Grain alignment in dense interstellar environments: spectropolarimetry of the 4.67-μm CO-ice feature in the field star Elias 16 (Taurus dark cloud)

We present spectropolarimetry of the solid CO feature at 4.67 μm along the line of sight to Elias 16, a field star background to the Taurus dark cloud. A clear increase in polarization is observed across the feature with the peak of polarization shifted in wavelength relative to the peak of absorption. This shows that dust grains in dense, cold environments (temperatures ∼20 K or less) can align and produce polarization by dichroic absorption. For a grain model, consisting of a core with a single mantle, the polarization feature is best modelled by a thick CO mantle, possibly including 10 per cent water-ice, with the volume ratio of mantle to bare grain of ∼5. Radiative torques could be responsible for the grain alignment provided the grain radius is at least 0.5 μm. This would require the grain cores to have a radius of at least 0.3 μm, much larger than grain sizes in the diffuse interstellar medium. Sizes of this order seem reasonable on the basis of independent evidence for grain growth by coagulation, as well as mantle formation, inside dense clouds.     

Thoracican cirripedes (Crustacea) from the Hauterivian (Lower Cretaceous) of Hannover,northern Germany

Diverse thoracican cirripedes from the Hauterivian of the Hannover district of northern Germany are described, including seven species, belonging to five genera. Of these, a new genus belonging to the Scalpellidae, Jaegerscalpellum, includes one Hauterivian species, J. elegans sp. nov., an Aptian species, J. comptum (Withers, 1910) and an Albian species, J. politum (Darwin, 1851) are also referred to it. A new Cretiscalpellum, C. mutterlosei sp. nov. is described from the Hauterivian, and C. matrioni sp. nov. is described from the Middle Albian of France. The oldest record of the Unilatera Gale, 2018, Pedupycnolepas pulcher sp. nov. is described from the Hauterivian; this displays typical shell structure of the group, retained by living Verrucidae. Finally, four species of Zeugmatolepadidae, subfamily Martillepadinae, are recorded from the Hauterivian, including Martillepas hausmanni (Koch and Dunker, 1836), M. decoratus sp. nov., M. auriculum sp. nov. and Etcheslaepas borealis (Collins, 1990). The Hauterivian fauna from Hannover shows affinities both with Late Jurassic and later Cretaceous (Aptian-Cenomanian) forms, and includes the earliest scalpellids, unilateran (Pedupycnolepas) and Cretiscalpellum species known. It constrains the age of the Cretaceous cirripede evolutionary radiation to the earliest Cretaceous.     

Near‐surface hydraulic conductivity of northern hemisphere glaciers

The hydrology of near‐surface glacier ice remains a neglected aspect of glacier hydrology despite its role in modulating meltwater delivery to downstream environments. To elucidate the hydrological characteristics of this near‐surface glacial weathering crust, we describe the design and operation of a capacitance‐based piezometer that enables rapid, economical deployment across multiple sites and provides an accurate, high‐resolution record of near‐surface water‐level fluctuations. Piezometers were employed at 10 northern hemisphere glaciers, and through the application of standard bail–recharge techniques, we derive hydraulic conductivity (K) values from 0.003 to 3.519 m day^?1, with a mean of 0.185 ± 0.019 m day^?1. These results are comparable to those obtained in other discrete studies of glacier near‐surface ice, and for firn, and indicate that the weathering crust represents a hydrologically inefficient aquifer. Hydraulic conductivity correlated positively with water table height but negatively with altitude and cumulative short‐wave radiation since the last synoptic period of either negative air temperatures or turbulent energy flux dominance. The large range of K observed suggests complex interactions between meteorological influences and differences arising from variability in ice structure and crystallography. Our data demonstrate a greater complexity of near‐surface ice hydrology than hitherto appreciated and support the notion that the weathering crust can regulate the supraglacial discharge response to melt production. The conductivities reported here, coupled with typical supraglacial channel spacing, suggest that meltwater can be retained within the weathering crust for at least several days. Not only does this have implications for the accuracy of predictive meltwater run‐off models, but we also argue for biogeochemical processes and transfers that are strongly conditioned by water residence time and the efficacy of the cascade of sediments, impurities, microbes, and nutrients to downstream ecosystems. Because continued atmospheric warming will incur rising snowline elevations and glacier thinning, the supraglacial hydrological system may assume greater importance in many mountainous regions, and consequently, detailing weathering crust hydraulics represents a research priority because the flow path it represents remains poorly constrained.     

Climate change adaptation of coffee production in space and time

Savannas constitute the most fire-prone vegetation type on earth and are a significant source of greenhouse gas emissions. Most savanna fires are lit by people for a variety of livelihood applications. ‘Savanna burning’ is an accountable activity under the Kyoto Protocol, but only Australia, as a developed economy, accounts for emissions from this source in its national accounts. Over the past decade considerable effort has been given to developing savanna burning projects in northern Australia, combining customary indigenous (Aboriginal) approaches to landscape-scale fire management with development of scientifically robust emissions accounting methodologies. Formal acceptance by the Australian Government of that methodology, and its inclusion in Australia’s developing emissions trading scheme, paves the way for Aboriginal people to commercially benefit from savanna burning projects. The paper first describes this Australian experience, and then explores options for implementing community-based savanna burning emissions reduction projects in other continental savanna settings, specifically in Namibia and Venezuela. These latter examples illustrate that savanna fire management approaches potentially have broader application for contributing to livelihood opportunities in other fire-prone savanna regions.     

Tertiary Tsondab Sandstone Formation: preliminary bedform reconstruction and comparison to modern Namib Sand Sea dunes

The Tertiary Tsondab Sandstone Formation, which underlies much of the present Namib Sand Sea, is a key element in understanding the Cenozoic evolution of the Namib Desert. Outcrops of the aeolian facies of the Tsondab Sandstone at Elim and Diep Rivier consist of two sequences of bioturbated cross-strata separated by likely formation-scale surfaces of stabilisation. Cross-strata consist of scalloped sets about 200 m in width and separated by southeast dipping bounding surfaces. Internally, sets contain reactivation surfaces of probable seasonal origin. The north to south-southeast dipping foresets define crescent shapes with a trough axis trending northeast. Although additional data are needed to define the Tsondab bedform, the outcrop data is best satisfied in computer simulations by north trending, east migrating main bedforms, which had relatively large and slow-moving dunes superimposed upon their eastern flanks and migrated to the north. Foresets dipping to the south to south-southwest at Elim suggest that superimposed dunes also occurred on the western flanks of the main bedform and migrated to the south, but that their record was largely lost with net eastward migration of the main bedform. This preliminary Tsondab model shares attributes such as trend, scale of cross-strata, and presence of scalloped sets with reactivation surfaces with computer models of the modern linear dunes in which large-scale sinuosity migrates alongcrest to the north. Differences emerge in the overall set architecture and the orientation of cross-strata and bounding surfaces, as well as the degree of vegetation that must have characterised Tsondab dunes.     

The Water Budget Myth and Its Recharge Controversy: Linear vs. Nonlinear Models

The water budget myth, which is the idea that safe pumping must not exceed the initial recharge, gave rise to a controversy about the role of recharge in assessing the sustainability of groundwater development. To refute the concept of safe yield, a simplified water budget equation is used, which equals the total pumping rate to the sum of capture and storage change. Since initial recharge and discharge are canceled out from this equation, it is concluded that sustainable pumping has nothing to do with recharge. Investigating the assumptions underlying this equation, it is seen that it expresses the superposition principle, which implicitly assumes the groundwater reservoir can be depleted indefinitely and boundary conditions are an infinite source of water. To evaluate sustainability, however, the limits of the aquifer system must be examined accurately. Theoretically, this can only be accomplished applying nonlinear models, in which case setting up the simplified water budget equation is impossible without knowing the initial conditions. Hence, excluding recharge when assessing sustainable pumping may not be done inconsiderately, which is illustrated by two examples. An analytical solution, developed by Ernst in 1971 to simulate flow to a well in a polder area with a nonlinear function for drainage, even shows that it is not necessarily a misconception to assume the cone of depression stops expanding when the pumping rate is balanced by the infiltration rate.     

Long-Term Evaluation of Mulch Biowall Performance to Treat Chlorinated Solvents

Permeable reactive barriers (PRBs), such as mulch biowalls, have been installed at numerous groundwater cleanup sites, and laboratory and field studies have demonstrated biotic and abiotic processes that degrade chlorinated volatile organic compounds (CVOCs) in groundwater passing through these engineered remedies. However, the longevity of mulch biowalls remains a fundamental research question. Soil and groundwater sampling at seven mulch biowalls at Altus Air Force Base (AFB) approximately 10 years after installation demonstrated the ongoing degradation of CVOCs. Trichloroethene was not detected in five of seven groundwater samples collected from the biowall despite upgradient detections above federal drinking water standards. Microbial sampling established the presence of key dechlorinating bacteria and the abundance of genes encoding specific enzymes for degradation, high methane concentrations, low sulfate concentrations, and negative oxidation-reduction potential, all indicative of highly reducing conditions within the biowalls and favorable conditions for CVOC destruction via microbial reductive dechlorination. High cellulose content (>79%) of the mulch, elevated total organic carbon (TOC) content in groundwater, and elevated potentially bioavailable organic carbon (PBOC) measurements in soil samples further supports an ongoing, long-lived source of carbon. These results demonstrate the ongoing and long-term efficacy of the mulch biowalls at Altus AFB. In addition, concentrations of bacteria, TOC, PBOC, and other geochemical parameters suggest a modest impact of the biowalls downgradient. The continued presence of CVOCs downgradient may be attributable to back diffusion from low-permeability shale. However, the biowalls continue to provide benefits by removing CVOCs in groundwater, thus reducing further CVOC loading to the downgradient, low-permeability strata.     

SEAWAT‐Based Simulation of Axisymmetric Heat Transport

Simulation of heat transport has its applications in geothermal exploitation of aquifers and the analysis of temperature dependent chemical reactions. Under homogeneous conditions and in the absence of a regional hydraulic gradient, groundwater flow and heat transport from or to a well exhibit radial symmetry, and governing equations are reduced by one dimension (1D) which increases computational efficiency importantly. Solute transport codes can simulate heat transport and input parameters may be modified such that the Cartesian geometry can handle radial flow. In this article, SEAWAT is evaluated as simulator for heat transport under radial flow conditions. The 1971, 1D analytical solution of Gelhar and Collins is used to compare axisymmetric transport with retardation (i.e., as a result of thermal equilibrium between fluid and solid) and a large diffusion (conduction). It is shown that an axisymmetric simulation compares well with a fully three dimensional (3D) simulation of an aquifer thermal energy storage systems. The influence of grid discretization, solver parameters, and advection solution is illustrated. Because of the high diffusion to simulate conduction, convergence criterion for heat transport must be set much smaller (10^?10) than for solute transport (10^?6). Grid discretization should be considered carefully, in particular the subdivision of the screen interval. On the other hand, different methods to calculate the pumping or injection rate distribution over different nodes of a multilayer well lead to small differences only.     

On‐Site Vapor‐Phase Analysis as a Novel Approach for Monitoring Groundwater Wells

The results of comprehensive field testing of on‐site vapor‐phase‐based groundwater monitoring methods are presented to demonstrate their utility as a robust and cost‐effective approach for rapidly obtaining volatile organic compounds (VOCs) concentration data from a monitoring well. These methods—which rely on sensitive, commercially available field equipment to analyze vapor in equilibrium with groundwater—proved easy to implement and can be tailored to site‐specific needs, including multilevel sampling. During field testing, low‐flow groundwater concentrations could be reasonably estimated using submerged passive vapor diffusion samplers or field equilibration of collected groundwater (R² = 0.85 to 0.96). These two methods are not as reliant on in‐well mixing to overcome vertical stratification within wells as simpler headspace methods. The importance of well and aquifer‐specific factors on concentration data (and therefore method selection) is highlighted, including the effect of changing in‐well patterns due to seasonal temperature gradients. Results indicated that vertical stratification was relatively limited within the set of wells included in these studies, resulting in similar performance for short depth‐discrete passive vapor diffusion samplers (constructed from 40‐mL vials) and longer samplers (2.5 to 5 feet in length) designed to cover a larger portion of the screened interval. A year‐long, multi‐event evaluation demonstrated that vapor‐phase‐based monitoring methods are no more variable than conventional groundwater monitoring methods, with both types subject to similar spatial and temporal variability that can be difficult to reduce. Vapor sampling methods represent a promising approach for estimation of groundwater concentrations by reducing the cost liabilities associated with monitoring while providing a more sustainable approach.     

Pfiesteria shumwayae (Pfiesteriaceae) in New Zealand

Pfiesteria shumwayae Steidinger et Burkholder is now known to be present in New Zealand and occurs in estuaries around the country. The presence of Pfiesteria was initially determined by a polymerase chain reaction (PCR)‐based detection assay, using oligonucleotide primers targeted at ribosomal DNA extracted from estuarine water and sediments. Presence was confirmed by isolation from fresh sediments in the presence offish (Oreochromis mossambicus), followed by identification by scanning electron microscopy. The New Zealand isolates of P. shumwayae were ichthyotoxic in bioassays, but there is no historic evidence offish kills in New Zealand associated with the dinoflagellate.