Recent increase in atmospheric deposition of mercury to California aquatic systems inferred from a 300-year geochronological assessment of lake sediments

Age-dated sediment cores from 4 remote lakes across California were analyzed for total Hg (Hg_T) concentration as a function of pre- and post-industrialization. Particle size, magnetic susceptibility and organic C and N, were measured to determine if the Hg concentration in sediment cores could be related to atmospheric deposition and/or watershed processes. Results indicate that (a) for each lake modern (1970–2004) Hg_T lake sediment concentrations have increased by an average factor of 5 times more than historic (pre-1850) Hg_T concentrations; (b) the ratio of modern to pre-industrial lake sediment Hg_T for these lakes are higher than estimated for other locations where atmospheric deposition is presumed to be the main source of Hg; (c) 2 of the 4 studied lakes demonstrated significant relationships between Hg_T concentrations and percentage organic material (r² = 0.68 and p < 0.01; r² = 0.67 and p < 0.01) whereas the other two indicated no significant relationship (r² = 0.05 and p = 0.51; r² = 0.12 and p = 0.36).     

Devonian lacustrine shore zone architecture: Giving perspective to cliff exposures with ground penetrating radar

Lake margin sedimentary systems have been the subject of only limited study. The cyclic Middle Devonian lacustrine succession of Northern Scotland contains repeated developments of shore zone sandstones and thus provides an ideal location for the study of these units. The cycles comprise deep lake, shallow lake, playa and shore zone facies. Detailed field observations are presented alongside ground penetrating radar data which has aided large‐scale and three‐dimensional characterization of the shore zone sand bodies. Loading and discrete channel forms are recognized in thin‐bedded sandstones within the lower portion of the lake shore zone successions. Up‐section, the sandstone beds appear to become amalgamated, forming subtle low angle accretionary bar complexes. Where imaged on the radar profiles, the repeated development of shoreward migrating features succeeded by more shallow angled lakeward accreting surfaces is recognized; these are ascribed to washover and swash–backwash processes, respectively. The orientation of these features is similar to palaeocurrent measurements from oscillation ripples, suggesting an alignment of the shore zone bars perpendicular to the prevailing wind direction. Further loaded sandstone beds and sand‐filled shallow channel features overlie the bar forms. The context of the shore zone facies allows the controls on its formation to be examined. The shore zone sandstones overlie playa facies which contain abundant desiccation horizons, reflecting the most arid phase in the climatically controlled lacustrine cycle. As climatic conditions ameliorated, the rejuvenation of fluvial systems resulted in the transport of sand out into the basin. Initial deposition was limited to intermittent events where sediment was laid down on a water‐saturated substrate. High resolution fluctuations in lake level resulted in periodic short‐lived reworking events along the lake margins which produced amalgamated sands, forming low relief bars. Shore zone reworking is likely to have occurred over a wide  area as the lake margin migrated back and forth, and gradually transgressed.     

Seeking a Holocene drift ice proxy: non‐clay mineral variations from the SW to N‐central Iceland shelf: trends,regime shifts,and periodicities

Quantitative X‐ray diffraction analysis of the <2 mm sediment fraction was carried out on 1257 samples (from the seafloor and 16 cores) from the Iceland shelf west of 18° W. All but one core (B997‐347PC) were from transects along troughs on the NW to N‐central shelf, an area that in modern and historic times has been affected by drift ice. The paper focuses on the non‐clay mineralogy of the sediments (excluding calcite and volcanic glass). Quartz and potassium feldspars occupy similar positions in an R‐mode principal component analysis, and oligoclase feldspar tracks quartz; these minerals are used as a proxy for ice‐rafted detritus (IRD). Accordingly, the sum of these largely foreign minerals (Q&K) (to Icelandic bedrock) is used as a proxy for drift ice. A stacked, equi‐spaced 100 a record is developed which shows both low‐frequency trends and higher‐frequency events. The detrended stacked record compares well with the flux of quartz (mg cm^?2 a^?1) at MD99‐2269 off N Iceland. The multi‐taper method indicated that there are three significant frequencies at the 95% confidence level with periods of ca. 2500, 445 and 304 a. Regime shift analysis pinpoints intervals when there was a statistically significant shift in the average Q&K weight %, and identifies four IRD‐rich events separated by intervals with lower inputs. There is some association between peaks of IRD input, less dense surface waters (from δ¹⁸O data on planktonic foraminifera) and intervals of moraine building. Copyright © 2009 John Wiley & Sons, Ltd.     

Glacimarine lithofacies,provenance and depositional processes on a West Greenland trough‐mouth fan

Along the West Greenland continental margin adjoining Baffin Bay, bathymetric data show a series of large submarine fans located at the mouths of cross‐shelf troughs. One of these fans, termed here ‘Uummannaq Fan’, is a trough‐mouth fan built largely by debris delivered from a fast‐flowing outlet of the Greenland Ice Sheet during past glacial maxima. Cores from this fan provide the first information on glacimarine sedimentary facies within a major West Greenland trough‐mouth fan and on the nature of Late Weichselian–Holocene glacigenic sediment delivery to this region of the Baffin Bay margin. Glacigenic debris flows deposited on the upper slope and extending to at least 1800 m water depth in front of the trough‐mouth are related to the remobilization of subglacial debris that was delivered onto the upper slope at times when an ice stream was positioned at the shelf edge. In contrast, sedimentary facies from the northern sector of the fan are characterized by hemipelagic and ice‐rafted sediments and turbidites; glacigenic debris flows are notably absent in cores from this region. Quantitative X‐ray diffraction studies of the <2‐mm sediment fraction indicate that the bulk of the sediment in the fan is derived from Uummannaq Trough but there are distinct intervals when sediment from northern Baffin Bay sources dominates, especially on the northern limit of the fan. These data demonstrate considerable variation in the nature of sediment delivery across the Uummannaq Fan when the Greenland Ice Sheet was at the shelf edge. They highlight the variability of glacimarine depositional processes operating on trough‐mouth fans on high‐latitude continental margins during the last glacial maximum and indicate that glacigenic debris flows are just one of a number of mechanisms by which such large depocentres form. Copyright © 2012 John Wiley & Sons, Ltd.     

Sodium and strontium in mollusc shells: preservation,palaeosalinity and palaeotemperature of the Middle Pleistocene of eastern England

This paper revisits the utility of sodium (Na) content in aragonite and calcite mollusc shells as an indicator of palaeosalinity. The data come mainly from a related suite of Middle Pleistocene marine and freshwater fossils that have been subject to broadly similar diagenetic histories. Environmental salinity is re-affirmed as the primary factor in determining the sodium content of modern and ancient mollusc shells: values <2000 ppm Na are generally indicative of non-marine environments while values >2000 Na ppm are typically from marine shells. There is a positive relationship between Na (salinity) and Sr which is a helpful discriminator of palaeosalinity in the fossil data set. The Na and Sr data give confidence that the fossil shells have not suffered pervasive diagenetic alteration and that the marine fossils lived in fully marine conditions. Oxygen isotope values in the best-preserved, fully marine fossil shells, suggest Middle Pleistocene ‘eastern England’ seawater temperatures were broadly similar to those of the modern North Sea.     

BIOSCREEN-AT: BIOSCREEN with an exact analytical solution

BIOSCREEN is used extensively for screening-level evaluation of the transport of dissolved contaminants in ground water. The code has an effective graphical user interface that makes it ideal for use in both professional practice and as a teaching aid. BIOSCREEN implements the approximate transport solution of Domenico (1987). This note describes an enhanced version of the program, BIOSCREEN-AT, which supplements the Domenico solution with an exact analytical solution. The exact analytical solution has been integrated seamlessly within the BIOSCREEN interface and provides a simple and direct way to calculate an exact solution to the transport equation and, if desired, to assess the significance of the errors introduced by the Domenico (1987) solution for site-specific applications. The modified version of BIOSCREEN is designated BIOSCREEN-AT and can be downloaded free of charge from http://www.sspa.com/./software/BIOSCREEN.htm.     

Asymmetries in tropical rainfall and circulation patterns in idealised CO2 removal experiments

Atmospheric CO₂ removal is currently receiving serious consideration as a supplement or even alternative to emissions reduction. However the possible consequences of such a strategy for the climate system, and particularly for regional changes to the hydrological cycle, are not well understood. Two idealised general circulation model experiments are described, where CO₂ concentrations are steadily increased, then decreased along the same path. Global mean precipitation continues to increase for several decades after CO₂ begins to decrease. The mean tropical circulation shows associated changes due to the constraint on the global circulation imposed by precipitation and water vapour. The patterns of precipitation and circulation change also exhibit asymmetries with regard to changes in both CO₂ and global mean temperature, but while the lag in global precipitation can be ascribed to different levels of CO₂ at the same temperature state, the regional changes cannot. Instead, ocean memory and heat transfer are important here. In particular the equatorial East Pacific continues to warm relative to the West Pacific during CO₂ ramp-down, producing an anomalously large equatorial Pacific sea surface temperature gradient and associated rainfall anomalies. The mechanism is likely to be a lag in response to atmospheric forcing between mixed-layer water in the east Pacific and the sub-thermocline water below, due to transport through the ocean circulation. The implication of this study is that a CO₂ pathway of increasing then decreasing atmospheric CO₂ concentrations may lead us to climate states during CO₂ decrease that have not been experienced during the increase.     

Urban climate and clues of heat island events in the metropolitan area of Rio de Janeiro

This paper aims to map the thermal field in the metropolitan region of Rio de Janeiro (MARJ) considering the atmospheric characteristics and the land use that contribute to understanding the urban heat island. Three thermal maps are defined through the use of Landsat5-TM satellite images for three winter events chosen for the decades of 1980, 1990, and 2000, respectively. The results reveal a concentration of warmer cores in urban central areas as well as some local warmer areas in suburban region. Sites with lower temperatures correspond to vegetated areas which are away from the central part of the MARJ, including points of suburban areas. This work emphasizes the importance of the combined analysis of surface temperature with land use and atmospheric conditions, depicting a distinct pattern of heat islands for tropical climate.