Kornerupine parageneses in whiteschists and other magnesian rocks: is kornerupine + talc a high-pressure assemblage equivalent to tourmaline + orthoamphibole?

Kornerupine, (□,Fe,Mg)(Mg,Fe,Al)₉(Si,Al,B)₅ (O,OH,F)₂₂, has been reported with talc in rocks from six localities worldwide, but only at Chilapila Hill in the Lufilian Arc, Zambia do textural relationships imply that kornerupine (Krn) equilibrated with talc (Tlc) during a prograde metamorphic event at T≈ 640 °C, P≈ 13 kbar; a prograde Krn + Tlc assemblage has also been reported from Mautia Hill, Tanzania (P ≤ 13 kbar). In order to estimate possible constraints on the stability range for the kornerupine + talc paragenesis in nature, we constructed a P-T diagram in the model system MgO-Al₂O₃-SiO₂-H₂O (MASH) for seven phases quartz (Qtz), B-free kornerupine sensu stricto, anthophyllite (Ath), chlorite (Chl), cordierite (Crd), kyanite (Ky), and talc. The minimum pressure for Krn + Tlc + Ky stability in MASH is close to that for Ky + Tlc stability, i.e., 6–8 kbar, at T≤ 780 °C. However, in the natural system, B₂O₃ and Na₂O are major constituents in Krn and orthoamphibole (Oam), respectively, and dravitic tourmaline (Tur) is widespread. The critical assemblage alternative to Krn + Tlc in nature is Tur + Oam. The upper pressure limit of Tur + Ath is determined by the upper pressure for anthophyllite: 7.7–10.5 kbar at 682–794 °C in the MgO-SiO₂-H₂O system (Chernosky et al. 1985, Am Mineral 70:223–236), and is undoubtedly higher in the presence of Na₂O, CaO, and Al₂O₃. At three of the six localities, talc is a retrograde phase; nonetheless, it possibly equilibrated with kornerupine on the retrograde path or during a later metamorphic event at P-T conditions appropriate for Ky + Tlc. At the sixth locality (Mulvoj, southwestern Pamir Mountains, Tajikistan), Krn is found in the same thin section as talc and kyanite and all three minerals formed during a prograde metamorphic event at T≥ 650 °C, P near 7 kbar. However, Krn is restricted to a lens 4 to 6 mm thick of phlogopite + anthophyllite + Tur and it does not touch either talc or kyanite. A reaction relating the Mulvoj and Chilapila Hill (Krn + Tlc + Ky + Qtz + Tur) parageneses is calculated from compositions in the Mulvoj rock to be 0.40Tur + 2.55Ath + 1.33H₂O + 0.27F = Krn + 2.16Tlc + 0.36B₂O₃ + 0.02Rutile + 0.19Na₂O + 0.17CaO. Given the difference in metamorphic pressures estimated for Mulvoj and Chilapila Hill, Krn + Tlc is inferred to be favored by increasing pressure as well as by low Na₂O and CaO contents. Some FeO, F, Fe₂O₃, and BeO are present in measurable amounts in at least one of the phases in the Mulvoj and Chilapila Hill whiteschists (e.g., Krn contains 0.24–0.67 wt% BeO), but the effect of these constituents is subordinate to that of Na₂O, CaO and B₂O₃. The Krn + Tlc could be a more important assemblage in B-bearing whiteschists than has been reported to date, particularly at pressures where orthoamphibole is no longer stable. Received: 21 April 1997 / Accepted: 13 October 1997     

The radiocarbon budget for Mono Lake: an unsolved mystery

Since 1957 the ¹⁴C/C ratio of the dissolved inorganic carbon in Mono Lake has risen by about 60‰. The magnitude of this increase is about four times larger than that expected from the invasion of bomb-produced¹⁴C from the atmosphere. We have eliminated the following explanations: (1) measurement error, (2) an unusually high physical exchange rate for non-reactive gases, (3) inorganic enhancement of the CO₂ exchange rate, and (4) biological enhancement of the CO₂ exchange rate. Clandestine disposal of waste radiocarbon remains a dark-horse explanation.In the course of our investigations we have uncovered evidence for at least one episodic input of radiocarbon-free carbon to the lake over the last 1000 years. We speculate that this injection was related to a hydrothermal event resulting from sublacustrine volcanic activity.     

森林生态服务市场的开发

<正> 森林提供许多有价值的生态服务,诸如保护流域和生物多样性以及贮存碳素等,现已引起企业、政府乃至个人越来越多的关注,同时人们也意识到随着森林这些功能的退化甚至丧失所带来的危险和代价。这种退化既能引起洪水、山崩之类的局部灾难,也会导致全球气候变化之类的广泛影响。     

A Cromerian Complex stalagmite from the Mendip Hills,England

In order to provide a better chronological constraint on a British Middle Pleistocene interglacial, a large stalagmite boss from the Mendip Hills was selected for palaeoclimate data using pollen analysis. Dating analyses by thermal ionisation mass spectrometry (TIMS) of uranium–thorium ratios and by magnetostratigraphy constrain the age of the sample to 450–780 ka. The isotopic consistency of the TIMS analyses, plus the presence of luminescence laminations, suggest that the sample has been preserved under closed-system conditions. Pollen assemblages have been recovered from the speleothems, despite the fact that the pH of calcite deposition is usually greater than 7. Furthermore the evidence presented here indicates that the pollen was probably transported by the speleothem feedwater, rather than entering the cave aerially. The pollen record contained within the stalagmite is interpreted as early–mid-interglacial but does not have clear Cromerian affinity. © 1997 John Wiley & Sons, Ltd.     

Organic carbon fluxes of a glacier surface: A case study of Foxfonna,a small Arctic glacier

Arctic glaciers are rapidly responding to global warming by releasing organic carbon (OC) to downstream ecosystems. The glacier surface is arguably the most biologically active and biodiverse glacial habitat and therefore the site of important OC transformation and storage, although rates and magnitudes are poorly constrained. In this paper, we present measurements of OC fluxes associated with atmospheric deposition, ice melt, biological growth, fluvial transport and storage (in superimposed ice and cryoconite debris) for a supraglacial catchment on Foxfonna glacier, Svalbard (Norway), across two consecutive years. We found that in general atmospheric OC input (averaging 0.63 ± 0.25 Mg a^-1 total organic carbon, i.e. TOC, and 0.40 ± 0.22 Mg a^-1 dissolved organic carbon, i.e. DOC) exceeded fluvial OC export (0.46 ± 0.04 Mg a^-1 TOC and 0.36 ± 0.03 Mg a^-1 DOC). Early in the summer, OC was mobilised in snowmelt but its release was delayed by temporary storage in superimposed ice on the glacier surface. This delayed the export of 28.5% of the TOC in runoff. Biological production in cryoconite deposits was a negligible potential source of OC to runoff, while englacial ice melt was far more important on account of the glacier's negative ice mass balance (–0.89 and –0.42 m a^-1 in 2011 and 2012, respectively). However, construction of a detailed OC budget using these fluxes shows an excess of inputs over outputs, resulting in a net retention of OC on the glacier surface at a rate that would require c. 3 years to account for the OC stored as cryoconite debris. © 2018 John Wiley & Sons, Ltd.     

U-Pb and Pb-Pb apatite ages for Antarctic achondrite Graves Nunataks 06129

The Antarctic achondrite Graves Nunataks 06128 (GRA 06128) and Graves Nunataks 06129 (GRA 06129) represent a unique high-temperature, nonbasaltic magmatism in the early solar system. These objects have been interpreted as products of low-degree partial melting of volatile-rich chondritic material, which may have been the asteroid parent bodies of brachinite. Previous studies have investigated their crystallization and metamorphic history with various isotope systematics. Here, we report the U-Pb intercept age of 4466 ± 29 Ma and the weighted-average ²⁰⁷Pb-²⁰⁶Pb age of 4460 ± 30 Ma for the Cl-apatite grains from GRA 06129. Our apatite ages are obviously younger than that of the ²⁶Al-²⁶Mg model age (4565.9 ± 0.3 Ma; Shearer et al. 2010a ), but are the same as the ⁴⁰Ar-³⁹Ar age obtained via step-heating of the bulk rock (4460 ± 28 Ma; Fernandes and Shearer 2010 ; Shearer et al. 2010a ). Based on petrographic observations, merrillites are usually rimmed by apatite and exist as inclusions in apatite. Therefore, the apatite U-Pb age from GRA 06129 probably records a metamorphic event of replacing merrillite with apatite, caused by Cl-rich melts or fluids on their parent body. A collisional event has provided the impact heating for this metamorphic event. Increasing amounts of geochronologic evidence show that the giant impact of the Moon-forming event has affected the asteroid belt at 4450–4470 Ma (Bogard and Garrison 2009 ; Popova et al. 2013 ; Yin et al. 2014 ; Zhang et al. 2016 ). Considering the contemporary metamorphic events for GRA 06129 (4460 ± 30 Ma), it is likely that the asteroid parent body of GRA 06129 was also affected by the same giant impact as the Moon-forming event.     

新型双船起重拆除平台试验研究

拆除大型海上结构物是一项非常复杂且充满挑战的工程。现提出一种新型海上平台拆除方案,该方案利用三条半潜船来代替具有重型起重装置的单一船舶,通过两艘相同的半潜船将平台上层建筑托起,随后运至第三艘半潜船上完成平台拆除。在风浪流作用下,半潜船和平台的所处方位和运动姿态一直处于动态变化中,这对船舶调节压载的稳定性以及双船运动的同步性提出了要求。为了确保该方案的高效性和安全性,设计了一套完整的模型试验装置,包括船舶模型、平台拆卸辅助设备、六自由度运动采集与分析系统、控制系统、无线通讯系统以及测量系统。开展了相应的水池试验,试验结果验证了双船起重拆除平台方案中双船协同运输这一关键环节的可行性和安全性。     

Influence of vegetation cover on sand transport by wind: field studies at Owens Lake,California

Field studies conducted at Owens Lake, California, provide direct measurements of sand flux on sand sheets with zero to 20 per cent cover of salt grass. Results from 12 different sand transport events show that aerodynamic roughness length and threshold wind shear velocity increase with vegetation cover as measured by vertically projected cover and roughness density (λ). This results in a negative exponential decrease in sediment flux with increasing vegetation cover such that sand transport is effectively eliminated when the vertically projected cover of salt grass is greater than 15 per cent. A general empirical model for the relation between sand flux and vegetation cover has been derived and can be used to predict the amount of vegetation required to stabilize sand dune areas. © 1998 John Wiley & Sons, Ltd.     

Soil water movement and nutrient cycling in semi-arid rangeland: vegetation change and system resilience

Recent decades have seen rapid intensification of cattle production in semi-arid savannah ecosystems, increasingly on formalized ranch blocks. As a result, vegetation community changes have occurred, notably bush encroachment (increased bush dominance) in intensively grazed areas. The exact causes of this vegetation change remain widely debated. Previous studies have suggested: (i) increased leaching of water and nutrients into the subsoil in intensively grazed areas provides deeper rooting bush species with a competitive advantage for soil water and nutrients, and (ii) nutrient leaching may be exacerbated by nutrient inputs from cattle dung and urine. Our research in the Eastern Kalahari showed that in infertile sandy soils both the magnitude of soil water and concentration of soil nutrients leached into the subsoil is largely unaffected by the ecological and biochemical effects of increased cattle use. We found that despite the high soil hydraulic conductivity ( &greaterno;12 cm h⁻¹), relatively high subsoil moisture contents and the restriction of water movement to matrix flow pathways prevent leaching losses beyond the rooting zone of savannah grass species. No significant differences in patterns of soil water redistribution were noted between bush dominant and grass dominant sites. We also found that the low nutrient status of Kalahari soils and leachate movement as matrix flow combine to allow nutrient adsorption on to soil particles. Nutrient adsorption ensures that nitrogen and phosphorus cycling remains topsoil dominated even following the removal of vegetation and direct nutrient inputs in cattle dung and urine. This conclusion refutes environmental change models that portray increases in the leaching of soil water and available nitrogen as a major factor causing bush encroachment. This provides a possible explanation for the now widely cited, but hitherto unexplained, resilience of dryland soils. We suggest that infertile sandy soils appear resilient to changes in soil water distribution and nutrient availability caused by increased cattle use. Hence, soil characteristics contribute to the resilience to permanent ecological change that is increasingly recognized as an attribute of semi-arid rangelands. © 1998 John Wiley & Sons, Ltd.