly enriched in the north. This is consistent with observations from previous CIRS analysis that show increased abundances of nitriles and hydrocarbons but not C₂H₂ towards the north pole.