Particle–water interactions of 2,2′,5,5′-tetrachlorobiphenyl under simulated estuarine conditions

A batch sorption technique for the determination of particle–water interactions of hydrophobic organic micropollutants under simulated estuarine conditions is described. Results are presented for the behaviour of 2,2′,5,5′-tetrachlorobiphenyl (2,2′,5,5′-TCB) in river and sea waters, both in the presence and absence of estuarine suspended particles. Adsorption onto particles in sea water was enhanced compared with adsorption in river water owing to salting out of the compound, and possibly of the particulate organic matter, in the presence of high concentrations of dissolved ions. The particle–water distribution coefficient, K_D, decreased from about 120×10³ to 10×10³ ml g⁻¹, and from about 150×10³ to 20×10³ ml g⁻¹, in river water and sea water, respectively, over a particle concentration range of 10–1000 mg l⁻¹. Incomplete recovery of compound from the reactor walls is partly responsible for a particle concentration effect, while artefacts relating to inadequate sediment and water phase separation were ruled out following further experiments. The particle concentration effect, which is replicated in many field studies of hydrophobic organic micropollutants, including 2,2′,5,5′-TCB, is incorporated into a simple partitioning model and is discussed in the context of the likely estuarine behaviour of such compounds.     

Water Resources Implications of Global Warming: A U.S. Regional Perspective

The implications of global warming for the performance of six U.S. water resource systems are evaluated. The six case study sites represent a range of geographic and hydrologic, as well as institutional and social settings. Large, multi-reservoir systems (Columbia River, Missouri River, Apalachicola-Chatahoochee-Flint (ACF) Rivers), small, one or two reservoir systems (Tacoma and Boston) and medium size systems (Savannah River) are represented. The river basins range from mountainous to low relief and semi-humid to semi-arid, and the system operational purposes range from predominantly municipal to broadly multi-purpose. The studies inferred, using a chain of climate downscaling, hydrologic and water resources systems models, the sensitivity of six water resources systems to changes in precipitation, temperature and solar radiation. The climate change scenarios used in this study are based on results from transient climate change experiments performed with coupled ocean-atmosphere General Circulation Models (GCMs) for the 1995 Intergovernmental Panel on Climate Change (IPCC) assessment. An earlier doubled-CO₂ scenario from one of the GCMs was also used in the evaluation. The GCM scenarios were transferred to the local level using a simple downscaling approach that scales local weather variables by fixed monthly ratios (for precipitation) and fixed monthly shifts (for temperature). For those river basins where snow plays an important role in the current climate hydrology (Tacoma, Columbia, Missouri and, to a lesser extent, Boston) changes in temperature result in important changes in seasonal streamflow hydrographs. In these systems, spring snowmelt peaks are reduced and winter flows increase, on average. Changes in precipitation are generally reflected in the annual total runoff volumes more than in the seasonal shape of the hydrographs. In the Savannah and ACF systems, where snow plays a minor hydrological role, changes in hydrological response are linked more directly to temperature and precipitation changes. Effects on system performance varied from system to system, from GCM to GCM, and for each system operating objective (such as hydropower production, municipal and industrial supply, flood control, recreation, navigation and instream flow protection). Effects were generally smaller for the transient scenarios than for the doubled CO₂ scenario. In terms of streamflow, one of the transient scenarios tended to have increases at most sites, while another tended to have decreases at most sites. The third showed no general consistency over the six sites. Generally, the water resource system performance effects were determined by the hydrologic changes and the amount of buffering provided by the system's storage capacity. The effects of demand growth and other plausible future operational considerations were evaluated as well. For most sites, the effects of these non-climatic effects on future system performance would about equal or exceed the effects of climate change over system planning horizons.     

Depthimeter-Precise Vessel Depth for Bathymetry

This article describes the design, operation, and field testing of the depthimeter. The depthimeter merges heave and acoustically derived vessel depth to form estimates of instantaneous vessel depth and instantaneous sea surface height, both relative to mean sea level. Results from sea trials held in December 1997 demonstrate successful operation of the system.     

Surface images of the short period contact binary AE Phe

We present high resolution Doppler images of the short period (P = 0.362 d) contact binary AE Phe. Using least squares deconvolution, we make use of the information content of the several thousand lines in each échelle spectrum to obtain the necessary S/N and time resolution required to resolve individual starspot features. A single pair of rotationally broadened profiles (free of sidelobes due to blending) with a typical S/N of 3000 ‐ 4000 per spectrum is thus obtained. With 300 sec exposures we achieve a cadence of 350 sec which is equivalent to sampling the rotation phase every 4°. We derive images for four nights of data which reveal starspots at most latitudes on both components of the common envelope system. Individual starspots evolve significantly on very short timescales, of order one day; significantly faster than the week timescales found on active single stars and the Sun. (© 2004 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Accelerated initial stiffness schemes for elastoplasticity

Iterative methods for the solution of non‐linear finite element equations are generally based on variants of the Newton–Raphson method. When they are stable, full Newton–Raphson schemes usually converge rapidly but may be expensive for some types of problems (for example, when the tangent stiffness matrix is unsymmetric). Initial stiffness schemes, on the other hand, are extremely robust but may require large numbers of iterations for cases where the plastic zone is extensive. In most geomechanics applications it is generally preferable to use a tangent stiffness scheme, but there are situations in which initial stiffness schemes are very useful. These situations include problems where a nonassociated flow rule is used or where the zone of plastic yielding is highly localized. This paper surveys the performance of several single‐parameter techniques for accelerating the convergence of the initial stiffness scheme. Some simple but effective modifications to these procedures are also proposed. In particular, a modified version of Thomas' acceleration scheme is developed which has a good rate of convergence. Previously published results on the performance of various acceleration algorithms for initial stiffness iteration are rare and have been restricted to relatively simple yield criteria and simple problems. In this study, detailed numerical results are presented for the expansion of a thick cylinder, the collapse of a rigid strip footing, and the failure of a vertical cut. These analyses use the Mohr–Coulomb and Tresca yield criteria which are popular in soil mechanics. Copyright © 2000 John Wiley & Sons, Ltd.     

Iron and Manganese in Groundwater: Using Kriging and GIS to Locate High Concentrations in Buncombe County,North Carolina

For health, economic, and aesthetic reasons, allowable concentrations (as suggested by the United States Environmental Protection Agency) of the secondary contaminants iron (Fe) and manganese (Mn) found present in drinking water are 0.3 and 0.05 mg/L, respectively. Water samples taken from private drinking wells in rural communities within Buncombe County, North Carolina contain concentrations of these metals that exceed secondary water quality criteria. This study predicted the spatial distribution of Fe and Mn in the county, and evaluated the effect of site environmental factors (bedrock geology, ground elevation, saprolite thickness, and drinking water well depth) in controlling the variability of Fe and Mn in groundwater. A statistically significant correlation between Fe and Mn concentrations, attributable to bedrock geology, was identified. Prediction models were created using ordinary kriging and cokriging interpolation techniques to estimate the presence of Fe and Mn in groundwater where direct measurements are not possible. This same procedure can be used to estimate the trend of other contaminants in the groundwater in different areas with similar hydrogeological settings.     

Particle‐size evidence of barrier estuary regime as a new proxy for ENSO climate variability

We investigate a new proxy for ENSO climate variability based on particle‐size data from long‐term, coastal sediment records preserved in a barrier estuary setting. Corresponding ~4–8 year periodicities identified from Wavelet analysis of particle‐size data from Pescadero Marsh in Central Coast California and rainfall data from San Francisco reflect established ENSO periodicity, as further evidenced in the Multivariate ENSO Index (MEI), and thus confirms an important ENSO control on both precipitation and barrier regime variability. Despite the fact that barrier estuary mean particle size is influenced by coastal erosion, precipitation and streamflow, balanced against barrier morphology and volume, it is encouraging that considerable correspondence can also be observed in the time series of MEI, regional rainfall and site‐based mean particle size over the period 1871–2008. This correspondence is, however, weakened after c.1970 by temporal variation in sedimentation rate and event‐based deposition. These confounding effects are more likely when: (i) accommodation space may be a limiting factor; and (ii) particularly strong El Niños, e.g. 1982/1983 and 1997/1998, deposit discrete >cm‐thick units during winter storms. The efficacy of the sediment record of climate variability appears not to be compromised by location within the back‐barrier setting, but it is limited to those El Niños that lead to barrier breakdown. For wider application of this particle size index of ENSO variability, it is important to establish a well‐resolved chronology and to sample the record at the appropriate interval to characterize deposition at a sub‐annual scale. Further, the sample site must be selected to limit the influence of decreasing accommodation space through time (infilling) and event‐based deposition. It is concluded that particle‐size data from back‐barrier sediment records have proven potential for preserving evidence of sub‐decadal climate variability, allowing researchers to explore temporal and spatial patterns in phenomena such as ENSO. Copyright © 2017 John Wiley & Sons, Ltd.     

A regime shift in sediment export from a coastal watershed during a record wet winter,California: Implications for landscape response to hydroclimatic extremes

Small, steep watersheds are prolific sediment sources from which sediment flux is highly sensitive to climatic changes. Storm intensity and frequency are widely expected to increase during the 21st century, and so assessing the response of small, steep watersheds to extreme rainfall is essential to understanding landscape response to climate change. During record winter rainfall in 2016–2017, the San Lorenzo River, coastal California, had nine flow peaks representing 2–10‐year flood magnitudes. By the third flood, fluvial suspended sediment showed a regime shift to greater and coarser sediment supply, coincident with numerous landslides in the watershed. Even with no singular catastrophic flood, these flows exported more than half as much sediment as had a 100‐year flood 35 years earlier, substantially enlarging the nearshore delta. Annual sediment load in 2017 was an order of magnitude greater than during an average‐rainfall year, and 500‐fold greater than in a recent drought. These anomalous sediment inputs are critical to the coastal littoral system, delivering enough sediment, sometimes over only a few days, to maintain beaches for several years. Future projections of megadroughts punctuated by major atmospheric‐river storm activity suggest that interannual sediment‐yield variations will become more extreme than today in the western USA, with potential consequences for coastal management, ecosystems, and water‐storage capacity. The occurrence of two years with major sediment export over the past 35 years that were not associated with extremes of the El Niño Southern Oscillation or Pacific Decadal Oscillation suggests caution in interpreting climatic signals from marine sedimentary deposits derived from small, steep, coastal watersheds, to avoid misinterpreting the frequencies of those cycles. Published 2018. This article is a U.S. Government work and is in the public domain in the USA.     

Simulation of the effect of wind speedup in the formation of transverse dune fields

A computer simulation model for transverse‐dune‐field dynamics, corresponding to a uni‐directional wind regime, is developed. In a previous formulation, two distinct problems were found regarding the cross‐sectional dune shape, namely the erosion in the lee of dunes and the steepness of the windward slopes. The first problem is solved by introducing no erosion in shadow zones. The second issue is overcome by introducing a wind speedup (shear velocity increase) factor, which can be accounted for by adding a term to the original transport length, which is proportional to the surface height. By incorporating these features we are able to model dunes whose individual shape and collective patterns are similar to those observed in nature. Moreover we show how the introduction of a non‐linear shear‐velocity‐increase term leads to the reduction of dune height, and this may result in an equilibrium dune field configuration. This is thought to be because the non‐linear increase of the transport length makes the sand trapping efficiency lower than unity, even for higher dunes, so that the incoming and the outgoing sand flux are in balance. To fully describe the inter‐dune morphology more precise dynamics in the lee of the dune must be incorporated. Copyright © 2000 John Wiley & Sons, Ltd.