A model of sand transport in Treporti channel: northern Venice lagoon

The origin of the sands in the Venice lagoon has been the subject of an extensive field survey in parallel with numerical modelling. Four transects along Treporti and Burano canals were conducted from which 33 bottom sediment samples were collected. These samples were analysed for grain size and sorting to examine any trends in the granulometry of these sediments that might shed light on transport paths. The modelling study consists of three parts: the sediment transport model sedtrans96 was used with a finite-element hydrodynamic model (Shyfem) and an empirical wave model (US Army Corps of Engineering) to simulate sand transport in the Treporti canal. A type of link box model was created where finite elements of the hydrodynamic model have been combined to macro-boxes on which the water and sediment flux over the sections, and a mass balance has been computed. Several grain size classes were simulated; the distributions before and after the simulation were examined. Idealised wind and tidal values were initially used to force 12 h simulations to test the sediment transport sensitivity. Finally, a full-year simulation (1987) has been carried out using measured tidal and wind data. Only a part of Venice lagoon was covered by the simulation: a major channel (Treporti) running from Lido inlet towards the northern lagoon. The total sand transport through all of the sections was computed for 1 year. Sediment mass balance was determined, and the resulting trends of erosion and deposition were computed. There were no trends in the median grain diameter and sorting of bottom samples from the Treporti canal; all sands were fine (120 μm, one outlier of 300 μm was removed). The absence of a trend in grain size suggests that there is no significant import of sand to the lagoon through the Lido inlet. The results from the simulations seem therefore to confirm the hypothesis of reworking of sand within the lagoon. The computed erosion is some centimeters per year diagnostic of channel scouring and enlargement with time. The Treporti canal is subject to strong current velocities of around 1 m/s, which hold fine sand in suspension and thus prevent sedimentation.     

The role of ballast in the helium-shell flash

Calculations are presented of the evolutionary track of an asymptotic giant branch (AGB) star, after most of its envelope is consumed and it starts moving to the right in the Hertzsprung–Russell (HR) diagram. On looking for the conditions that may create a helium-shell flash at this stage, it is found that a necessary condition for the creation of a helium-shell flash at this stage is the presence of mass 'ballast' over the helium-burning shell. The effects of different amounts of such ballast are studied, and the detailed evolution of such a flash is presented.     

Warming of an elevated layer over the Caribbean

Air temperatures in the trade wind inversion (~850 hPa) over the Caribbean have been rising much faster than sea temperatures. This is associated with an accelerated Hadley circulation, with sinking motions over the Caribbean corresponding with increasing rising motion over the Amazon. The sinking motions induce a faster rate of warming and drying in the trade wind inversion than at other levels. Much of the trend in Caribbean climate is attributable to physical mechanisms; changes in atmospheric composition play a secondary role. Smoke and dust plumes from Africa, drifting westward across the Atlantic, enhance the greenhouse effect in an elevated (1–3 km) layer. A stabilized lower atmosphere across the Caribbean has contributed to warming and drying trends over the twentieth century which are projected to continue. The atmosphere is warming faster than the ocean, causing a decline in sensible heat fluxes that fuel tropical cyclones.     

Volcanic gaps due to oblique consumption of aseismic ridges

The present-day consumption of oceanic ridges and other buoyant rises and fragments at circum-Pacific subduction zones, and presumably elsewhere, are closely related to existing gaps in volcanism. Examples are the gaps associated with the Nazca, Juan Fernandez, Cocos, Marcus-Necker and Louisville ridges. The buoyancy of these ridges breaks the continuity of the subducted plate, which may lead to reduced water supply required for melting of magma, and therefore create temporary volcanic gaps. The oblique consumption of these ridges causes the gap to migrate with time. This mechanism may be useful in interpreting time-space patterns of past volcanic chains associated with subduction in terms of the consumption of the disruptive oceanic plateaus and ridges.     

Thermodynamic properties,low-temperature heat-capacity anomalies,and single-crystal X-ray refinement of hydronium jarosite, (H<Subscript>3</Subscript>O)Fe<Subscript>3</Subscript>(SO<Subscript>4</Subscript>)<Subscript>2</Subscript>(OH)<Subscript>6</Subscript>

Crystals of hydronium jarosite were synthesized by hydrothermal treatment of Fe(III)–SO₄ solutions. Single-crystal XRD refinement with R₁=0.0232 for the unique observed reflections (|F_o| > 4_F) and wR₂=0.0451 for all data gave a=7.3559(8) Å, c=17.019(3) Å, V^o=160.11(4) cm³, and fractional positions for all atoms except the H in the H₃O groups. The chemical composition of this sample is described by the formula (H₃O)_0.91Fe_2.91(SO₄)₂[(OH)_5.64(H₂O)_0.18]. The enthalpy of formation (H^o_f) is –3694.5 ± 4.6 kJ mol^–1, calculated from acid (5.0 N HCl) solution calorimetry data for hydronium jarosite, -FeOOH, MgO, H₂O, and -MgSO₄. The entropy at standard temperature and pressure (S^o) is 438.9±0.7 J mol^–1 K^–1, calculated from adiabatic and semi-adiabatic calorimetry data. The heat capacity (C_p) data between 273 and 400 K were fitted to a Maier-Kelley polynomial C_p(T in K)=280.6 + 0.6149T–3199700T^–2. The Gibbs free energy of formation is –3162.2 ± 4.6 kJ mol^–1. Speciation and activity calculations for Fe(III)–SO₄ solutions show that these new thermodynamic data reproduce the results of solubility experiments with hydronium jarosite. A spin-glass freezing transition was manifested as a broad anomaly in the C_p data, and as a broad maximum in the zero-field-cooled magnetic susceptibility data at 16.5 K. Another anomaly in C_p, below 0.7 K, has been tentatively attributed to spin cluster tunneling. A set of thermodynamic values for an ideal composition end member (H₃O)Fe₃(SO₄)₂(OH)₆ was estimated: G^o_f= –3226.4 ± 4.6 kJ mol^–1, H^o_f=–3770.2 ± 4.6 kJ mol^–1, S^o=448.2 ± 0.7 J mol^–1 K^–1, C_p (T in K)=287.2 + 0.6281T–3286000T^–2 (between 273 and 400 K).     

Salt cave cross-sections and their paleoenvironmental implications

Salt caves respond rapidly to environmental changes. Direct measurement and ¹⁴C dating show that complex cross-sections may develop in a few hundred years. Two basic forms are discussed: (1) ingrowing vadose canyons where changing width may correspond to changing discharge; (2) wide low passages with flat ceilings, developed by upward dissolution, which may indicate rising base level. Some cross-sections are deformed by Holocene tectonics.     

Effect of adsorbed iron on thermoluminescence and electron spin resonance spectra of Ca-Fe-exchanged montmorillonite

The electron spin resonance (ESR) spectra and the natural and gamma-induced thermoluminescence (TL) glow curves of a series of variably cation-exchanged Fe-Ca-clays prepared from SWy-1 montmorillonite were examined. The ESR signal (g = 2) intensity associated with the surface Fe was found to increase linearly with surface Fe content up to a nominal concentration of 50% exchangeable Fe. At > 50% exchangeable Fe, no appreciable increase in the signal was noted. The TL intensity decreased linearly with increasing surface Fe up to 50% nominal exchangeable Fe. At > 50%, the signal was not appreciably further diminished. The natural TL showed only a high-temperature peak, but irradiation produced an additional low-temperature peak. One month after gamma-irradiation, the integrated TL signal was still 10-100 times higher than that from the non-irradiated material. Thus, (1) surface iron clusters may form above a certain critical Fe concentration; (2) the Fe clusters are probably less effective in quenching TL than are single Fe atoms, implying interaction between surface Fe and the stored energy content of the material; and (3) the electronic energy stored in the material as the result of gamma-irradiation is only slowly dissipated.     

Fine-grained sediment transport in Chignecto Bay, Bay of Fundy, Canada

This paper describes measurements of suspended sediment fluxes at a total of 32 stations situated on four reference sections in the turbid estuary of Chignecto Bay, Bay of Fundy, Canada. The purpose of the study was to determine the sediment budget (sources, transport paths and sinks) and the seasonal variations in particulate fluxes. The major sources of sediment are the eroding cliffs surrounding the bay (1.0 × 10⁶ m³ y⁻¹) and the seabed (6 × 10⁶ m³ y⁻¹. There are no present-day sinks within the estuary; sediment is principally moved in suspension to the wider part of the Bay of Fundy. Residuals in sediment mass transport are strongly affected by storms. These disrupt the logarithmic longitudinal sediment concentration profile which is normally present, and cause sediment to be transported out of the estuary. Well-defined turbid ribbons occur which meander unpredictably through the sampling sites; estimates of sediment mass transport are thus dubious.     

Comparison of large-scale structures and velocities in the local universe

Comparison of the large-scale density and velocity fields in the local universe shows detailed agreement, strengthening the standard paradigm of the gravitational origin of these structures. Quantitative analysis can determine the cosmological density parameter, , and biasing factor,b; there is virtually no sensitivity in any local analyses to the cosmological constant,. Comparison of the dipole anisotropy of the cosmic microwave background with the acceleration due to theIRAS galaxies puts the linear growth factor in the range ^0.6 /b = 0.6 _–0.3 ^+0.7 (95% confidence). A direct comparison of the density and velocity fields of nearby galaxies gives = 1.3 _–0.6 ^+0.7 , and from nonlinear analysis the weaker limit > 0.45 forb > 0.5 (again 95% confidence). A tighter limit, > 0.3 (4–6), is obtained by a reconstruction of the probability distribution function of the initial fluctuations from which the structures observed today arose. The last two methods depend critically on the smooth velocity field determined from the observed velocities of nearby galaxies by thePOTENT method. A new analysis of these velocities, with more than three times the data used to obtain the above quoted results, is now underway and promises to tighten the uncertainties considerably, as well as reduce systematic bias.