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41.
Paul Keller François Fontan André-Mathicu Fransolet 《Contributions to Mineralogy and Petrology》1994,118(3):239-248
Minerals of the triphylite-lithiophilite, Li(Fe, Mn)PO4, and the triplite-zwieselite-magniotriplite series, (Mn, Fe, Mg)2PO4F, occur in the late stage period of pegmatite evolution. Unfortunately, neither are the genetic relationships between these phosphates fully understood nor are thermodynamic data known. Consequently, phosphate associations and assemblages from 8 granitic pegmatites — Clementine II, Rubicon II and III, and Tsaobismund (Namibia); Hagendorf-Süd and Rabenstein (Germany); Valmy (France); Viitaniemi (Finland) — have been tested for compositional zoning and intercrystalline partitioning of main elements by electron microprobe techniques. Although the selected pegmatites display varying degrees of fractionation, and the intergrowth textures indicate different genetic relationships between the phosphates, the plots of mole fractions X
Fe=Fe/(Fe+Mn+Mg+Ca), X
Mn=Mn/(Fe+Mn+Mg+Ca), and X
Mg=Mg/(Fe+Mn+Mg+Ca) can be fitted relatively well with smooth curves in Roozeboom diagrams. Their deviations from symmetrical distribution curves are mainly dependent upon X
Mg or X
Ca, and upon non-ideal solutions. Surprisingly small differences between the partition coefficients were detected for intergrowths of different origin. However, the partitioning of shared components among coexisting phases is clearly dependent upon the conditions of formation. Compositional zoning is observed only when both Fe–Mn phosphates are intergrown mutually or with other Fe–Mn–Mg mineral solid-solutios. Thus, the zoning does not seem to be due to continuous crystallization, but to later diffusion processes. The triplite structure has preference for Mn, Mg, and Ca, while Fe prefers minerals of the triphylite series. A quantification of main element fractionation between minerals of the triphylite and the triplite series is possible in the cases where diffusion can be excluded. For the Fe/(Fe+Mn) ratios of core compositions an equation with a high correlation coefficient (R=0.988) was determined: Fe/(Fe+Mn)Tr=[Fe/(Fe+Mn)Li]/{2.737-(1.737)[Fe/(Fe+Mn)Li]} (Tr=triplite series, Li=triphylite series). Consequently, the Fe/(Fe+Mn) ratio of the triplite series can now also be used in the interpretation of pegmatite evolution, just like that of the triphylite series which has been successfully applied in the past. 相似文献
42.
43.
Some turbiditic measures carried out by a limnological diffusiometer along with the physico-chemical determinations of the
Lake of Neuchatel have permitted to subdivide the water column in 4 distinct layers: the Epilimnium, the Clear Water Layer,
the Pelagic Nepheloid Layer and the Benthic Nepheloid Layer.
相似文献
44.
A least-squares prediction method is described to estimate horizontal coordinate distortions at lower order points of a network
using known coordinate differences (NAD27 coordinate distortions Δϕ′s and Δλ′s) at higher order points between NAD27 coordinates
and coordinates derived from a recent (MAY 76), relatively distortion free, adjustment of these points. Empirical autocovariance
functions of Δϕ and Δλ and crosscovariance function between Δϕ and Δλ are derived from some 5,250 data points and modelled
using series of exponential functions. Empirical mean square values of Δϕ and Δλ, which are a measure of the distortions in
NAD27 ϕ and λ, are 0.051 and 0.645 arcsecs2 respectively. The corresponding mean value of the product ΔϕΔλ, which is a measure of the correlation between Δϕ and Δλ,
is 0.056 arcsecs2. The accuracy obtainable for predicted Δϕ and Δλ at an arbitrary point (e.g., lower order station) is a function of the accuracy
and configuration of known Δϕ′s and Δλ′s in the surrounding area. Accuracies obtainable for various types of data configuration
are given. Under favorable conditions taking place in about 60% of cases, accuracies in terms of ms agreement with known values
of 0″.02 (0.6 m) and 0″.01 (0.2 m along parallel at latitude 50°) for the predicted latitude and longitude distortions are
obtainable. Finally, a comparison with a method based on the use of complex polynomials is made.
Presented at International Symposium on Geodetic Networks and Computations, Munich, August–September 1981. 相似文献
45.
André Lacam 《Physics and Chemistry of Minerals》1983,9(3-4):127-132
The objectives of this study of olivines are, to calibrate the variation of electrical conductivity with pressure, up to 200 kbar in a diamond-anvil cell, and to determine how this is influenced by chemical composition. Experimentally, we have found that the variation of the electrical conductivity of three synthetic olivines containing 50, 75 and 100 mole percent of fayalite, is an exponential function of pressure P, closely represented at room temperature by:σxP=σx·exp ·(B x·P) where x is the iron content of the olivine, σ x the extrapolated value of conductivity at normal pressure and B x the slope of the regression line in semi-logarithmic coordinates. It is thus possible to express the temperature dependence of conductivity through the Boltzmann relationship:σxPT= σαT· exp ·(-H*/RT)=σxT·exp ·[-(E*+PV * x )/RT] where H* is the activation enthalpy, E* the activation energy and V x * the activation volume. At constant temperature V * x =B x·RT and is approximately equal to 0,6 cm3/mole at 295 K. On the other hand, we have found that σxT is an exponential function of x and thus, B x and of course V x * are linear functions. The experimental procedure is described and the results discussed. 相似文献
46.
47.
André Deprit Jesúus Palacián Etienne Deprit 《Celestial Mechanics and Dynamical Astronomy》2001,79(3):157-182
The relegation algorithm extends the method of normalization by Lie transformations. Given a Hamiltonian that is a power series = 0+ 1+ ... of a small parameter , normalization constructs a map which converts the principal part 0into an integral of the transformed system — relegation does the same for an arbitrary function [G]. If the Lie derivative induced by [G] is semi-simple, a double recursion produces the generator of the relegating transformation. The relegation algorithm is illustrated with an elementary example borrowed from galactic dynamics; the exercise serves as a standard against which to test software implementations. Relegation is also applied to the more substantial example of a Keplerian system perturbed by radiation pressure emanating from a rotating source.This revised version was published online in October 2005 with corrections to the Cover Date. 相似文献
48.
André Strasser 《Swiss Journal of Geoscience》2007,100(3):407-429
Detailed investigation of facies and sedimentary structures reveals that, during the Middle Oxfordian to Late Kimmeridgian,
the shallow carbonate platform of the Swiss and French Jura Mountains recorded high-frequency sea-level fluctuations quite
faithfully. The cyclostratigraphic analysis within the established biostratigraphic and sequence-chronostratigraphic framework
implies that the resulting hierarchically stacked depositional sequences formed in tune with the orbital cycles of precession
(20 kyr) and eccentricity (100 and 400 kyr). The astronomical time scale presented here is based on the correlation of 19
platform sections and 4 hemipelagic sections from south-eastern France where good biostratigraphic control is available. The
cyclostratigraphic interpretation suggests that the interval between sequence boundaries Ox4 and Kim1 (early Middle Oxfordian
to earliest Kimmeridgian) lasted 3.2 myr and that the Kimmeridgian sensu gallico has a duration of 3.2 to 3.3 myr. The astronomical time scale proposed here is compared to time scales established by other
authors in other regions and the discrepancies are discussed. Despite these discrepancies, there is a potential to estimate
the durations of ammonite zones and depositional sequences more precisely and to better evaluate the rates of sedimentary,
ecological and diagenetic processes.
Editorial handling: Hanspeter Funk, Helmut Weissert, Stefan Bucher 相似文献
49.
André Salgado César Varajão Fabrice Colin Régis Braucher Angélica Varajão Herminio Nalini Jr 《地球表面变化过程与地形》2007,32(6):905-911
The present work quantifies the erosive processes in the two main substrates (schists–phyllites and granites–gneisses) of the upper Maracujá Basin in the Quadrilátero Ferrífero/MG, Brazil, a region of semi‐humid tropical climate. Two measuring methods of concentration were used: (i) in situ produced 10Be in quartz veins (surface erosion rates) and (ii) 10Be in fluvial sediments (basin erosion rates). The results confirm that (i) erosion tends to be more aggressive close to the headwaters than in the lower parts of the basin and (ii) the region is now affected by dissection. Copyright © 2006 John Wiley & Sons, Ltd. 相似文献
50.
A comprehensive model inter-comparison study investigating the water budget during the BALTEX-PIDCAP period 总被引:2,自引:0,他引:2
D. Jacob B. J. J. M. Van den Hurk U. Andræ G. Elgered C. Fortelius L. P. Graham S. D. Jackson U. Karstens Chr. Köpken R. Lindau R. Podzun B. Rockel F. Rubel B. H. Sass R. N. B. Smith X. Yang 《Meteorology and Atmospheric Physics》2001,77(1-4):19-43
Summary A comparison of 8 regional atmospheric model systems was carried out for a three-month late summer/early autumn period in
1995 over the Baltic Sea and its catchment area. All models were configured on a common grid using similar surface and lateral
boundary conditions, and ran in either data assimilation mode (short term forecasts plus data assimilation), forecast mode
(short term forecasts initialised daily with analyses) or climate mode (no re-initialisation of model interior during entire
simulation period). Model results presented in this paper were generally post processed as daily averaged quantities, separate
for land and sea areas when relevant. Post processed output was compared against available analyses or observations of cloud
cover, precipitation, vertically integrated atmospheric specific humidity, runoff, surface radiation and near surface synoptic
observations.
The definition of a common grid and lateral forcing resulted in a high degree of agreement among the participating model results
for most cases. Models operated in climate mode generally displayed slightly larger deviations from the observations than
the data assimilation or forecast mode integration, but in all cases synoptic events were well captured. Correspondence to
near surface synoptic quantities was good. Significant disagreement between model results was shown in particular for cloud
cover and the radiative properties, average precipitation and runoff. Problems with choosing appropriate initial soil moisture
conditions from a common initial soil moisture field resulted in a wide range of evaporation and sensible heat flux values
during the first few weeks of the simulations, but better agreement was shown at later times.
Received September 8, 2000 Revised April 3, 2001 相似文献