The variability of ruthenium in chromite from chassignite and olivine‐phyric shergottite meteorites: New insights into the behavior of PGE and sulfur in Martian magmatic systems

The Martian meteorites comprise mantle‐derived mafic to ultramafic rocks that formed in shallow intrusions and/or lava flows. This study reports the first in situ platinum‐group element data on chromite and ulvöspinel from a series of dunitic chassignites and olivine‐phyric shergottites, determined using laser‐ablation ICP‐MS. As recent studies have shown that Ru has strongly contrasting affinities for coexisting sulfide and spinel phases, the precise in situ analysis of this element in spinel can provide important insights into the sulfide saturation history of Martian mantle‐derived melts. The new data reveal distinctive differences between the two meteorite groups. Chromite from the chassignites Northwest Africa 2737 (NWA 2737) and Chassigny contained detectable concentrations of Ru (up to ~160 ppb Ru) in solid solution, whereas chromite and ulvöspinel from the olivine‐phyric shergottites Yamato‐980459 (Y‐980459), Tissint, and Dhofar 019 displayed Ru concentrations consistently below detection limit (<42 ppb). The relatively elevated Ru signatures of chromite from the chassignites suggest a Ru‐rich (~1–4 ppb) parental melt for this meteorite group, which presumably did not experience segregation of immiscible sulfide liquids over the interval of mantle melting, melt ascent, and chromite crystallization. The relatively Ru‐depleted signature of chromite and ulvöspinel from the olivine‐phyric shergottites may be the consequence of relatively lower Ru contents (<1 ppb) in the parental melts, and/or the presence of sulfides during the crystallization of the spinel phases. The results of this study illustrate the significance of platinum‐group element in situ analysis on spinel phases to decipher the sulfide saturation history of magmatic systems.     

Open-system chemical behavior in deep Wilcox Group mudstones,Texas Gulf Coast,USA

Wilcox Group mudstones have been mechanically and geochemically transformed over a temperature range of 20–200 °C. Our research controlled for provenance and age by sampling from five wells, parallel to the paleodepositional axis, all within the Houston delta system. Across the sampled depths, mudstone porosity has been reduced from ∼25 to <10% and bulk mineralogical change as documented by quantitative X-ray diffraction includes decreases in quartz, K-feldspar and kaolinite content whereas illite + illite − smectite, chlorite, and plagioclase increase. These mineral transformations transfer elements at a scale of less than 1 mm from one mineralogical form to another, however, X-ray fluorescence data suggest that among major elements only Al₂O₃ and TiO₂ are fully conserved within the system (trace-element ZrO₂ is also conserved). K₂O has been added to and SiO₂ released from the Wilcox Group mudstones. Cathodoluminescence and secondary electron imaging did not find this SiO₂ locally precipitated. We, therefore, document an open-system geochemical behavior.     

How U.S. ocean policy and market power can reform the coral reef wildlife trade

As the world’s largest importer of marine ornamental species for the aquaria, curio, home décor, and jewelry industries, the United States has an opportunity to leverage its considerable market power to promote more sustainable trade and reduce the effects of ornamental trade stress on coral reefs worldwide. Evidence indicates that collection of some coral reef animals for these trades has caused virtual elimination of local populations, major changes in age structure, and promotion of collection practices that destroy reef habitats. Management and enforcement of collection activities in major source countries such as Indonesia and the Philippines remain weak. Strengthening US trade laws and enforcement capabilities combined with increasing consumer and industry demand for responsible conservation can create strong incentives for improving management in source countries. This is particularly important in light of the March 2010 failure of the parties to the Convention on International Trade in Endangered Species (CITES) to take action on key groups of corals.     

Role of geological inheritance in Australian beach morphodynamics

The Australian coast contains 10,685 beaches which occupy 49% of the 30,000 km coast and average 1.37 km in length. Their relatively short length is largely due to the presence of bedrock, calcarenite and laterite, which form boundaries to many of the beaches, as well as occurring as rocks, reefs and islands along and off the beaches. This geological inheritance plays a major role in Australian beach systems — determining their length and through wave refraction and attenuation influencing beach location, shape, type, morphodynamics and circulation, which in turn influence sediment transport and the backing dune and barrier systems. This paper uses a database covering every Australian beach to review the role of headlands, rocks and reefs on Australian beaches. Major effects are the short average beach length; reduction in breaker height resulting in lower energy beach types; wave refraction resulting in increased beach curvature; the presence of topographic rips on moderate and higher energy beaches and megarips during high wave conditions; and the interruption of and/or trapping of longshore sand transport leading to beach rotation.     

Propagation of coastal‐trapped waves under an ice cover in Hudson Bay*

Abstract

Three arrays of current‐meter moorings were deployed under landfast sea ice in southeast Hudson Bay for eight weeks in spring 1986. Spectral analysis shows low‐frequency signals with periods of 3 to 11 days. These signals are interpreted as being due to coastal‐trapped waves propagating cyclonically in Hudson Bay; their theoretical dispersion relations and corresponding modal structures are presented for winter stratification and are compared with observations. At a period of 3 days both the modified external Kelvin wave and higher mode continental shelf waves may be important in describing the observed low‐frequency variability, whereas at a period of 10 days the Kelvin wave appears to be the dominant mode. The generation mechanisms for these coastal trapped waves are also investigated. Two sources have been studied: the longshore atmospheric pressure gradient and the average atmospheric pressure over the ice cover in Hudson Bay. Coherence and phase analyses performed with time series of longshore current and atmospheric forcing data reveal that both the average atmospheric pressure and the longshore atmospheric pressure gradient are important in explaining the observed low‐frequency variability, without indicating which one is the most important.     

Characterization of seafloor pockmark seepage of hydrocarbons employing fractal: A case study from the western continental margin of India

Here we apply quantitative technique to describe the seafloor seepages based on the multi-beam backscatter and bathymetric investigations to characterize the pockmark morphology. The variable seafloor backscatter strength for coarser seafloor sediments are related to the diagenesis derived from biodegraded seepages. In this regard, box counting method is used to estimate ‘fractal dimension’ for backscatter imagery data of 398 blocks. These blocks are further sub-grouped into six classes depending on the spread of pockmark related seepages. The study area lies 102 km west off Marmagao along the central west coast of India which contains pre-dominantly (70%) gas-charged sediments. Comparison between the estimated self-similar fractals reveals that there is approximately 97% correlation between the box (D_box) and information (D_info) dimensions. Box dimension–derived fractal dimension values, suggest that the seepages are more along the fault trace in deeper waters, in comparison to sparsely distributed shallow water seepages. Besides, this poor seepage is confined within the smooth to moderately rough seafloor. It is established that the high backscatter strength along the upper slope of the pockmark region having higher fractal dimensions reflects multifractal behavior of seepage distribution. Entire area indicates patchy seepage patterns as supported by estimated fractal values showing intermittent fluctuations, which emphasizes non-linear behavior. Estimated self organizing criticality (SOC) parameters for six representative blocks reveal that the nature of pockmark, fault trace, sediment nature coupled with slumping of pockmark’s wall, sediment movement due to bottom currents are controlling the dynamic balance in the area seepage system. Further, our study emphasizing the multifractal behavior of seepage blocks, clearly depicts the drift in the seepage pattern.