Late Quaternary sea‐level change and evolution of Belfast Lough,Northern Ireland: new offshore evidence and implications for sea‐level reconstruction

The interplay of eustatic and isostatic factors causes complex relative sea‐level (RSL) histories, particularly in paraglacial settings. In this context the past record of RSL is important in understanding ice‐sheet history, earth rheology and resulting glacio‐isostatic adjustment. Field data to develop sea‐level reconstructions are often limited to shallow depths and uncertainty exists as to the veracity of modelled sea‐level curves. We use seismic stratigraphy, 39 vibrocores and 26 radiocarbon dates to investigate the deglacial history of Belfast Lough, Northern Ireland, and reconstruct past RSL. A typical sequence of till, glacimarine and Holocene sediments is preserved. Two sea‐level lowstands (both max. ?40 m) are recorded at c. 13.5 and 11.5k cal a bp . Each is followed by a rapid transgression and subsequent periods of RSL stability. The first transgression coincides temporally with a late stage of Meltwater Pulse 1a and the RSL stability occurred between c. 13.0 and c. 12.2k cal a bp (Younger Dryas). The second still/slowstand occurred between c. 10.3 and c. 11.5k cal a bp . Our data provide constraints on the direction and timing of RSL change during deglaciation. Application of the Depth of Closure concept adds an error term to sea‐level reconstructions based on seismic stratigraphic reconstructions.     

Solubility of carbon dioxide in aqueous fluids and mineral suspensions at 294 K and subcritical pressures

An experimental investigation has been carried on the solubility of CO₂ in water and 1 M NaCl between 0.3 and 4 MPa, in order to test the validity of the results given by various modelling codes. In addition to experiments with pure fluids, the effect of a range of likely reservoir minerals on CO₂–water interactions, including K-feldspar, kaolinite, calcite, Ca-montmorillonite and Na-montmorillonite were also investigated. In addition to measurements of CO₂ solubility, the pH of the CO₂-saturated suspensions was also measured directly at pressures of up to 1 MPa. The results demonstrate that predictions of CO₂ solubility made with PHREEQC and Geochemist’s Workbench agree to within 20% with the experimental value, provided corrections are first made off-line for the fugacity coefficient of CO₂, while predictions from standalone models are slightly more accurate. In the presence of mineral suspensions, PHREEQC and Geochemist’s Workbench give good results for calcite and kaolinite but underestimate the pH of montmorillonite-bearing assemblages while slightly overestimating the pH of K-feldspar suspensions. These results are significant because they indicate that CO₂-charged fluids reacted with clays may be less acidic than indicated by the models, which will impact predictions of the potential for dissolution of reservoir and cap rock minerals, as well as the potential for leaching of toxic metals.     

An Atomic Force Microscopy study of the growth of calcite in the presence of sodium sulfate

In situ atomic force microscopy (AFM) has been used to compare the growth of pure calcite and the growth of calcite in the presence of sulfate ions from aqueous solutions at a constant value of supersaturation (S.I. = 0.89) with respect to calcite. The effect of sulfate ions on calcite growth rates is determined and a potential incorporation of sulfate ions is identified in the calcite during growth. Solutions supersaturated with respect to calcite with solution concentration ratio of one and a constant pH of 10.2, were prepared and sulfate was added as Na₂SO₄ aqueous solution. The solution composition was readjusted in order to keep the supersaturation and pH constant. PHREEQC was used to determine relevant solution concentrations. In situ AFM experiments of calcite growth were performed using a fluid cell and flowing solutions passed over a freshly cleaved calcite surface. Growth rates were determined from the closure of the rhombohedral etch pits induced by initial dissolution with pure water. The spreading rate of 2-dimensional nuclei was also measured. At low concentrations of sulfate (≤ 0.5 mM), no effect on the growth rate of the calcite was observed. At higher concentrations (2 to 3 mM) of sulfate, the growth rate increased, possibly because a higher concentration of calcium and carbonate was necessary to maintain the supersaturation constant. At much higher concentrations of additional sulfate (up to 60 mM) the growth rate of the calcite was substantially decreased, despite the fact that a further increase of calcium and carbonate was required. The morphology of 2-dimensional growth nuclei became increasingly elongated with increasing sulfate content. Measurements of step height showed that newly grown steps were approximately 1 Å higher when grown in high sulfate concentrations, compared to steps grown in sulfate-free solutions. At sulfate concentrations above 5 mM the growth mechanism changes from layer growth to surface roughening. These observations suggest that the new growth has incorporated sulfate into the calcite surface.     

长江三角洲南部“大城市圈振兴”理论的质疑

工业发展和城市化的传统理论，对亚洲的某些具有较高生产力水平，且还在发展中的“大城市圈”不能充分地解释，本文对长江三角洲南部空间经济转为的“大城市圈振兴”理论进行了批判地评论，根据最新的现场调查结果，从根本上对“转为过程”的假说提出质疑，并且提出了更适当的的区域发展战略，此外还证明，关于亚洲大城市带的一般结论，必须建立在对地方性经济变革认识的基础之上。     

Copepod grazing during spring blooms: Does Calanus pacificus avoid harmful diatoms?

During late winter and spring of 2002 and 2003, 24, 2–3 day cruises were conducted to Dabob Bay, Washington State, USA, to examine the grazing, egg production, and hatching success rates of adult female Calanus pacificus and Pseudocalanus newmani. The results of the copepod grazing experiments for C. pacificus are discussed here. Each week, copepod grazing incubation experiments from two different depth layers were conducted. Grazing was measured by both changes in chlorophyll concentration and cell counts. In 2002, there was one moderate bloom consisting mainly of Thalassiosira spp. in early February, and a larger bloom in April comprised of two Chaetoceros species and Phaeocystis sp. Similarly, in 2003, there were two blooms, an early one dominated by Thalassiosira spp., and a later one consisting of Chaetoceros spp. and Thalassiosira spp. Clearance rates on individual prey species, as calculated by cell counts, showed that C. pacificus are highly selective in their feeding, and may have much higher clearance rates on individual taxa than rates calculated from bulk chlorophyll disappearance. During weeks of high phytoplankton concentration, the copepods generally ate phytoplankton. However, they often rejected the most abundant phytoplankton species, particularly certain Thalassiosira spp., even though the rejected prey were often of the same genus and similar size to the preferred prey. It is speculated that this avoidance may be related to the possible deleterious effects that certain of these diatom species have on the reproductive success of these copepods. During weeks of medium to low phytoplankton concentration, the copepods selectively ate certain species of phytoplankton, and often had high electivity for microzooplankton. The selection mechanism must consist of active particle rejection most likely based on detection of surface chemical properties, since the diatoms that were selected were of the same genus, nearly the same size, and at lower numerical abundance than those cells that were avoided. The grazing choices made by these copepods may have important consequences for the overall ecosystem function within coastal and estuarine systems through changes in the transfer efficiency of energy to higher trophic levels.     

Field Measurement of Suction, Water Content, and Water Permeability

This paper presents a review of techniques for field measurement of suction, water content, and water hydraulic conductivity (permeability). Main problems in the use of field tensiometers are addressed and hints on how to improve tensiometer performance are given. Advantages and limitations of instruments for indirect measurement of suction including electrical conductivity sensors, thermal conductivity sensors, dielectric permittivity sensors, filter paper, and psychrometer are discussed. Techniques for water content measurement based on dielectric methods are then presented. These include time and amplitude domain reflectometry and capacitance. Finally, a brief overview of methods for measurement of water permeability in the field is presented.     

Granitic plutonism as an indicator of microplates in the Palaeozoic of central and eastern Maine

Oxygen and strontium isotope ratios have been used to characterize source regions for granitic magmas for a transect across the northern Appalachian orogen in central and eastern Maine. The northwestern plutons (Katahdin and Seboeis) have δ¹⁸O values of 10.3–13.3 and initial ⁸⁷Sr/⁸⁶Sr ratios of 0.7083 and 0.7066, respectively. The central plutons (Bottle Lake and Center Pond) have lower δ¹⁸O values (8.2–9.9) and initial ⁸⁷Sr/⁸⁶Sr ratios (0.7043–0.7055). The southeastern plutons (Lucerne and Deblois) have δ¹⁸O values (9.0–11.0) but initial ⁸⁷Sr/⁸⁶Sr ratios (0.7077 and 0.7041, respectively) which are intermediate between the northwestern and central plutons.Source models derived from these results and other petrological and geochemical data reflect the juxtaposition of discrete source regions by transcurrent faulting, which may be related to oblique plate motions. This model illustrates the importance of microplate accretion in the Palaeozoic history of the northern Appalachian orogen.     

Contributions of individual variation in temperature, solar radiation and precipitation to crop yield in the North China Plain, 1961–2003

An understanding of the relative impacts of the changes in climate variables on crop yield can help develop effective adaptation strategies to cope with climate change. This study was conducted to investigate the effects of the interannual variability and trends in temperature, solar radiation and precipitation during 1961–2003 on wheat and maize yields in a double cropping system at Beijing and Zhengzhou in the North China Plain (NCP), and to examine the relative contributions of each climate variable in isolation. 129 climate scenarios consisting of all the combinations of these climate variables were constructed. Each scenario contained 43 years of observed values of one variable, combined with values of the other two variables from each individual year repeated 43 times. The Agricultural Production Systems Simulator (APSIM) was used to simulate crop yields using the ensemble of generated climate scenarios. The results showed that the warming trend during the study period did not have significant impact on wheat yield potential at both sites, and only had significant negative impact on maize yield potential at Beijing. This is in contrast with previous results on effect of warming. The decreasing trend in solar radiation had a much greater impact on simulated yields of both wheat and maize crops, causing a significant reduction in potential yield of wheat and maize at Beijing. Although decreasing trends in rainfed yield of both simulated wheat and maize were found, the substantial interannual variability of precipitation made the trends less prominent.     

The next few years of the ICES Journal of Marine Science

This issue marks a change in the editorial team of the ICESJournal of Marine Science, in that we have bid farewell to ourformer Editor-in-Chief, Niels Daan, after six years of sterlingservice, and to our Elsevier Publishing Editor, Andrew Richford,after an even longer period of years. Both deserve credit fortheir energy and vision that has left us the legacy of a journalas widely read and cited as the ICES Journal now is, but theyleave a gap that will be a huge challenge for us to meet. However,in my new capacity as Editor-in-Chief and in Els Bosma's capacityas Elsevier's Publishing Editor, I     

Particle–water interactions of 2,2′,5,5′-tetrachlorobiphenyl under simulated estuarine conditions

A batch sorption technique for the determination of particle–water interactions of hydrophobic organic micropollutants under simulated estuarine conditions is described. Results are presented for the behaviour of 2,2′,5,5′-tetrachlorobiphenyl (2,2′,5,5′-TCB) in river and sea waters, both in the presence and absence of estuarine suspended particles. Adsorption onto particles in sea water was enhanced compared with adsorption in river water owing to salting out of the compound, and possibly of the particulate organic matter, in the presence of high concentrations of dissolved ions. The particle–water distribution coefficient, K_D, decreased from about 120×10³ to 10×10³ ml g⁻¹, and from about 150×10³ to 20×10³ ml g⁻¹, in river water and sea water, respectively, over a particle concentration range of 10–1000 mg l⁻¹. Incomplete recovery of compound from the reactor walls is partly responsible for a particle concentration effect, while artefacts relating to inadequate sediment and water phase separation were ruled out following further experiments. The particle concentration effect, which is replicated in many field studies of hydrophobic organic micropollutants, including 2,2′,5,5′-TCB, is incorporated into a simple partitioning model and is discussed in the context of the likely estuarine behaviour of such compounds.