Petrologic and textural diversity among the PCA 02 howardite group,one of the largest pieces of the Vestan surface

Abstract— Nine howardites and two diogenites were recovered from the Pecora Escarpment Icefield (PCA) in 2002. Cosmogenic radionuclide abundances indicate that the samples are paired and that they constituted an approximately 1 m (diameter) meteoroid prior to atmospheric entry. At about 1 m in diameter, the PCA 02 HED group represents one of the largest single pre‐atmospheric pieces of the Vestan surface yet described. Mineral and textural variations were measured in six of the PCA 02 howardites to investigate meter‐scale diversity of the Vestan surface. Mineral compositions span the range of known eucrite and diogenite compositions. Additional non‐diogenitic groups of Mg‐ and Fe‐rich olivine are observed, and are interpreted to have been formed by exogenic contamination and impact melting, respectively. These howardites contain olivine‐rich impact melts that likely formed from dunite‐ and harzburgite‐rich target rocks. Containing the first recognized olivine‐rich HED impact melts, these samples provide meteoritic evidence that olivine‐rich lithologies have been exposed on the surface of Vesta. Finally, we present a new method for mapping distributions of lithologies in howardites using 8 elemental X‐ray maps. Proportions of diogenite and eucrite vary considerably among the PCA 02 howardites, suggesting they originated from a heterogeneous portion of the Vestan surface. While whole sample modes are dominated by diogenite, the finer grain size fractions are consistently more eucritic. This discrepancy has implications for near‐infrared spectral observations of portions of Vesta’s surface that are similar to the PCA 02 howardites, as the finer grained eucritic material will disproportionately dominate the spectra.     

Spatial and temporal dynamics of nitrogen exchange in an upwelling reach of a groundwater-fed river and potential response to perturbations changing rainfall patterns under UK climate change scenarios

We report the complex spatial and temporal dynamics of hyporheic exchange flows (HEFs) and nitrogen exchange in an upwelling reach of a 200 m groundwater-fed river. We show how research combining hydrological measurement, geophysics and isotopes, together with nutrient speciation techniques provides insight on nitrogen pathways and transformations that could not have been captured otherwise, including a zone of vertical preferential discharge of nitrate from deeper groundwater, and a zone of rapid denitrification linking the floodplain with the riverbed. Nitrate attenuation in the reach is dominated by denitrification but is spatially highly variable. This variability is driven by groundwater flow pathways and landscape setting, which influences hyporheic flow, residence time and nitrate removal. We observed the spatial connectivity of the river to the riparian zone is important because zones of horizontal preferential discharge supply organic matter from the floodplain and create anoxic riverbed conditions with overlapping zones of nitrification potential and denitrification activity that peaked 10–20 cm below the riverbed. Our data also show that temporal variability in water pathways in the reach is driven by changes in stage of the order of tens of centimetres and by strength of water flux, which may influence the depth of delivery of dissolved organic carbon. The temporal variability is sensitive to changes to river flows under UK climate projections that anticipate a 14%–15% increase in regional median winter rainfall and a 14%–19% reduction in summer rainfall. Superimposed on seasonal projections is more intensive storm activity that will likely lead to a more dynamic and inherently complex (hydrologically and biogeochemically) hyporheic zone. We recorded direct evidence of suppression of upwelling groundwater (flow reversal) during rainfall events. Such flow reversal may fuel riverbed sediments whereby delivery of organic carbon to depth, and higher denitrification rates in HEFs might act in concert to make nitrate removal in the riverbed more efficient.     

A Comparative Plume Study of DRO,GRO, Benzene,and MTBE: Implications for Risk Management

Groundwater remediation and no-further action decision making at petroleum underground storage tank (UST) sites has largely been based on an understanding of plume length, plume stability, and attenuation rates for key hydrocarbon constituents. Regulatory guidance to support and guide such decisions is based in part on plume studies involving individual hydrocarbon constituents, namely benzene and methyl tert-butyl ether (MTBE). Questions remain regarding whether current guidance is applicable to chemical mixtures such as gasoline range organics (GRO), diesel range organics (DRO), and oxygen containing organic compounds (OCOCs) resulting from hydrocarbon biodegradation. To help address this concern, data from California's GeoTracker database were used to estimate maximum plume lengths, plume stability, and attenuation rates of DRO (which can be used as an analytical surrogate for OCOCs) and GRO relative to benzene and MTBE. The distributions of maximum plume lengths were similar for the four constituents with medians ranging from 27 to 32 m. The fraction of monitoring wells with a decreasing concentration trend ranged from 19% for DRO to 40% for MTBE, while fewer than 7% of the wells had an increasing concentration trend for any of the constituents. Median attenuation rates ranged from 0.10% day⁻¹ for DRO to 0.17% day⁻¹ for MTBE. The results suggest attenuation based risk management is appropriate for DRO and GRO plumes at most petroleum UST sites.     

Multi-wavelength observations of Asteroid 2100 Ra-Shalom

We observed near-Earth asteroid (NEA) 2100 Ra-Shalom over a six-year period, obtaining rotationally resolved spectra in the visible, near-infrared, thermal-infrared, and radar wavelengths. We find that Ra-Shalom has an effective diameter of Deff=2.3±0.2 km, rotation period P=19.793±0.001 h, visual albedo pv=0.13±0.03, radar albedo , and polarization ratio μc=0.25±0.04. We used our radar observations to generate a three-dimensional shape model which shows several structural features of interest. Based on our thermal observations, Ra-Shalom has a high thermal inertia of ∼10³ J m⁻² s^−0.5 K⁻¹, consistent with a coarse or rocky surface and the inferences of others [Harris, A.W., Davies, J.K., Green, S.F., 1998. Icarus 135, 441-450; Delbo, M., Harris, A.W., Binzel, R.P., Pravec, P., Davies, J.K., 2003. Icarus 166, 116-130]. Our spectral data indicate that Ra-Shalom is a K-class asteroid and we find excellent agreement between our spectra and laboratory spectra of the CV3 meteorite Grosnaja. Our spectra show rotation-dependent variations consistent with global variations in grain size. Our radar observations show rotation-dependent variations in radar albedo consistent with global variations in the thickness of a relatively thin regolith.     

Simulation of long-term thermo-mechanical response of clay using an advanced constitutive model

Acta Geotechnica - There is extensive data to show that heating and cooling produces irrecoverable deformations in clays under fully drained conditions. The effects are most pronounced for normally...     

The Most Recent Cascadia Earthquake and Native American Narratives

The Cascadia subduction zone fault lies just off the Pacific coast of the USA and Canada. Although this fault has been seismically inactive over the written history of the Cascadia region, it has the potential to produce catastrophic earthquakes and tsunamis. A variety of dating methods have been used to show that the most recent Cascadia earthquake occurred in 1700. Among these methods is an informal analysis of oral traditions handed down by Native American peoples that appear to refer to a major earthquake in this region. A central difficulty in analyzing these narratives quantitatively is their use of a generation and other qualitative measures of time that have no fixed lengths. Here, these narratives are analyzed under an explicit statistical model of the lengths of these measures. The results raise a question about the previous conclusion that these narratives all refer to the most recent Cascadia earthquake.

     

Provenance and microprobe assays of phyllite‐tempered ceramics from the uplands of central Arizona

The ceramics in use across a broad upland zone of central Arizona during the early Classic period (ca. A.D. 1100–1300) were characterized by a lack of mineralogical variability; nearly all of the clay containers were tempered with one rock type, phyllite. Consequently, nearly all of the upland pottery is assigned to a single pottery type, Wingfield Plain. This compositional uniformity has frustrated ceramic provenance studies, and, as a result, little has been learned previously about the organization of ceramic production and exchange in the upland territory. There are, however, considerable and interpretable chemical differences in the phyllite‐tempered wares, as shown with microanalyses of the temper fragments and pottery clay fractions with an electron microprobe. The chemical patterning is useful for investigating issues pertaining to the upland zone, including the organization of ceramic manufacture, community arrangements, and pottery transactions during a time of prevalent hostilities in central Arizona. © 2008 Wiley Periodicals, Inc.