Thermal generation of ferromagnetic minerals from iron-enriched smectites

In recent years remagnetization of orogenic belts has been explained by fluid migration through rocks undergoing deformation. A laboratory study of remagnetization is presented in which varying amounts of iron (0-13.5 weight per cent Fe₂O₃) are adsorbed onto smectite surfaces. All smectite samples contain structural Fe (III) which is located in octahedral sites and is thermally stable up to 700 C. An increase in the amount of iron adsorbed onto the clay surface leads to the formation of ferric nanophases in which parts are magnetic. Mineralogical changes that occur during thermal treatment between room temperature and 700 C were monitored using electron spin resonance (ESR), bulk susceptibility, acquisition of isothermal remanent magnetization (IRM) and Curie temperature analysis. After heating the samples to 250 C, a new ferrimagnetic phase is created as indicated by ESR and IRM acquisition. ESR spectra, IRM acquisition and Curie analyses suggest that magnetite is the predominant phase that is being created. These grains continue to be created and grow with heating up to 500 C. Above this temperature a decrease in the intensity of the IRM at 1T suggests that the phase is being transformed into haematite. The thermal experiments on iron-loaded smectites show that surface-induced processes can lead to the formation of new magnetic minerals under conditions characteristic of low-grade metamorphism.     

Spatial gaps in arc volcanism: The effect of collision or subduction of oceanic plateaus

One of the major processes in the formation and deformation of continental lithosphere is the process of arc volcanism. The plate-tectonic theory predicts that a continuous chain of arc volcanoes lies parallel to any continuous subduction zone. However, the map pattern of active volcanoes shows at least 24 areas where there are major spatial gaps in the volcanic chains (> 200 km). A significant proportion (~ 30%) of oceanic crust is subducted at these gaps. All but three of these gaps coincide with the collision or subduction of a large aseismic plateau or ridge.The idea that the collision of such features may have a major tectonic impact on the arc lithosphere, including cessation of volcanism, is not new. However, it is not clear how the collision or subduction of an oceanic plateau perturbs the system to the extent of inhibiting arc volcanism. Three main factors necessary for arc volcanism are (1) source materials for the volcanics—either volatiles or melt from the subducting slab and/or melt from the overlying asthenospheric wedge, (2) a heat source, either for the dehydration or the melting of the slab, or the melting within the asthenosphere and (3) a favorable state of stress in the overlying lithosphere. The absence of any one of these features may cause a volcanic gap to form.There are several ways in which the collision or subduction of an oceanic plateau may affect arc volcanism. The clearest and most common cases considered are those where the feature completely resists subduction, causing local plate boundaries to reorganize. This includes the formation of new plate-bounding transform faults or a flip in subduction polarity. In these cases, subduction has slowed down or stopped and the lack of source material has created a volcanic gap.There are a few cases, most notably in Peru, Chile, and the Nankai trough, where the dip of subduction is so shallow that effectively no asthenospheric wedge exists to produce source material for volcanism. The shallow dip of the slab may be a buoyant effect of the plateau imbedded in the oceanic lithosphere.The cases which are the most enigmatic are those where subduction is continuous, the oceanic plateau is subducted along with the slab, and the dip of the slab is clearly steep enough to allow arc volcanism; yet a volcanic gap exists. In these areas, the subducted plateau may have a fundamental effect on the physical process of arc volcanism itself. The presence of a large topographic feature on the subducting plate may affect the stress state in the are by increasing the amount of decoupling between the two plates. Alternatively, the subduction of the plateau may change the chemical processes at depth if either the water-rich top of the plateau with accompanying sediments are scraped off during subduction or if the ridge is compositionally different.     

Solar and anthropogenic imprints on Lake Masoko (southern Tanzania) during the last 500 years

The Masoko crater-lake in southern Tanzania provides a continuous record of environmental changes covering the last 500 years. Multi-proxy studies were performed on a 52 cm sediment core retrieved from the deepest part of the lake. Magnetic, organic carbon, geochemical proxies and pollen assemblages indicate a dry climate during the ‘Little Ice Age’ (AD 1550–1850), confirming that the LIA in eastern Africa resulted in marked and synchronous hydrological changes. However, the direction of response varies between different African lakes (low versus high lake-levels), indicating strong regional contrasts that prevent the clear identification of climate trends over eastern Africa at this time. Inferred changes in Masoko lake-levels closely resemble the record of solar activity cycles, indicating a possible control of solar activity on the climate in this area. This observation supports previous results from East African lakes, and extends this relationship southward. Finally, anthropogenic impact is observed in the Masoko sediments during the last 60 years, suggesting that human disturbance significantly affected this remote basin during colonial and post-colonial times.     

Late Quaternary environmental and human events at En Gedi, reflected by the geology and archaeology of the Moringa Cave (Dead Sea area, Israel)

The Moringa Cave within Pleistocene sediments in the En Gedi area of the Dead Sea Fault Escarpment contains a sequence of various Pleistocene lacustrine deposits associated with higher-than-today lake levels at the Dead Sea basin. In addition it contains Chalcolithic remains and 5th century BC burials attributed to the Persian period, cemented and covered by Late Holocene travertine flowstone. These deposits represent a chain of Late Pleistocene and Holocene interconnected environmental and human events, echoing broader scale regional and global climate events. A major shift between depositional environments is associated with the rapid fall of Lake Lisan level during the latest Pleistocene. This exposed the sediments, providing for cave formation processes sometime between the latest Pleistocene (ca. 15 ka) and the Middle Holocene (ca. 4500 BC), eventually leading to human use of the cave. The Chalcolithic use of the cave can be related to a relatively moist desert environment, probably related to a shift in the location of the northern boundary of the Saharo-Arabian desert belt. The travertine layer was U-Th dated 2.46 ± 0.10 to 2.10 ± 0.04 ka, in agreement with the archaeological finds from the Persian period. Together with the inner consistency of the dating results, this strongly supports the reliability of the radiometric ages. The 2.46-2.10 ka travertine deposition within the presently dry cave suggests a higher recharge of the Judean Desert aquifer, correlative to a rising Dead Sea towards the end of the 1st millennium BC. This suggests a relatively moist local and regional climate facilitating human habitation of the desert.     

Integrated cave drip monitoring for epikarst recharge estimation in a dry Mediterranean area,Sif Cave,Israel

Understanding recharge mechanisms and controls in karst regions is extremely important for managing water resources because of the dynamic nature of the system. The objective of this study was to evaluate water percolation through epikarst by monitoring water flow into a cave and conducting artificial irrigation and tracer experiments, at Sif Cave in Wadi Sussi, Israel from 2005 through 2007. The research is based on continuous high‐resolution direct measurements of both rainfall and water percolation in the cave chamber collected by three large PVC sheets which integrate drips from three different areas (17, 46, and 52 m²). Barrels equipped with pressure transducers record drip rate and volume for each of the three areas. The combined measured rainfall and cave data enables estimation of recharge into the epikarst and to better understand the relationship of rainfall‐recharge. Three distinct types of flow regimes were identified: (1) ‘Quick flow’ through preferential flow paths (large fractures and conduits); (2) ‘Intermediate flow’ through a secondary crack system; and (3) ‘Slow flow’ through the matrix. A threshold of ～100 mm of rain at the beginning of the rainy season is required to increase soil water content allowing later rainfall events to percolate deeper through the soil and to initiate dripping in the cave. During winter, as the soil water content rises, the lag time between a rain event and cave drip response decreases. Annual recharge (140–160 mm in different areas in the cave) measured represents 30–35% of annual rainfall (460 mm). Copyright © 2011 John Wiley & Sons, Ltd.     

The heat flux density in a non-homogeneous bare loessial soil

This work describes the relationship between the diurnal patterns of the radiant energy exchange in the atmospheric surface layer and the soil heat flux density of a bare irrigated soil in an arid environment. The measurements show that the soil heat flux density is a large fraction of the net radiation. The soil moisture content has little effect on this fraction but modifies the phase relationship between the net radiation and the soil heat flux density waves. Differences between the thermal regimes of the wet and dry soil appear to be caused by latent heat exchanges rather than changes of the soil thermal properties. The data also show that the variation with depth of the soil thermal properties strongly influences the propagation of the temperature and heat flux density waves in the soil. A heat diffusion theory for non-homogeneous conductors (Lettau, 1962) which enables the thermal properties of the soil to be predicted is tested by comparison with experimental determinations in the field.     

FATTY ACIDS PROFILE IN A HIGH CELL DENSITY CULTURE OF ARACHIDONIC ACID-RICH PARIETOCHLORIS INCISA （TREBOUXIOPHYCEAE, CHLOROPHYTA） EXPOSED TO HIGH PFD

The changes in arachidonic acid (AA) and fatty acids profiles along the growth curve ofParietochloris incisa, a coccoid snow green alga, were studied in a 2.8 cm light-path flat photobiorcactor, exposed to strong photon flux density [PFD, 2400 μEmol/(m²·s)]. Sixteen fatty acids were identified by gas chromatography showing that AA was the dominant fatty acid (33%–41%) followed by linoleic acid (17%–21%). AA content was closely investigated with respect to total fatty acids (TFA), ash free dry weight (AFDW) of cell mass as well as total culture content. These parameters were influenced significantly in a similar manner by culture growth phase, i.e., slightly decreasing in the lag period, gradually increasing in the logarithmic phase, becoming maximal at the early stationary phase, starting to decrease at the late stationary phase, sharply dropping at the decline phase. The increase in AA per culture volume during the logarithmic phase was not only associated with the increase in AFDW but also connected with a corresponding increase in AA/TFA, TFA/AFDW as well as AA/AFDW. The sharp decrease in AA content of the culture during the decline phase was mainly due to the decrease in AA/TFA, TFA/AFDW and AA/AFDW, although AFDW declined only a small extent. Maximal AA concentration, obtained at the early stationary phase, was 900 mg/L culture volume, and the average daily net increase of AA during 9 days logarithmic growth was 1.7 g/(m²·day). Therefore, harvesting prior to the decline phase in a batch culture, or at steady state in continuous culture mode seems best for high AA production. The latter possibility was also further confirmed by continuous culture with 5 gradients of harvesting rate. Contribution No. 4138 from the Institute of Oceanology, Chinese Academy of Sciences. Project 39970575 supported by NSFC and A/2786-2 supported by International Foundation for Sciences (IFS).     

Phytolith indices as proxies of grass subfamilies on East African tropical mountains

The main objective of this paper is to provide researchers that investigate fossil phytolith assemblages and model/data comparisons a new tool for estimating C₃/C₄ grass composition over time. We tested the reliability of modern soil phytolith assemblages and phytolith indices for tracing the dominance of different grass subfamilies and tree cover density. We analyzed modern soil phytolith assemblages from sites over elevation gradients on Mount Kenya (Kenya), Mount Rungwe and around Lake Masoko (southern Tanzania). These data were compared with available botanical data. A phytolith index named Ic, proved to be an effective proxy of the proportions of Pooideae, Arundinoideae and Bambusoideae grasses (mainly C₃ grasses) versus Panicoideae grasses (mainly C₄ grasses), increasing with elevation in East-Africa. When tropical mountains are covered by open habitats (e.g. grasses and shrublands), Ic should be a reliable proxy of the C₃/C₄ grass composition. These results highlight the value of the phytolith index Ic, when interpreting paleo-environmental records from tropical mountains, to: 1) better understand past local and regional C₃/C₄ grass distributions and associated climatic changes and 2) increase the set of C₃/C₄ data available for model/data comparisons.