“Mysterite” : a late condensate from the solar nebula

We have attempted to clarify the nature of “mysterite”, a material that had been postulated to explain the overabundance of Tl, Bi and Ag in certain chondrites. Four dark clasts and a vein sample from the H6 chondrite Supuhee were analyzed by radiochemical neutron activation analysis for Ag, Au, Bi, Br, Cd, Cs, Ge, In, Ir, Ni, Os, Rb, Re, Sb, Se, Te, Tl and Zn. One of the clasts is enriched in all volatile elements, while the other 4 samples are enriched only in the siderophile volatiles Ag, Bi and Tl. The enrichments range up to 100 times typical H6 chondrite abundances. The proportions of Ag, Bi, Tl suggest the presence of at least two, Tl-rich and Tl-poor, varieties of mysterite ($\text{Tl}\text{Bi}\text{= 7.2}$ and <0.1). The former seems to dominate in Supuhee and Krymka, and the latter in Mezö-Madaras. Apparently mysterite is a late condensate from the solar nebula that collected volatiles left behind by earlier generations of chondrites. It was incorporated in Supuhee and perhaps in other chondrites (mainly of low petrologic types) during brecciation events.     

On lipid surface films on the sea. I. A simple method for sampling and studies of composition

A method for collection of surface films on the sea has been developed and tested at various places along the Swedish West Coast. Considerable amounts of lipids on the sea surface were found even when no seaslicks were observed. Triglycerides, free fatty acids, and wax esters are the dominating constituents, and there are characteristic deviations in the fatty-acid patterns compared to the corresponding lipids dissolved in the sub-surface water. Organochlorine residues, phthalic acid esters and heavy metals also occur in considerable amounts.     

Fluxes of iron and manganese across the sediment–water interface under various redox conditions

Fluxes of dissolved forms of iron and manganese across the sediment–water interface were studied in situ in the Gulf of Finland and the Vistula Lagoon (Baltic Sea), and in the Golubaya Bay (Black Sea) from 2001 to 2005. Fluxes were measured using chamber incubations, and sediment cores were collected and sliced to assess the porewater and solid phase metal distribution at different depths. Measured and calculated benthic fluxes of manganese and iron were directed out of sediment for all sites and were found to vary between 70–4450 and 5–1000 µmole m^− 2 day^− 1 for manganese and iron, respectively. The behavior of the studied metals at various redox conditions in the near-bottom water and in the sediment was the main focus in this study. Our results show the importance of bottom water redox conditions for iron fluxes. We measured no fluxes at oxic conditions, intermediate fluxes at anoxic conditions (up to 200 μmole m^− 2 day^− 1) and high fluxes at suboxic conditions (up to 1000 μmole m^− 2 day^− 1). Total dissolved iron fluxes were generally dominated by iron(II). Contribution of iron(III) to the total iron flux did not exceed 20%. Obtained fluxes of manganese at all studied regions showed a linear correlation (r² = 0.97) to its concentration in the porewater of the top sediment layer (0–5 mm) and did not depend on dissolved oxygen concentrations of bottom water. Organically complexed iron and manganese were in most cases not involved in the benthic exchange processes.     

A study on the fractionation of organic matter in natural water by ultrafiltration techniques

Diaflo ultrafilters have been studied for the fractionation of organic matter in natural water. One method for their use, including pretreatment, is described. The filter retention is not only depending on the weight of the molecule but also on the charge as shown by experiments with dyestuffs and inorganic ions. For pure solutions of phosphate and nitrate the retentions were 77 and 27% respectively. Filter UM 2, with a nominal molecular weight cutoff at 1,000, retained coloured and total organic matter to 94 and 91% respectively. UM 10 (10,000) retained coloured matter to 88%. Through filtrations the binding of calcium to organic in water was found to be 1 to 10%.     

How well do we know “Cosmic” abundances?

Five lines of evidence suggest that Cl chondrites closely approximate the condensable fraction of primordial solar-system matter: continuity of isotopic and elemental abundance trends, agreement with solar and cosmic-ray abundances, fractionation patterns among chondrites, and absence of chondrules. Maximum differences between Cl abundances and true solar-system abundances are estimated as factors of 2–5 for individual elements and a factor of 1.5 or less for groups of 10 or more elements.     

Temporal and life history related trends of perfluorochemicals in harbor porpoises from the Danish North Sea

Eighty-five stranded or bycaught harbor porpoises collected from the Danish North Sea between 1980 and 2005 were analyzed for perfluorochemicals in the liver. PFOS was the predominant compound, making up on average 88.9% of the ∑PFC, followed by PFOSA (7.8%). PFUnA (1.9%) and PFDA (1.2%) were detected in most samples. PFHxS, PFNA and PFOA were only found in a minority of the samples. We found substantial differences in PFC concentrations among life history stages, the highest concentrations were found in neonates, suckling juveniles and lactating females. Such differences should be considered when PFC levels in wildlife are evaluated. The high concentrations found in young porpoises are of concern as PFCs have known toxic effects on the development of the central nervous system and reproductive organs. Despite efforts to reduce PFC emissions, a decreasing temporal trend of concentrations was not detected for any compound. PFCA concentrations were found to be increasing.     

Propagation of the Storegga tsunami into ice‐free lakes along the southern shores of the Barents Sea

Deposits in coastal lakes in northernmost Norway reveal that the Storegga tsunami propagated well into the Barents Sea ca. 8100–8200 years ago. A tsunami deposit – found in cores from five coastal lakes located near the North Cape in Finnmark – rests on an erosional unconformity and consists of graded sand layers and re‐deposited organic remains. Rip‐up clasts of lake mud, peat and soil suggest strong erosion of the lake floor and neighbouring land. Inundation reached at least 500 m inland and minimum vertical run‐up has been reconstructed to 3–4 m. In this part of the Arctic coastal lakes are usually covered by >1 m of solid lake ice in winter. The significant erosion and deposition of rip‐up clasts indicate that the lakes were ice free and that the ground was probably not frozen. We suggest that the Storegga slide and ensuing tsunami happened sometime in the summer season, between April and October. Copyright © 2011 John Wiley & Sons, Ltd.     

Radio observations of Comet 9P/Tempel 1 before and after Deep Impact

Comet 9P/Tempel 1 was the target of a multi-wavelength worldwide investigation in 2005. The NASA Deep Impact mission reached the comet on 4.24 July 2005, delivering a 370-kg impactor which hit the comet at 10.3 km s⁻¹. Following this impact, a cloud of gas and dust was excavated from the comet nucleus. The comet was observed in 2005 prior to and after the impact, at 18-cm wavelength with the Nançay radio telescope, in the millimeter range with the IRAM and CSO radio telescopes, and at 557 GHz with the Odin satellite. OH observations at Nançay provided a 4-month monitoring of the outgassing of the comet from March to June, followed by the observation of H₂O with Odin from June to August 2005. The peak of outgassing was found to be around between May and July. Observations conducted with the IRAM 30-m radio telescope in May and July 2005 resulted in detections of HCN, CH₃OH and H₂S with classical abundances relative to water (0.12, 2.7 and 0.5%, respectively). In addition, a variation of the HCN production rate with a period of 1.73±0.10 days was observed in May 2005, consistent with the 1.7-day rotation period of the nucleus. The phase of these variations, as well as those of CN seen in July by Jehin et al. [Jehin, E., Manfroid, J., Hutsemékers, D., Cochran, A.L., Arpigny, C., Jackson, W.M., Rauer, H., Schulz, R., Zucconi, J.-M., 2006. Astrophys. J. 641, L145-L148], is consistent with a rotation period of the nucleus of 1.715 days and a strong variation of the outgassing activity by a factor 3 from minimum to maximum. This also implies that the impact took place on the rising phase of the “natural” outgassing which reached its maximum ≈4 h after the impact. Post-impact observations at IRAM and CSO did not reveal a significant change of the outgassing rates and relative abundances, with the exception of CH₃OH which may have been more abundant by up to one order of magnitude in the ejecta. Most other variations are linked to the intrinsic variability of the comet. The Odin satellite monitored nearly continuously the H₂O line at 557 GHz during the 38 h following the impact on the 4th of July, in addition to weekly monitoring. Once the periodic variations related to the nucleus rotation are removed, a small increase of outgassing related to the impact is present, which corresponds to the release of ≈5000±2000 tons of water. Two other bursts of activity, also observed at other wavelengths, were seen on 23 June and 7 July; they correspond to even larger releases of gas.