The Global Stratotype Section and Point （GSSP） for the base of the Holocene Series/Epoch （Quaternary System/Period） in the NGRIP ice core

The Greenland ice core from NorthGRIP （NGRIP） contains a proxy climate record across the Pleistocene-Holocene boundary of unprecedented clarity and resolution. Analysis of an array of physical and chemical parameters within the ice enables the base of the Holocene, as reflected in the first signs of climatic warming at the end of the Younger Dryas/Greenland Stadial 1 cold phase, to be located with a high degree of precision.     

Triassic to Early Jurassic climatic trends recorded in the Jameson Land Basin,East Greenland: clay mineralogy,petrography and heavy mineralogy

During the Early Triassic the Jameson Land Basin (Central East Greenland) was located around 30° N, in the Northern arid belt, but by the Early Jurassic was positioned at a latitude of approximately 50° N. This study examines the record of this transition through a largely continental succession using clay mineralogy, sedimentology, petrography and heavy mineralogy. The Jameson Land Basin is aligned north–south and is 280 km long and 80 km wide. Following an Early Triassic marine phase the basin was filled by predominantly continental sediments. The Early‐to‐Late Triassic succession comprises coarse alluvial clastics (Pingo Dal Formation) overlain by a succession of fine‐grained evaporite‐rich playa/lacustrine sediments (Gipsdalen Formation), indicative of arid climatic conditions. The overlying buff, dolomitic and then red lacustrine mudstones with subordinate sandstones (Fleming Fjord Formation) record reduced aridity. The uppermost Triassic grades into dark organic‐rich, and in places coaly, mudstones and buff coarse‐grained sandstones of lacustrine origin that belong to the Kap Stewart Group, which spans the Triassic–Jurassic boundary, and appear to record more humid climatic conditions. Clay mineralogy analyses highlight significant variations in the kaolinite/illite ratio, from both mudstone and sandstone samples, through the Triassic and into the earliest Jurassic. Complementary heavy mineral analyses demonstrate that the variations recognised in clay mineralogy and sandstone maturity through the Triassic–Early Jurassic succession are not a product of major provenance change or the effect of significant diagenetic alteration. The observed variations are consistent with sedimentological evidence for a long‐term trend towards more humid conditions through the Late Triassic to Early Jurassic, and the suggestion of a significant pluvial episode in the mid‐Carnian.     

A nocturnal atmospheric loss of CH<Subscript>2</Subscript>I<Subscript>2</Subscript> in the remote marine boundary layer

Ocean emissions of inorganic and organic iodine compounds drive the biogeochemical cycle of iodine and produce reactive ozone-destroying iodine radicals that influence the oxidizing capacity of the atmosphere. Di-iodomethane (CH₂I₂) and chloro-iodomethane (CH₂ICl) are the two most important organic iodine precursors in the marine boundary layer. Ship-borne measurements made during the TORERO (Tropical Ocean tRoposphere Exchange of Reactive halogens and Oxygenated VOC) field campaign in the east tropical Pacific Ocean in January/February 2012 revealed strong diurnal cycles of CH₂I₂ and CH₂ICl in air and of CH₂I₂ in seawater. Both compounds are known to undergo rapid photolysis during the day, but models assume no night-time atmospheric losses. Surprisingly, the diurnal cycle of CH₂I₂ was lower in amplitude than that of CH₂ICl, despite its faster photolysis rate. We speculate that night-time loss of CH₂I₂ occurs due to reaction with NO₃ radicals. Indirect results from a laboratory study under ambient atmospheric boundary layer conditions indicate a k _CH2I2+NO3 of ≤4 × 10^?13 cm³ molecule^?1 s^?1; a previous kinetic study carried out at ≤100 Torr found k _CH2I2+NO3 of 4 × 10^?13 cm³ molecule^?1 s^?1. Using the 1-dimensional atmospheric THAMO model driven by sea-air fluxes calculated from the seawater and air measurements (averaging 1.8 +/? 0.8 nmol m^?2 d^?1 for CH₂I₂ and 3.7 +/? 0.8 nmol m^?2 d^?1 for CH₂ICl), we show that the model overestimates night-time CH₂I₂ by >60 % but reaches good agreement with the measurements when the CH₂I₂ + NO₃ reaction is included at 2–4 × 10^?13 cm³ molecule^?1 s^?1. We conclude that the reaction has a significant effect on CH₂I₂ and helps reconcile observed and modeled concentrations. We recommend further direct measurements of this reaction under atmospheric conditions, including of product branching ratios.     

Influence of small-scale gold mining and toxic element concentrations in Bonsa river,Ghana: a potential risk to water quality and public health

A preliminary assessment of toxic element pollution caused by artisanal and small-scale gold mining in the Bonsa river of Ghana as well as the influence of TOC and SO₄ ^2? concentration on these traces in the sediment has been determined. With the exception of mercury (Hg), manganese (Mn), and arsenic (As), the concentration of aluminum (Al) in filtered river water exceeded the WHO guideline limit of 0.1 mg L^?1 in drinking water. Analyses of toxic element in sediment using Canadian Sediment Quality Criteria, contamination factor, geoaccumulation index, and enrichment factor indicate that river sediment is severely contaminated with Hg confirming the negative impact of the amalgamation technique in gold beneficiation in Ghana. The level of Hg in the surface water exceeded reported values from some rivers in Africa, Asia, and South America. The ranking order of the mean element concentration in both matrices followed the conservative order of traces found in the Earth crust except copper, which was below the detection limit of 0.01 mg kg^?1. A Pearson correlation matrix of the toxic element and geology of the river bedrock indicates that the Hg contamination is of anthropogenic origin whilst As, Mn, and Al are the result of natural enrichment. The partitioning of elements in the sediment compartments is independent of TOC and SO₄ ^2? concentration. Health-risk assessment based on average daily dose, hazard quotient, and cancer risk indicates that Hg is a health risk to the human population. In conclusion, the study has shown that there is a likely anthropic affection of the river and that this situation has worsened since earlier studies. In order to sustain aquatic life and to prevent future human health hazard, an immediate mercury remediation in the river is recommended.     

The Solar Minimum Active Region 7978, Its X2.6/1B Flare,CME, and Interplanetary Shock Propagation of 9 July 1996

The first X-class flare in four years occurred on 9 July 1996. This X2.6/1B flare reached its maximum at 09:11 UT and was located in active region 7978 (S10° W30°) which was an old-cycle sunspot polarity group. We report the SOHO LASCO/EIT/MDI and SOONSPOT observations before and after this event together with Yohkoh SXT images of the flare, radio observations of the type II shock, and GOES disk-integrated soft X-ray flux during an extended period that included energy build-up in this active region.The LASCO coronagraphs measured a significant coronal mass ejection (CME) on the solar west limb beginning on 8 July at about 09:53 UT. The GOES 8 soft X-ray flux (0.1–0.8 nm) had started to increase on the previous day from below the A-level background (10^-8 W m^-2). At the start time of the CME, it was at the mid-B level and continued to climb. This CME is similar to many events which have been seen by LASCO and which are being interpreted as disruption of existing streamers by emerging flux ropes.LASCO and EIT were not collecting data at the time of the X-flare due to a temporary software outage. A larger CME was in progress when the first LASCO images were taken after the flare. Since the first image of the 'big' CME was obtained after the flare's start time, we cannot clearly demonstrate the physical connection of the CME to the flare. However, the LASCO CME data are consistent with an association of the flare and the CME. No eruptive filaments were observed during this event.We used the flare evidence noted above to employ in real time a simplified Shock-Time-of-Arrival (STOA) algorithm to estimate the arrival of a weak shock at the WIND spacecraft. We compare this prediction with the plasma and IMF data from WIND and plasma data from the SOHO/CELIAS instrument and suggest that the flare - and possibly the interplanetary consequences of the 'big' CME - was the progenitor of the mild, high-latitude, geomagnetic storm (daily sum of Kp=16+, Ap=8) on 12 July 1996. We speculate that the shock was attenuated enroute to Earth as a result of interaction with the heliospheric current/plasma sheet.presently at High Altitude Observatory, Boulder, CO80309, U.S.A.presently at Naval Research Laboratory, Washington DC, 20375, U.S.A.