Fluorite Deposits at Voznesenka in the Khanka Massif, Russia: Geology and Age of Mineralization

Abstract. A huge fluorite deposit at Voznesenka in the Khanka massif, Far East Russia is concluded to have formed at ca. 450 Ma in Late Ordovician time based on the K‐Ar ages for Li‐micas in the fluorite ore and greisenized leucogranite within the deposit. This conclusion is inconsistent with the current view of Devonian mineralization that stemmed from widely scattered whole‐rock Rb‐Sr isotope data for the heterogeneous leucogranite stocks influenced by strong alteration. The Voznesenka and neighboring fluorite deposits may have formed in Cambrian limestone in relation to the intrusion of the Li‐F‐rich felsic magma which has a similar chemistry to representative Li‐F‐rich felsic rocks including topaz granite and ongonite or topaz rhyolite; these rocks may be classified as a specific group of highly fractionated felsic magmas. Biotite granite plutons exposed in the Voznesenka district are divided in age into two groups based on the CHIME age data for zircon, monazite and xenotime: Ordovician and Permian. The Ordovician plutons seem to be coeval to the fluorite deposits and are characterized by F‐rich chemistry, reduced nature and association of tin mineralization with the deposition of fluorite and tourmaline. The biotite granite magmas of initially enhanced F contents could have been highly fractionated to form Li‐F‐rich leucogranite cupolas that provided fluorite deposits within the host limestone. Future prospecting for similar fluorite deposits is to be focused on areas of intersection between Ordovician Li‐F‐rich granite and Cambrian carbonate sequences. The Permian granite of southeastern margin of the Grodekovo batholith is characterized by lesser F content, oxidized nature and the lack of tin and fluorite mineralization in contrast to the Ordovician granite. The result of Permian age does not support the current view of Silurian age for the batholith and requires overall chronological reinvestigation in connection with the tectonic history of the Khanka massif because the Grodekovo is a representative of Paleozoic batholiths in Primorie.     

A spatial comparison of four satellite derived 1 km global land cover datasets

Global change issues are high on the current international political agenda. A variety of global protocols and conventions have been established aimed at mitigating global environmental risks. A system for monitoring, evaluation and compliance of these international agreements is needed, with each component requiring comprehensive analytical work based on consistent datasets. Consequently, scientists and policymakers have put faith in earth observation data for improved global analysis. Land cover provides in many aspects the foundation for environmental monitoring [FAO, 2002a. Proceedings of the FAO/UNEP Expert Consultation on Strategies for Global Land Cover Mapping and Monitoring. FAO, Rome, Italy, 38 pp.]. Despite the significance of land cover as an environmental variable, our knowledge of land cover and its dynamics is poor [Foody, G.M., 2002. Status of land cover classification accuracy assessment. Rem. Sens. Environ. 80, 185–201]. This study compares four satellite derived 1 km land cover datasets freely available from the internet and in wide use among the scientific community. Our analysis shows that while these datasets have in many cases reasonable agreement at a global level in terms of total area and general spatial pattern, there is limited agreement on the spatial distribution of the individual land classes. If global datasets are used at a continental or regional level, agreement in many cases decreases significantly. Reasons for these differences are many—ranging from the classes and thresholds applied, time of data collection, sensor type, classification techniques, use of in situ data, etc., and make comparison difficult. Results of studies based on global land cover datasets are likely influenced by the dataset chosen. Scientists and policymakers should be made aware of the inherent limitations in using current global land cover datasets, and would be wise to utilise multiple datasets for comparison.     

Kobyashevite, Cu5(SO4)2(OH)6·4H2O, a new devilline-group mineral from the Vishnevye Mountains, South Urals, Russia

A new mineral kobyashevite, Cu₅(SO₄)₂(OH)₆·4H₂O (IMA 2011–066), was found at the Kapital’naya mine, Vishnevye Mountains, South Urals, Russia. It is a supergene mineral that occurs in cavities of a calcite-quartz vein with pyrite and chalcopyrite. Kobyashevite forms elongated crystals up to 0.2 mm typically curved or split and combined into thin crusts up to 1?×?2 mm. Kobyashevite is bluish-green to turquoise-coloured. Lustre is vitreous. Mohs hardness is 2½. Cleavage is {010} distinct. D(calc.) is 3.16 g/cm³. Kobyashevite is optically biaxial (?), α 1.602(4), β 1.666(5), γ 1.679(5), 2 V(meas.) 50(10)°. The chemical composition (wt%, electron-microprobe data) is: CuO 57.72, ZnO 0.09, FeO 0.28, SO₃ 23.52, H₂O(calc.) 18.39, total 100.00. The empirical formula, calculated based on 18 O, is: Cu_4.96Fe_0.03Zn_0.01S_2.01O_8.04(OH)_5.96·4H₂O. Kobyashevite is triclinic, $ P\overline{\,1 } $ , a 6.0731(6), b 11.0597(13), c 5.5094(6)?Å, α 102.883(9)°, β 92.348(8)°, γ 92.597(9)°, V 359.87(7)?ų, Z?=?1. Strong reflections of the X-ray powder pattern [d,Å-I(hkl)] are: 10.84–100(010); 5.399–40(020); 5.178–12(110); 3.590–16(030); 2.691–16(20–1, 040, 002), 2.653–12(04–1, 02–2), 2.583–12(2–11, 201, 2–1–1), 2.425–12(03–2, 211, 131). The crystal structure (single-crystal X-ray data, R?=?0.0399) сontains [Cu₄(SO₄)₂(OH)₆] corrugated layers linked via isolated [CuO₂(H₂O)₄] octahedra; the structural formula is CuCu₄(SO₄)₂(OH)₆·4H₂O. Kobyashevite is a devilline-group member. It is named in memory of the Russian mineralogist Yuriy Stepanovich Kobyashev (1935–2009), a specialist on mineralogy of the Urals.     

Seasonal variability of element fluxes in two Central Siberian rivers draining high latitude permafrost dominated areas

In order to constrain the origin and fluxes of elements carried by rivers of high latitude permafrost-dominated areas, major and trace element concentrations as well as Sr and U isotopic ratios were analyzed in the dissolved load of two Siberian rivers (Kochechum and Nizhnyaya Tunguska) regularly sampled over two hydrological cycles (2005-2007). Large water volumes of both rivers were also collected in spring 2008 in order to perform size separation through dialysis experiments. This study was completed by spatial sampling of the Kochechum watershed carried out during summer and by a detailed analysis of the main hydrological compartments of a small watershed. From element concentration variations along the hydrological cycle, different periods can be marked out, matching hydrological periods. During winter baseflow period (October to May) there is a concentration increase for major soluble cations and anions by an order of magnitude. The spring flood period (end of May-beginning of June) is marked by a sharp concentration decrease for soluble elements whereas dissolved organic carbon and insoluble element concentrations strongly increase.When the spring flood discharge occurs, the significant increase of aluminum and iron concentrations is related to the presence of organo-mineral colloids that mobilize insoluble elements. The study of colloidal REE reveals the occurrence of two colloid sources successively involved over time: spring colloids mainly originate from the uppermost organic-rich part of soils whereas summer colloids rather come from the deep mineral horizons. Furthermore, U and Sr isotopic ratios together with soluble cation budgets in the Kochechum river impose for soluble elements the existence of three distinct fluxes over the year: (a) at the spring flood a surface flux coming from the leaching of shallow organic soil levels and containing a significant colloidal component (b) a subsurface flux predominant during summer and fall mainly controlled by water-rock interactions within mineral soils and (c) a deep groundwater flux predominant during winter which enters large rivers through unfrozen permafrost-paths. Detailed study of the Kochechum watershed suggests that the contribution of this deep flux strongly depends on the depth and continuous nature of the permafrost.     

A multi-method approach to dating middle and late Quaternary high relative sea-level events on NW Svalbard – A case study

Waxing and waning ice sheets and changing sea levels have been interpreted from the Quaternary stratigraphic record at Leinstranda, Brøggerhalvøya in NW Svalbard. We have identified seven high relative sea-level events, related to glacio-isostatic loading, and separated by at least four glacial events. To establish a chronology for the high sea-level events (interstadials and interglacials) and the intervening glaciations, we have used three different absolute dating methods: optically stimulated luminescence (OSL) of shallow marine deposits, and electron spin resonance (ESR) and radiocarbon (AMS-¹⁴C) dating of fossils contained in these sediments. Of the absolute dating methods, OSL has provided the stratigraphically most consistent dataset and which also matches a biostratigraphically inferred interglacial. The ESR ages of mollusc shells suffer from low precision due to unusually large uranium content in most dated shell samples, which in turn is most likely a result of significant recent uranium enrichment of the sediments. Most radiocarbon ages are non-finite. The results show that the high relative sea-level events range in age from the Saalian sensu lato (≥Marine Isotope Stage, MIS, 6) to the early Holocene (MIS 1), and include events OSL-dated to 185 ± 8 ka, 129 ± 10 ka, 99 ± 8 ka and 36 ± 3 ka. The methods used by us and by previous investigators of the same site are compared and assessed, and sources of error, accuracy and precision of ages are discussed.     

高压脉冲放电技术成桩法

主要介绍了高压脉冲放电技术的发展现状、成桩机理、成桩特点以及成桩的新工艺。该成桩方法具有高的承载能力和经济效益,具有其它桩所不具有的优点。还对其成桩技术的应用前景进行了展望。     

Variation Trend and Characteristics of Anthropogenic CO Column Content in the Atmosphere over Beijing and Moscow

The anthropogenic CO column content in the atmosphere is derived from measurements with infrared grating spectrometers in Beijing, China, and Moscow, Russia, during 1992-2012. Some specific variation char- acteristics and long-term variation trends of the CO col- umn content in the atmosphere in these regions are dis- cussed. An evident variation trend of anthropogenic CO in the atmosphere for the Beijing region is not observed during 1992-2012, while for the Moscow region, it de- creases yearly by about 1.4% for the same period. High CO concentrations appear quite frequently in Beijing, but much less frequently in Moscow, except during the natu- ral fire events in summer 2010. From back trajectory analysis, the high CO concentration observed in Beijing can be attributed to the intensive CO emission sources in its surrounding areas.     

Tectonics of Venus: A review

The article presents a new tectonic scheme of Venus and gives the following interpretation of the planet's main structural units: (1) plains — areas of flood volcanism over stretched crust; (2) dome-like uplifts — areas of uplifting and volcanic activity above the mantle hot-spots; (3) coronae —former dome-like uplifts, partially subsided and diffused by gravity; (4) ridge belts — fold zones; (5) tesserae — fragments of ductile compression and shortening of crust; (6) supercoronae — coronae formed in the course of further evolution and relaxation of Beta-type uplifts. Ishtar Terra is considered to be a fragment of an ancient tessera paleocontinent, on the edge of which the Lakshmi supercorona is superimposed. Aphrodite Terra is considered as a belt of mantle hot-spot structures (dome-like uplifts, coronae, supercoronae, volcanoes, rifts).Three types of planetary belts have been distinguished on Venus: uplifted 'weakened' belts with an abundance of mantle hot-spot structures; a northern fan of ridge belts; and belts of low basalt plains. The center of the planetary system of uplifted weakened belts is situated in Atla Regio.The present tectonic structure of Venus is inferred to have formed during two stages of evolution characterized by different tectonic regimes. Stage I is a regime of soft ductile plates (formation of tessera uplifts and volcanic plains). Stage II is a formation of 'weakened' uplifted planetary belts, various tectonic regimes of mantle hot-spots, and plains-forming volcanism.'Geology and Tectonics of Venus', special issue edited by Alexander T. Basilevsky (USSR Acad. of Sci. Moscow), James W. Head (Brown University, Providence), Gordon H. Pettengill (MIT, Cambridge, Massachusetts) and R. S. Saunders (J.P.L., Pasadena).