Formation of iron sulfide nodules during anaerobic oxidation of methane

The biomarker compositions of iron sulfide nodules (ISNs; upper Pliocene Valle Ricca section near Rome, Italy) that contain the ferrimagnetic mineral greigite (Fe₃S₄) were examined. In addition to the presence of specific terrestrial and marine biomarkers, consistent with formation in coastal marine sediments, these ISNs contain compounds thought to originate from sulfate reducing bacteria (SRB). These compounds include a variety of low-molecular-weight and branched alkanols and several non-isoprenoidal dialkyl glycerol diethers (DGDs). In addition, archaeal biomarkers, including archaeol, macrocyclic isoprenoidal DGDs and isoprenoidal glycerol dialkyl glycerol tetraethers are also present. Both SRB and archaeal lipid δ¹³C values are depleted in ¹³C (δ¹³C values are typically less than −50‰), which suggests that the SRB and archaea consumed ¹³C depleted methane. These biomarker and isotopic signatures are similar to those found in cold seeps and marine sediments where anaerobic oxidation of methane (AOM) occurs with sulfate serving as the terminal electron acceptor. Association of AOM with formation of greigite-containing ISNs could provide an explanation for documented remagnetization of the Valle Ricca sediments. Upward migration of methane, subsequent AOM and associated authigenic greigite formation are widespread processes in the geological record that have considerable potential to compromise paleomagnetic records.     

The effect of composition,temperature and pressure on the stability of the 1Tc and 2M polytypes of sapphirine

Microprobe analyses and structural characterisation by means of transmission electron microscopy and powder X-ray diffraction are presented for a suite of natural and synthetic sapphirines. Most sapphirines appear to consist of intergrowths of the common 2M polytype with minor amounts of the 1Tc phase, although the converse situation is found in some cases. Attempts to correlate the structural state of the mineral with other factors reveal that: (i) There is no strong relationship between mean tetrahedral cation radius or mean octahedral cation radius and the preferred polytype. The Tschermak substitution M²⁺M⁴⁺-M³⁺M³⁺ does not appreciably influence the 1Tc-2M equilibrium, (ii) However, the total content and mean oxidation state of iron in sapphirine are important in this respect. Fe²⁺ stabilises the 2M phase, whereas Fe³⁺ stabilises the 1Tc phase. (iii) P-T estimates for the host rocks, and estimates for the conditions of sapphirine crystallisation, where obtainable, suggest that the 1Tc phase is stable at lower T and higher P than the 2M phase. Some quantitative constraints are inferred.     

Al,Si ordering in cordierite using “magic angle spinning” NMR

A method of determining the number of Al-O-Al bonds per unit cell from ²⁹Si nuclear magnetic resonance (NMR) data of synthetic cordierites with increasing Si, Al order is described. The number of Al-O-Al bonds is found to vary linearly with the logarithm of the annealing time. This may be correlated with previously published heat of solution data on similar samples (Carpenter et al. 1983) to determine the enthalpy change Δh, associated with a single Al?Si interchange in cordierite. Δh is found to be 8.1 kcal/mole. The NMR data show that the short range Al, Si order cannot be described in terms of twin domains of ordered orthorhombic cordierite. An ordering model derived from group theoretical constraints on possible Al, Si distributions within the hexagonal symmetry of the cordierite is found to provide a better fit to the NMR data.     

Extreme behavior in a triple friction pendulum isolated frame

While isolation can provide significantly enhanced performance compared to fixed‐base counter parts in design level or even maximum considered level earthquakes, there is still uncertainty over the performance of isolation systems in extreme events. Researchers have looked at component level stability of rubber bearings and on the effect of moat impact on behavior of structures isolated on general bilinear isolators. However, testing of triple friction pendulum (TFP) sliding bearings has not been done dynamically or incorporated into a building system. Here, one‐third scale laboratory tests were conducted to on a 2‐story 2‐bay TFP‐isolated structure. Input motions were increasingly scaled until failure occurred at the isolation level. As the superstructure was designed with a yield force equivalent to the force of the bearing just at their ultimate displacement capacity, there was minimal yielding. A numerical model is presented to simulate the isolated building up to and including bearing failure. Forces transferred to the superstructure in extreme motions are examined using both experimental and numerical data. Additionally, the effect of the hardening stage of the TFP bearing is evaluated using the numerical model, finding slight benefits.     

Asteroid 21 Lutetia at 3 μm: Observations with IRTF SpeX

We present observations of Asteroid 21 Lutetia collected 2003–2008 using the SpeX instrument on the NASA Infrared Telescope Facility (IRTF) covering 2–4 μm. We also reevaluate NSFCam observations obtained in 1996 (Rivkin, A.S., Lebofsky, L.A., Clark, B.E., Howell, E.S., Britt, D.T. [2000]. Icarus 145, 351–368). Taken together, these show deeper 3-μm band depths (of order 3–5%) in the southern hemisphere of Lutetia, and shallower band depths (of order 2% or less) in the north. Such variation is consistent with observations at shorter wavelength by previous workers (Nedelcu, D.A. et al. [2007]. Astron. Astrophys. 470, 1157–1164; Lazzarin, M. et al. [2010]. Mon. Not. R. Astron. Soc. 408, 1433–1437), who observed hemispheric-level variations from C-like spectra to X-like spectra.While the shallowness of absorption bands on Lutetia hinders identification of its surface composition, goethite appears plausible as a constituent in its southern hemisphere (Beck, P., Quirico, E., Sevestre, D., Montes-Hernandez, G., Pommerol, A., Schmitt, B. [2011]. Astron. Astrophys. 526, A85–A89). Mathematical models of space weathered goethite are most consistent with Lutetia’s southern hemisphere spectrum, but more work and further observations are necessary to confirm this suggestion.     

Cryptic sequence boundaries in braided fluvial successions

In braided fluvial deposits, consisting of monotonous successions of sandstone or conglomerate, it may be difficult to distinguish regionally significant bounding surfaces (sequence boundaries) from autogenic channel-scour surfaces. Major surfaces may be characterized by erosional relief and draped by lag deposits, but not all sequence boundaries show these characteristics. Other clues to the presence of a major surface are sharp changes in detrital composition, shifts in regional palaeocurrent trends and evidence of early diagenesis of the sandstones immediately below the sequence boundary. Examples of these attributes of cryptic sequence boundaries are illustrated from three Mesozoic units in the Colorado Plateau area of the United States. In the Chinle Formation (Triassic), near Moab, Utah, angular intraformational unconformities overlie sandstones showing evidence of early diagenesis. In the Castlegate Sandstone (Upper Cretaceous) of east-central Utah, a cryptic sequence boundary can be discriminated from other erosion surfaces by the evidence of detrital petrography and early diagenesis. Palaeocurrent data indicate changes in regional palaeoslope at two sequence boundaries within this unit. Evidence of early diagenesis is also present at a sequence boundary in the Kayenta Formation (Jurassic) of westernmost Colorado.     

Structural controls on the formation of BSR over a diapiric anticline from a dense MCS survey offshore southwestern Taiwan

A dense seismic reflection survey with up to 250-m line-spacing has been conducted in a 15 × 15 km wide area offshore southwestern Taiwan where Bottom Simulating Reflector is highly concentrated and geochemical signals for the presence of gas hydrate are strong. A complex interplay between north–south trending thrust faults and northwest–southeast oblique ramps exists in this region, leading to the formation of 3 plunging anticlines arranged in a relay pattern. Landward in the slope basin, a north–south trending diapiric fold, accompanied by bright reflections and numerous diffractions on the seismic profiles, extends across the entire survey area. This fold is bounded to the west by a minor east-verging back-thrust and assumes a symmetric shape, except at the northern and southern edges of this area, where it actively overrides the anticlines along a west-verging thrust, forming a duplex structure. A clear BSR is observed along 67% of the acquired profiles. The BSR is almost continuous in the slope basin but poorly imaged near the crest of the anticlines. Local geothermal gradient values estimated from BSR sub-bottom depths are low along the western limb and crest of the anticlines ranging from 40 to 50 °C/km, increase toward 50–60 °C/km in the slope basin and 55–65 °C/km along the diapiric fold, and reach maximum values of 70 °C/km at the southern tip of the Good Weather Ridge. Furthermore, the local dips of BSR and sedimentary strata that crosscut the BSR at intersections of any 2 seismic profiles have been computed. The stratigraphic dips indicated a dominant east–west shortening in the study area, but strata near the crest of the plunging anticlines generally strike to southwest almost perpendicular to the direction of plate convergence. The intensity of the estimated bedding-guided fluid and gas flux into the hydrate stability zone is weaker than 2 in the slope basin and the south-central half of the diapiric fold, increases to 7 in the northern half of the diapiric fold and plunging anticlines, and reaches a maximum of 16 at the western frontal thrust system. Rapid sedimentation, active tectonics and fluid migration paths with significant dissolved gas content impact on the mechanism for BSR formation and gas hydrate accumulation. As we begin to integrate the results from these studies, we are able to outline the regional variations, and discuss the importance of structural controls in the mechanisms leading to the gas hydrate emplacements.     

Evolving Turbulence Realizations of Atmospheric Flow

A significant difference exists between estimates of contaminant atmospheric transport and dispersion calculated by an ensemble-averaged model and the turbulent details of any particular atmospheric transport and dispersion realization. In some cases, however, it is important to be able to make inferences of these realizations using ensemble-averaged models. It is possible to make such inferences if there are sensors in the field to report contaminant concentration observations. Any information determined about the atmospheric transport and dispersion realization can then be assimilated into a forecast model. This approach can enhance the accuracy of the atmospheric transport and dispersion forecast of a particular event. This work adopts that approach and reports on a genetic algorithm used to optimize the variational problem. Given contaminant sensor measurements and a transport and dispersion model, one can back-calculate unknown source and meteorological parameters. In this case, we demonstrate the dynamic recovery of unknown meteorological variables, including the transport variables that comprise the “outer variability” (wind speed and wind direction) and the dispersion variables that comprise the “inner variability” (contaminant spread). The optimization problem is set up in an Eulerian grid space, where the comparison of the concentration field variable between the predictions and the observations forms the cost function. The transport and dispersion parameters, which are determined from the optimization, are in Lagrangian space. This calculation is applied to continuous and instantaneous releases in a horizontally homogeneous wind field such as that observed during traditional transport and dispersion field experiments. The method proves to be successful at recovering the unknown transport and dispersion parameters for a numerical experiment.     

Carbon,hydrogen and nitrogen isotopes in solvent-extractable organic matter from carbonaceous chondrites

Solvent extractions were done on the carbonaceous chondrites Murray, Murchison, Orgueil and Renazzo, using CCl₄ and CH₃OH. Between 2 and 10% of the total carbon in these meteorites is extractable by ordinary techniques, most of it in CH₃OH. After demineralization with HF, perhaps as much as 30% of the total carbon in Murray may be extractable with CH₃OH. The extracts from Renazzo have isotopic ratios which suggest that they are mainly terrestrial organic matter, with lesser contributions from indigenous organics. The CH₃OH-soluble organic matter from Murchison and both untreated and HF-treated Murray has δ¹³C values of about +5 to + 10%. and δ¹⁵N values of about +90 to +100%., both of which are significantly higher than the bulk meteorite values. The Orgueil CH₃OH-extract also has a δ¹⁵N value well above the value in residual organic matter. Values for δD of +300 to +500%. are found for the CH₃OH-soluble organic matter. The combined data for C, H and N isotopes makes it highly unlikely that the CH₃OH-soluble components are derivable from, or simply related to, the insoluble organic polymer found in the same meteorites. A relationship is suggested between the event that formed hydrous minerals in CI1 and CM2 meteorites and the introduction of water-soluble (methanol-soluble) organic compounds. Organic matter soluble in CCl₄ has essentially no nitrogen, and δ³C and δD values are lower than for CH₃OH-soluble phases. Either there are large isotopic fractionations for carbon and hydrogen between different soluble organic phases, or the less polar components are partially of terrestrial origin.     

Complex replacement patterns in garnets from Bergen Arcs eclogites: A combined EBSD and analytical TEM study

Eclogite-facies rocks within the Bergen Arcs, western Norway, have formed from granulites along shear zones and fluid pathways. Garnets that were inherited from granulite facies protoliths show different types of replacement patterns due to an incomplete eclogitisation process including concentric rim zoning, zoning along vein fillings and inclusion trails, and zoning bands without inclusions. The interfacial part between the granulitic core and the eclogitic rim of garnet as well as the microstructure of other relevant minerals (omphacite, plagioclase) has been analysed using analytical transmission electron microscopy (ATEM). In garnet, the interface is characterised by gradual changes in composition from X_alm=0.31, X_pyr=0.50 to X_alm=0.54, and X_pyr=0.25 within ≈20 μm and exhibits no distinct change in microstructure. Granulitic plagioclase shows exsolution lamellae of the Bøggild intergrowth. In omphacite, anti-phase domains (APDs) which potentially record the temperature of cation ordering after mineral growth have been observed and their size suggest eclogitisation at 600–700 °C. The electron backscatter diffraction (EBSD) analysis revealed that the lattice orientation of the granulitic feldspar is basically unrelated to tectonic axes whereas newly formed eclogitic minerals omphacite and kyanite show a crystallographic relation to the foliation. In garnet, no change in the basic crystallographic orientation between the eclogitic and granulitic garnet composition was confirmed. However, misorientation analysis suggests a cellular microstructure not more than 1° misorientation in the core of the garnets, which is missing in the eclogitic rim indicating textural equilibration of the latter. The heterogeneous replacement patterns are characteristic for dissolution and re-precipitation reactions in an open system limited to fluid availability. The appearance of the compositional profile in garnet is interpreted as a diffusional re-equilibration step after the time-limited, fluid-mediated eclogitisation event that apparently obscured the initially sharp interface within the further retrograde metamorphic history.