The Triassic age for oceanic eclogites in the Dabie orogen: Entrainment of oceanic fragments in the continental subduction

Low-temperature and high-pressure eclogites with an oceanic affinity in the western part of the Dabie orogen have been investigated with combined Lu–Hf and U–Pb geochronology. These eclogites formed over a range of temperatures (482–565 °C and 1.9–2.2 GPa). Three eclogites, which were sampled from the Gaoqiao country, yielded Lu–Hf ages of 240.7 ± 1.2 Ma, 243.3 ± 4.1 Ma and 238.3 ± 1.2 Ma, with a corresponding lower-intercept U–Pb zircon age of 232 ± 26 Ma. Despite the well-preserved prograde major- and trace-element zoning in garnets, these Lu–Hf ages mostly reflect the high-pressure eclogite-facies metamorphism instead of representing the early phase of garnet growth due to the occurrence of omphacite inclusions from core to rim and the shell effect. An upper-intercept zircon U–Pb age of 765 ± 24 Ma is defined for the Gaoqiao eclogite, which is consistent with the weighted-mean age of 768 ± 21 Ma for the country gneiss. However, the gneiss has not been subjected to successive high-pressure metamorphism. The new Triassic ages are likely an estimate of the involvement of oceanic fragments in the continental subduction.     

Abiotic interactions of natural dissolved organic matter and carbonate aquifer rock

Abiotic interactions between natural dissolved organic matter (NDOM) and carbonate aquifer rock may be controlling factors of biogeochemical processes and contaminant fate in carbonate aquifer systems. The importance and effects of these interactions were examined using batch adsorption experiments of soil NDOM and representative carbonate sorbents from the Floridan Aquifer. Adsorption of NDOM carbon to aquifer rocks was well-described using a modified linear model and was mostly reversible. Significant adsorption was observed at higher NDOM concentrations, while the release of indigenous organic matter from the rocks occurred at lower concentrations. Longer interaction periods led to more adsorption, indicating that adsorption equilibrium was not achieved. For relatively pure carbonate rock samples, sorbent surface area was found to be the most important controlling factor of adsorption, whereas the presence of indigenous organic matter and subdominant mineral phases were more important, when they occurred. Preferential adsorption of a high over low molecular weight and humic over fulvic components of NDOM onto carbonate sorbents was detected using liquid size exclusion chromatography and excitation–emission fluorometry, respectively. The presence of NDOM inhibited mineral dissolution, though this inhibition was not proportional to NDOM concentration as surface area and mineralogy of carbonate sorbents played additional roles. Though the NDOM–carbonate rock adsorption mechanism could not be completely determined due to the heterogeneity and complexity of NDOM and sorbent surfaces, it is speculated that both rapid and weak outer-sphere bonding and stronger but slower hydrophobic interaction occur. These results have important implications for groundwater quality and hydrogeologic projects such as aquifer storage and recovery.     

Ecological Modernization or Aristocratic Conservation? Exploring the Impact of Affluence on Carbon Emissions at the Local Level

Social scientists have debated how affluence impacts carbon emissions at the national level. We conduct an exploratory study at the subnational level to expose another dimension of the affluence–emissions debate. Based on the notion of aristocratic conservation, we hypothesize that affluence is positively related to carbon emissions from consumption activities but negatively related to emissions from production activities. We test these hypotheses using county-level data in the United States for the year 2002. A spatial regression analysis demonstrates that median household income is positively associated with consumption-based emissions; nevertheless, we find evidence of an environmental inequality Kuznets curve in the relationship between median household income and production-based emissions. This finding suggests that the wealthiest counties are able to displace certain types of emissions, specifically those related to energy and industrial production. We discuss the theoretical and political implications of these results.     

A new pathway for Deep water exchange between the Natal Valley and Mozambique Basin?

Although global thermohaline circulation pathways are fairly well known, the same cannot be said for local circulation pathways. Within the southwest Indian Ocean specifically there is little consensus regarding the finer point of thermohaline circulation. We present recently collected multibeam bathymetry and PARASOUND data from the northern Natal Valley and Mozambique Ridge, southwest Indian Ocean. These data show the Ariel Graben, a prominent feature in this region, creates a deep saddle across the Mozambique Ridge at ca. 28°S connecting the northern Natal Valley with the Mozambique Basin. Results show a west to east change in bathymetric and echo character across the northern flank of the Ariel Graben. Whereby eroded plastered sediment drifts in the west give way to aggrading plastered sediment drift in the midgraben, terminating in a field of seafloor undulations in the east. In contrast, the southern flank of the Ariel Graben exhibits an overall rugged character with sediments ponding in bathymetric depressions in between rugged sub/outcrop. It is postulated that this change in sea-floor character is the manifestation of deep water flow through the Ariel Graben. Current flow stripping, due to increased curvature of the graben axis, results in preferential deposition of suspended load in an area of limited accommodation space consequently developing an over-steepened plastered drift. These deposited sediments overcome the necessary shear stresses, resulting in soft sediment deformation in the form of down-slope growth faulting (creep) and generation of undulating sea-floor morphology. Contrary to previous views, our works suggests that water flows from west to east across the Mozambique Ridge via the Ariel Graben.     

The impact of precipitation on speed–flow relationships along a UK motorway corridor

Although the fundamental traffic diagram provides the characteristics of a typical road traffic speed–flow relationship, little consideration has been given to the impact of adverse weather conditions on the relationship and the subsequent impact on local speed–flow. For the first time, this study uses precipitation radar along with a state-of-the art traffic information system to ascertain the relationship between speed–flow and precipitation on a UK transport corridor at the local (junction to junction) scale. It is evident that precipitation causes a significant reduction in speed and maximum flow on many links of the corridor as well as a downward reduction in the overall speed-flow relationship. With increased instances of heavy precipitation predicted in the UK as a result of climate change, these findings highlight the subsequent impact on journey travel times and associated economic costs.     

The Little Ice Age climate of New Zealand reconstructed from Southern Alps cirque glaciers: a synoptic type approach

Little Ice Age (LIA) austral summer temperature anomalies were derived from palaeoequilibrium line altitudes at 22 cirque glacier sites across the Southern Alps of New Zealand. Modern analog seasons with temperature anomalies akin to the LIA reconstructions were selected, and then applied in a sampling of high-resolution gridded New Zealand climate data and global reanalysis data to generate LIA climate composites at local, regional and hemispheric scales. The composite anomaly patterns assist in improving our understanding of atmospheric circulation contributions to the LIA climate state, allow an interrogation of synoptic type frequency changes for the LIA relative to present, and provide a hemispheric context of the past conditions in New Zealand. An LIA summer temperature anomaly of ?0.56 °C (±0.29 °C) for the Southern Alps based on palaeo-equilibrium lines compares well with local tree-ring reconstructions of austral summer temperature. Reconstructed geopotential height at 1,000 hPa (z1000) suggests enhanced southwesterly flow across New Zealand occurred during the LIA to generate the terrestrial temperature anomalies. The mean atmospheric circulation pattern for summer resulted from a crucial reduction of the ‘HSE’-blocking synoptic type (highs over and to the west of NZ; largely settled conditions) and increases in both the ‘T’- and ‘SW’-trough synoptic types (lows passing over NZ; enhanced southerly and southwesterly flow) relative to normal. Associated land-based temperature and precipitation anomalies suggest both colder- and wetter-than-normal conditions were a pervasive component of the base climate state across New Zealand during the LIA, as were colder-than-normal Tasman Sea surface temperatures. Proxy temperature and circulation evidence were used to corroborate the spatially heterogeneous Southern Hemisphere composite z1000 and sea surface temperature patterns generated in this study. A comparison of the composites to climate mode archetypes suggests LIA summer climate and atmospheric circulation over New Zealand was driven by increased frequency of weak El Niño-Modoki in the tropical Pacific and negative Southern Annular Mode activity.