Evaluation of oxygen isotopes in carbonate as an indicator of lake evolution in arid areas: The modern Qinghai Lake, Qinghai–Tibet Plateau

The oxygen isotopic composition of carbonate in lakes has been used as a useful indicator in Palaeolimnological research, and has made some important contributions to our understanding of lacustrine systems. For modern lakes in arid or cold areas, however, there are few data available to test the effect of lake salinity and temperature on the oxygen isotopic composition of various carbonate sources such as ostracod, bulk carbonate, and fine-grained carbonate (< 60 μm). Here we examined the oxygen isotopic composition of ostracods, bulk carbonate, and fine-grained carbonates, as well as that of coexisting water from Lake Qinghai and the smaller surrounding lakes and ponds on the Qinghai–Tibet Plateau. Our investigation highlights three key effects. First, the oxygen isotopic composition of ostracods, bulk carbonate, and fine-grained carbonate in the lakes and ponds shows a clear response to lake water δ¹⁸O values, and these vary with water salinity. The relationship between lake water δ¹⁸O and salinity is not only dominated by the evaporation/freshwater input ratios, but is also controlled by the distance to the mouth of the major rivers supplying to the lake. Second, the ostracod, bulk carbonate, and fine-grained carbonate show similar isotopic change trends in the study area, and oxygen isotopic differences between ostracods and authigenic carbonate may be explained by the different water temperatures and very small ‘vital offsets’ of ostracods. Finally, the effect of water depth on temperature leads to increasing δ¹⁸O values in carbonates as water depth increases, both in benthic ostracods living on the lake bottom, as well as in bulk carbonate precipitated at the water surface.For arid, high-altitude Lake Qinghai, our results suggest that variations in the δ¹⁸O values of carbonate in Lake Qinghai are mainly controlled by the oxygen-isotope ratio of the lake water changing with water salinity. As a secondary effect, increasing water depth leads to cooler bottom and surface water, which may result in more positive δ¹⁸O values of ostracod and bulk carbonate.     

生烃动力学模拟实验结合GC-RMS测定在有效气源岩判识中的应用

采用动力学模拟实验对Ⅰ型干酪根的生烃过程进行了模拟,并对热解产物中的正烷烃组分进行了GC-IRMS分析。分析结果表明,当Ro<1.6%时,C8+正烷烃的碳同位素组成主要继承了母质的特征,而随热演化程度的变化不显著,因此可用于油(气)/源对比。当Ro在1.6%～2.0%之间时,C8+正烷烃迅速裂解,其δ13C显著增重。Ro>2.0%之后,C1—C4气态烃随热演化程度的增加,逐渐富集13C,其δ13C与Ro之间的关系明显受升温速率的影响,所以由模拟实验获得的δ13C1-Ro关系式不适用于高—过成熟的气源岩研究;而δ13C1-F(甲烷生成率)的关系则不受升温速率的影响,适用范围较宽,故可用于高演化阶段的有效气源岩的判识。     

银催化HDEA电化学发光法测定矿样中的痕量银

在碱性介质中,痕量Ag(Ⅰ)对新试剂6-(2-羟基-4-二乙基氨苯偶氮)-2,3-二氢-1,4-酞嗪二酮(简称HDEA)的电化学发光具有显著的催化作用。基于此,提出了HDEA-KCI-KOH体系测定矿样中痕量Ag的新方法。方法的检测限为2.0×10~(-8)mol/L Ag,线性范围为5.0×10~(-8)—3.0×10~(-6)mol/L Ag。采用巯基棉富集分离,应用本法测定一些矿样中的Ag,结果良好。     

The effects of soil sand contents on characteristics of humic acids along soil profiles

It is generally accepted that the compositions and properties of soil organic matter (SOM) are influenced by many factors. In order to reveal the effects of soil texture on characteristics and dynamics of SOM and its sub-fraction, humic acid (HA), along two soil profiles, a yellow soil profile and a purplish soil profile, under the same climate and vegetation conditions were determined. Results indicate that the decomposition and humification degrees of SOM and HA of the purplish soils are higher than those of the corresponding yellow soils indicated by A/O–A ratios of HAs, TOCs and HA yields of bulk soil samples, nevertheless, the development degree of the purplish soil is lower than that of the yellow soil. The variations of E₄/E₆ ratios of HAs along the soil profiles indicate the overall molecular sizes of HAs decreased downward along the soil profiles. A/O–A ratios of HAs decreased downward along both the soil profiles indicate that humification processes decrease downward along both the soil profiles. Leaching of SOM shows significant effects on the distribution and characteristics of HAs in the yellow soil profile but the purplish soil profile, which is consistent with the higher hydrophobicity of HAs in purplish soils, shows that the distribution characteristics of SOM along the soil profiles are a complex result of the combination of soil texture and characteristics of SOM itself. The remarkably different sand contents are concluded tentatively as one of reasons to the different distributions and dynamics of HAs along the soil profiles, however, to profoundly understand the evolution and transport of SOM along soil profiles needs more researches.     

Review of Earth Critical Zone Research

Since the Earth Critical Zone put forward by National Research Council of America in 2001, it has got a lot of attention and some significant progresses have been made. This paper summarized those Earth Critical Zone projects and related research plans organized and implemented by the United States of America, Germany, Australia, France, China and the European Union, as well as main scientific problems and future development direction in the study of Earth Critical Zone. According to research status of China, the four main research contents should be strengthened including structure, formation and evolution mechanism of Earth Critical Zone, the coulpling interaction mechanism between migration and transformation of material and multi-processes, sevice function and evolution features of Earth Critical Zone and its support and effect on sustainable development, model simulation of process and system of Earth Critical Zone. In addition, our country should actively conduct cooperation and communication with the advanced countries, and enhance our involvement in international key research plans.     

森林沼泽景观区区域化探新、旧方法技术应用效果对比

自森林沼泽景观区1∶20万区域化探工作开展以来,各个单位、不同阶段工作方法技术各有不同,工作效果不明显。中国地质科学院地球物理地球化学勘查研究所近年来通过研究制定了新的工作方法技术,通过应用取得了较好的效果,为此本文仅以内蒙古一二五公里幅1∶20万区域化探新、旧方法技术的应用效果对比进行初步探讨。     

Numerical Simulation of Drag Partition over Rough Surfaces

We present a numerical simulation of drag partition over rough surfaces. A computational fluid dynamics model is applied with high resolution to simulatingturbulent flows over arrays of roughness elements positioned on asmooth surface. The skin drag on the surface and the pressure drag on the roughnesselements are computed. The simulated drag partition compares well with wind-tunnelmeasurements and theoretical estimates for similar rough surfaces. This confirms that the computational approach offers an alternative to wind-tunnel and field experiments in studying drag and drag partition. The model is then applied to studying drag partition over rough surfaces with various roughness configurations. It is shown that drag partition depends not only on the magnitude of the roughness frontal area but also on the sizes and arrangement of roughness elements, because (1) the pressure drag coefficient is sensitive to roughness-element dimensions and (2) the arragement of roughness elements lead to different interferences of turbulent wakes. The impact ofthe latter factor is not insignificant.     

The impact of tropical western Pacific convection on the North Pacific atmospheric circulation during the boreal winter

In this study, we investigate the impact of atmospheric convection over the western tropical Pacific (100–145°E, 0–20°N) on the boreal winter North Pacific atmosphere flow by analyzing National Center for Environmental Prediction Reanalysis 1, Extended Reconstructed Sea Surface Temperature and Global Precipitation Climatology Project data. The western tropical Pacific convection is not only the main energy source driving the local Hadley and Walker circulations, but it also significantly influences North Pacific circulation, by modifying a mid-latitude Jet stream through the connection with the local Hadley circulation. On the one hand, this strong convection leads to a northward expansion of local Hadley cells simultaneous with a northward movement of the western North Pacific jet because of the close correlation between the Jet and Hadley circulation boundaries. On the other hand, this strong convection also intensifies tropical Pacific Walker circulation, which reduces the eastern Pacific sea surface temperature, resembling a La Nina state through the enhanced equatorial upwelling. The cooling of the eastern tropical Pacific has an inter-tropical convergence zone located further north; thus, the local Hadley circulation moves northward. As a result, the jet axis over the eastern North Pacific, which also corresponds to the boundary of the local Hadley circulation, moves to higher latitude. Consequently, this northward movement of the Jet axis over the North Pacific is reflected as a northwest–southeast dipole sea level pressure (SLP) pattern. The composite analysis of SLP over the North Pacific against the omega (Ω) (Pa/s) at 500 hPa over the western tropical Pacific actually reveals that this northwest-southeast dipole structure is attributed to the intensified tropical western Pacific convection, which pushes the Pacific Jet to the north. Finally we also analyzed south Pacific for the austral winter as did previously to North Pacific, and found that the results were consistent.     

Impact of reservoir operation and climate change on the hydrological regime of the Sesan and Srepok Rivers in the Lower Mekong Basin

The transboundary Sesan and Srepok sub-basins (2S) are the “hot-spot” areas for reservoir development in the Lower Mekong region, with 12 reservoirs built in the Vietnam territory. This study examines the impacts of reservoir operations in Vietnam and projected climate change on the downstream hydrologic regime of the 2S Rivers by jointly applying the Soil Water Assessment Tool (SWAT) and Water Evaluation and Planning (WEAP) models. Different scenarios of reservoir operation are considered and simulated to assess their impact on annual, seasonal, and monthly flow regimes under maximum hydropower capacity generation with and without taking into account the minimum flow requirement downstream near the Vietnam border with Cambodia. The precipitation and temperature projections from the high-resolution regional climate model HadGEM3-RA under two Representative Concentration Pathways, 4.5 and 8.5, of HadGEM2-AO are used as future climate change scenarios for the impact assessment. The study results show that reservoir operation leads to an increase in the dry season stream flows and a decrease in the wet season stream flows. The monthly flow regime exhibits considerable changes for both the Sesan and Srepok Rivers but with different magnitudes and patterns of increase and decrease. Climate change is likely to induce considerable changes in stream flows, though these changes are comparatively lower than those caused by reservoir operation. Climate change is likely to have both counterbalancing and reinforcing effects over the impact of reservoir operation, reducing changes during dry season but increasing changes in most of the other months.