Kriging with imprecise (fuzzy) variograms. II: Application

The geostatistical analysis of soil liner permeability is based on 20 measurements and imprecise prior information on nugget effect, sill, and range of the unknown variogram. Using this information, membership functions for variogram parameters are assessed and the fuzzy variogram is constructed. Both kriging estimates and estimation variances are calculated as fuzzy numbers from the fuzzy variogram and data points. Contour maps are presented, indicating values of the kriged permeability and the estimation variance corresponding to selected membership values called levels.     

Barotropic,subtidal exchange between Calcasieu Lake and the Gulf of Mexico

Long-term measurements of flow through Calcasieu Pass, Louisiana, are compared to water level variations within Calcasieu Lake, Louisiana. Except during periods of freshets driven by local rainfall, the exchange is shown to be predominantly barotropic. A simple wind-driven model accounts for the observed phase relations between wind, current, and water level.     

The effects of tributyltin within aThalassia seagrass ecosystem

Flow-through seagrass core microcosms were used to examine responses of species and processes to a logarithmic gradient of dosing with¹⁴C-labeled tributyltin-chloride (TBT-CI). Experiments involved delivery of TBT-CI to the water column of replicate cores of a treatment (n=16) once per week; one-half of the cores were sacrificed after 3 wk of dosing, the others were dosed for 6 wk. Initial water column concentrations for the three treatments averaged 0.205, 2.23, and 22.21 μg I^?1, expressed as the TBT⁺ cation, but these concentrations dropped rapidly. Retained¹⁴C tracer, an estimate of total organotin species, was distributed to sediments, plants, and other biological tissues, all of whose tracer concentrations increased with time. Measures to indicate responses of both autotrophic and heterotrophic organisms were made; in general, treatment effects were demonstrable statistically only at the highest dose level. Accumulation of chlorophyll and biomass on glass slides was highest when suspended for the entire experiment in the water of the highest treatment; this unexpected result was perhaps an indirect effect related to reduced grazing activity in the microcosms. The highest dose of TBT-CI resulted in virtual population mortality of a few macrobenthic species and decreased loss of plant material in litter bags, both demonstrated within the first 3 wk of dosing. Reduced litter loss was coincident with mortality of an amphipod (Cymadusa compta) capable of shredding plant material, and a causal relation between the two effects is plausible. Thus, if concentrated to similar levels in aThalassia bed, TBT⁺ may have direct species-level effects and process-level effects, potentially causing ecosystem change via disruption of a species-process linkage influential in seagrass detrital food web dynamics.     

Identifying ‘place’ in place branding: core and periphery in Brisbane’s “New World City”

Brisbane is Australia’s third largest city, and capital of the state of Queensland. It has a sprawling urban footprint and impending connections to neighbouring metropolises, said to create a ‘200 km city’. The governing body of Brisbane controls the largest municipality in Australia, with unrivalled opportunity to influence both urban planning and marketing for the CBD and suburbs. Brisbane is home to over one million people, and its population has grown rapidly over the past decades, doubling in the past 40 years. Brisbane represents the quintessential city with an emerging quest for urbanity, both in brand and physical form. The relationships between the city’s urban planning and its branding is not well examined, despite clear entanglement between these two strategies. We use a case-study analysis of both Brisbane City (which is glossed as the Central Business District) and an outer-suburban area, Inala, to interrogate how urban identities and brand are being constructed in relation to their social settings and governance, with particular reference to the importance of city branding and its relationship to planning strategies. The manifestation of branding and relationship to place qualities at the core and on the periphery of Brisbane are examined, with relevance for other rapidly growing, ambitious cities. The focus of Brisbane’s push for urbanity is on the city centre, and is not representative of the typical suburban condition, nor of many cities dominated by suburban forms. An analysis of place brand, planning strategies and resident’s responses to place, from planning, architectural and anthropological perspectives are offered, as an alternative reading of place brand from the marketing dominated approach usually favoured in branding analysis. We make recommendations to incorporate a more complete version of place in the construction of a “genuine” urbanity. We argue that the recognition of resident-centred place identity in place branding will produce more socially sustainable places, as well as more authentic city brands.     

Evaluating the Effects of Autofluorescence during Raman Hyperspectral Imaging

Raman hyperspectral imaging is becoming a popular technique to analyse geological materials. Autofluorescence can affect the quality of the spectra that comprise hyperspectral data sets. Few studies have addressed potential misinterpretation of Raman images from hyperspectral data sets affected by autofluorescence. Additionally, little work has been done to develop methods for identifying the spatial distribution of spectra affected by autofluorescence. This study illustrates how autofluorescence may lead to misinterpretation of the distribution of materials based on intensity at a point images. A method is proposed utilising signal to axis analysis to create images that identify regions affected by autofluorescence. Post‐processing baseline correction is often used to address autofluorescence, and most software programs utilise a form of partial least squares regression modelling based on a subjective choice of polynomial order. This study shows that an inappropriate choice of polynomial order can introduce error, which may lead to misinterpretation of Raman images. A signal to axis analysis method is proposed to statistically compare seemingly ‘appropriate’ baseline correction trials. Although post‐processing of hyperspectral data sets and creating Raman images seem simple, data quality issues such as autofluorescence must be considered. If baseline correction is deemed necessary, it should be addressed as an experiment involving statistical comparison.     

Retrospective analysis: bile hydrocarbons and histopathology of demersal rockfish in Prince William Sound,Alaska, after the Exxon Valdez oil spill

Demersal rockfish are the only fish species that have been found dead in significant numbers after major oil spills, but the link between oil exposure and effect has not been well established. After the 1989 Exxon Valdez oil spill in Prince William Sound, Alaska, several species of rockfish (Sebastes spp.) from oiled and reference sites were analyzed for hydrocarbon metabolites in bile (1989-1991) and for microscopic lesions (1990 and 1991). Biliary hydrocarbons consistent with exposure to Exxon Valdez oil were elevated in 1989, but not in 1990 or 1991. Significant microscopic findings included pigmented macrophage aggregates and hepatic megalocytosis, fibrosis, and lipid accumulation. Site differences in microscopic findings were significant with respect to previous oil exposure in 1991 (P=0.038), but not in 1990. However, differences in microscopic findings were highly significant with respect to age and species in both years (P<0.001). We conclude that demersal rockfish were exposed to Exxon Valdez oil in 1989, but differences in microscopic changes in 1990 and 1991 were related more to age and species differences than to previous oil exposure.     

Sediment velocity estimation using iterative 3-D migrations of short offset seismic reflection data in deep water

In deep ocean settings where water depth greatly exceeds the source-to-receiver length, the geometry is insufficient for accurate determinations of velocity from reflection-moveout. However, velocities are crucial for estimates of physical properties and image processing. Focusing analyses with conventional post-stack two-dimensional migration improves images, but does not produce geologically meaningful velocities except in the special case of a two-dimensional earth. For the more general case of the three-dimensional earth there is no a priori method to determine the degree of geometrical complexity. We present a technique using a short-offset three-dimensional (3-D) data set over the 5 km deep trench west of the Lesser Antilles. These data illustrate highly sensitive post-stack 3-D focusing analyses (± 20 m s^–1 interval velocities), and the relationship of these seismically derived velocities to rock velocities. In our Barbados example we were able to establish the presence of a widespread 80-160 m thick low-velocity zone at and above the main low-angle fault. This observation suggests the water-rich décollement leaks water into the overlying sections. Also evident is a low-velocity section associated with turbidite sands. These results are confirmed with sparse logging data and well samples. Deep-water short offset 3-D experiments provide a potentially effective approach for velocity estimation, replacing the operational complexity of long-offsets with simpler short-offset techniques. In areas of structural complications and abundant diffracted energy, it is a surprisingly accurate method, utilizing the high fidelity 3-D wavefield and the information carried in zero-offset diffraction ellipsoids. The velocity used to properly collapse a diffraction ellipsoid is explicitly the velocity of propagation in the media since the travel path is known exactly. Thus, the derived velocities should closely represent rock velocities, unlike the 2-D case where the propagation geometry is not known.     

River–aquifer interactions in a semi‐arid environment stressed by groundwater abstraction

Rivers and aquifers are, in many cases, a connected resource and as such the interactions between them need to be understood and quantified for the resource to be managed appropriately. The objective of this paper is to advance the understanding of river–aquifer interactions processes in semi‐arid environments stressed by groundwater abstraction. This is performed using data from a specific catchment where records of precipitation, evapotranspiration, river flow, groundwater levels and groundwater abstraction are analysed using basic statistics, hydrograph analysis and a simple mathematical model to determine the processes causing the spatial and temporal changes in river–aquifer interactions. This combined approach provides a novel but simple methodology to analyse river–aquifer interactions, which can be applied to catchments worldwide. The analysis revealed that the groundwater levels have declined (~ 3 m) since the onset of groundwater abstraction. The decline is predominantly due to the abstraction rather than climatic changes (r = 0.84 for the relationship between groundwater abstraction and groundwater levels; r = 0.92 for the relationship between decline in groundwater levels and magnitude of seasonal drawdown). It is then demonstrated that, since the onset of abstraction, the river has changed from being gaining to losing during low‐flow periods, defined as periods with flow less than 0.5, 1.0 or 1.5 GL/day (1 GL/day = 1 × 10⁶ m³/day). If defined as < 1.0 GL/day, low‐flow periods constitute approximately 65% of the river flows; the periods where the river is losing at low‐flow conditions are thus significant. Importantly, there was a significant delay (> 10 years) between the onset of groundwater abstraction and the changeover from gaining to losing conditions. Finally, a relationship between the groundwater gradient towards the river and the river flow at low‐flow is demonstrated. The results have important implications for water management as well as water ecology and quality. Copyright © 2012 John Wiley & Sons, Ltd.