Style Transfer applied to CT image downscaling: a study case from Brazilian Coquinas

Computational Geosciences - The identification of micropore systems in carbonate rocks is an important task of image processing because of the high impact these systems cause on fluid flow....     

Enhanced Atlantic Meridional Overturning Circulation supports the Last Glacial Inception

The Atlantic Meridional Overturning Circulation (AMOC) is a key feature of the climate system. However, its role during climate change is still poorly constrained particularly during an Interglacial to Glacial climate transition and the associated global cooling. We present here the first reconstruction of the evolution of the vertical structure of the rate of the AMOC from the Last Interglaciation to the subsequent glaciation (128,000–60,000 years ago) based on sedimentary (²³¹Pa/²³⁰Th) records. We show a deep AMOC during the interglacial warmth Marine Isotope Stage (MIS) 5.5 and a shallower glacial one during glacial MIS 4. The change between these two patterns occurred mostly during the glacial inception, i.e. the transition from MIS 5.5 to MIS 5.4. Our data show that AMOC was enhanced during this latter transition as a consequence of a large increase of the overturning rate of the Intermediate Waters, above 2500 m. We suggest that this AMOC pattern required a reinforced Gulf Stream-North Atlantic Current system that ultimately supported ice-sheet growth by providing heat and moisture to the Northern high latitudes. From MIS 5.4 to MIS 5.1, the AMOC was broadly continuous below 2000 m and supported periods of ice-sheet growth. As a result, a glacial AMOC is triggered at the beginning of MIS 4 due to the extension of ice-sheet and the subsequent reorganization of deep-water formation. This study highlights the role of intermediate waters as a major player during climate change.     

Towards a Validation of Scintillometer Measurements: The LITFASS-2009 Experiment

Scintillometry has been increasingly used over the last decade for the experimental determination of area-averaged turbulent fluxes at a horizontal scale of a few kilometres. Nevertheless, a number of assumptions in the scintillometer data processing and interpretation still call for a thorough evaluation, in particular over heterogeneous terrain. Moreover, a validation of the path-averaged structure parameters derived from scintillometer data (and forming the basis for the flux calculations) by independent measurements is still missing. To achieve this, the LITFASS-2009 field campaign has been performed around the Meteorological Observatory Lindenberg ?C Richard-A?mann-Observatory of the German Meteorological Service (DWD) in July 2009. The experiment combined tower-based in-situ turbulence measurements, field-scale laser scintillometers, long-range optical (large-aperture) and microwave scintillometers, and airborne turbulence measurements using an automatically operating unmanned aircraft. The paper describes the project design and strategy, and discusses first results. Daytime near-surface values of the temperature structure parameter, ${C_{T}^{2}}$ , over different types of farmland differ by more than one order of magnitude in their dependence on the type and status of the vegetation. Considerable spatial variability in ${C_{T}^{2}}$ was also found along the flight legs at heights between 50 and 100?m. However, it appeared difficult to separate the effects of heterogeneity from the temporal variability of the turbulence fields. Aircraft measurements and scintillometer data agreed in magnitude with respect to the temporal variation of the path-averaged ${C_{T}^{2}}$ values during the diurnal cycle. The decrease of ${C_{T}^{2}}$ with height found from the scintillometer measurements close to the surface and at 43?m under daytime convective conditions corresponds to free-convection scaling, whereas the aircraft measurements at 54 and 83?m suggest a different behaviour.     

Stratigraphy, mineralogy, and origin of layered deposits inside Terby crater, Mars

The 174 km diameter Terby impact crater (28.0°S-74.1°E) located on the northern rim of the Hellas basin displays anomalous inner morphology, including a flat floor and light-toned layered deposits. An analysis of these deposits was performed using multiple datasets from Mars Global Surveyor, Mars Odyssey, Mars Express and Mars Reconnaissance Orbiter missions, with visible images for interpretation, near-infrared data for mineralogical mapping, and topography for geometry. The geometry of layered deposits was consistent with that of sediments that settled mainly in a sub-aqueous environment, during the Noachian period as determined by crater counts. To the north, the thickest sediments displayed sequences for fan deltas, as identified by 100 m to 1 km long clinoforms, as defined by horizontal beds passing to foreset beds dipping by 6-10° toward the center of the Terby crater. The identification of distinct sub-aqueous fan sequences, separated by unconformities and local wedges, showed the accumulation of sediments from prograding/onlapping depositional sequences, due to lake level and sediment supply variations. The mineralogy of several layers with hydrated minerals, including Fe/Mg phyllosilicates, supports this type of sedimentary environment. The volume of fan sediments was estimated as >5000 km³ (a large amount considering classical martian fan deltas such as Eberswalde (6 km³)) and requires sustained liquid water activity. Such a large sedimentary deposition in Terby crater is characteristic of the Noachian/Phyllosian period during which the environment favored the formation of phyllosilicates. The latter were detected by spectral data in the layered deposits of Terby crater in three distinct layer sequences. During the Hesperian period, the sediments experienced strong erosion, possibly enhanced by more acidic conditions, forming the current morphology with three mesas and closed depressions. Small fluvial valleys and alluvial fans formed subsequently, attesting to late fluvial processes dated as late Early to early Late Hesperian. After this late fluvial episode, the Terby impact crater was submitted to aeolian processes and permanent cold conditions with viscous flow features. Therefore, the Terby crater displays, in a single location, geologic features that characterize the three main periods of time on Mars, with the presence of one of the thickest sub-aqueous fan deposits reported on Mars. The filling of Terby impact crater is thus one potential “reference geologic cross-section” for Mars stratigraphy.     

Benthic primary production, respiration and remineralisation: in situ measurements in the soft-bottom Abra alba community of the western English Channel (North Brittany)

In situ measurements of ammonium and carbon dioxide fluxes were performed using benthic chambers at the end of spring and the end of summer in two soft-bottom Abra alba communities of the western English Channel (North Brittany): the muddy sand community (5 m, about 10% of surface irradiance) and the fine-sand community (19 m, about 1% of surface irradiance). High rates of ammonium regeneration were measured in the two communities at the end of summer (296.03±40.07 and 201.7±62.74 μmolN m⁻² h⁻¹, respectively) as well as high respiration rates (2.60±0.94 and 2.23±0.59 mmolC m⁻² h⁻¹, respectively). Significant benthic gross primary production (up to 6.11 mmolC m⁻² h⁻¹) was measured in the muddy sand community but no benthic primary production was measured in the fine-sand community. It suggests that microphytobenthic production values used in simulations previously published for these two communities were overestimated while values of community respiration were underestimated. The study confirms that this benthic system is heterotrophic and strengthens the idea that an important pelagic-benthic coupling is required for the functioning in such coastal ecosystems.     

Late Devonian and Triassic basalts from the southern continental margin of the East European Platform,tracers of a single heterogeneous lithospheric mantle source

In Late Devonian and Early-to-Late Triassic times, the southern continental margin of the Eastern European Platform was the site of a basaltic volcanism in the Donbas and Fore-Caucasus areas respectively. Both volcanic piles rest unconformably upon Paleoproterozoic and Late Paleozoic units respectively, and emplaced during continental rifting periods some 600 km away from expected locations of active oceanic subduction zones. This paper reports a comparative geochemical study of the basaltic rocks, and views them as the best tracers of the involved mantle below the Eastern European Platform. The Late Devonian alkaline basic rocks differ from the calc-alkaline Triassic basic rocks by their higher alkali-silica ratio, their higher TiO₂, K₂O, P₂O₅ and FeO contents, their higher trace element contents, a higher degree of fractionation between the most and the least incompatible elements and the absence of Ta-Nb negative anomalies. These general features, clearly distinct from those of partial melting and fractional crystallization, are due to mantle source effects. With similar Nd and Sr isotopic signatures indicating mantle-crust mixing, both suites would originate from the melting of a same but heterogeneous continental mantle lithosphere (refertilized depleted mantle). Accordingly the Nd model ages, the youngest major event associated with mantle metasomatism occurred during Early Neoproterozoic times (∼650Ma).     

Organic complexation of rare earth elements in natural waters: Evaluating model calculations from ultrafiltration data

The Stockholm Humic Model (SHM) and Humic Ion-Binding Models V and VI were compared for their ability to predict the role of dissolved organic matter (DOM) in the speciation of rare earth elements (REE) in natural waters. Unlike Models V and VI, SHM is part of a speciation code that also allows us to consider dissolution/precipitation, sorption/desorption and oxidation/reduction reactions. In this context, it is particularly interesting to test the performance of SHM. The REE specific equilibrium constants required by the speciation models were estimated using linear free-energy relationships (LFER) between the first hydrolysis constants and the stability constants for REE complexation with lactic and acetic acid. Three datasets were used for the purpose of comparison: (i) World Average River Water (Dissolved Organic Carbon (DOC) = 5 mg L⁻¹), previously investigated using Model V, was reinvestigated using SHM and Model VI; (ii) two natural organic-rich waters (DOC = 18-24 mg L⁻¹), whose REE speciation has already been determined with both Model V and ultrafiltration studies, were also reinvestigated using SHM and Model VI; finally, (iii) new ultrafiltration experiments were carried out on samples of circumneutral-pH (pH 6.2-7.1), organic-rich (DOC = 7-20 mg L⁻¹) groundwaters from the Kervidy-Naizin and Petit-Hermitage catchments, western France. The results were then compared with speciation predictions provided by Model VI and SHM, successively. When applied to World Average River Water, both Model VI and SHM yield comparable results, confirming the earlier finding that a large fraction of the dissolved REE in rivers occurs as organic complexes This implies that the two models are equally valid for calculating REE speciation in low-DOC waters at circumneutral-pH. The two models also successfully reproduced ultrafiltration results obtained for DOC-rich acidic groundwaters and river waters. By contrast, the two models yielded different results when compared to newly obtained ultrafiltration results for DOC-rich (DOC > 7 mg L⁻¹) groundwaters at circumneutral-pH, with Model VI predictions being closer to the ultrafiltration data than SHM. Sensitivity analysis indicates that the “active DOM parameter” (i.e., the proportion of DOC that can effectively complex with REE) is a key parameter for both Model VI and SHM. However, a survey of ultrafiltration results allows the “active DOM parameter” to be precisely determined for the newly ultrafiltered waters studied here. Thus, the observed discrepancy between SHM predictions and ultrafiltration results cannot be explained by the use of inappropriate “active DOM parameter” values in this model. Save this unexplained discrepancy, the results presented in this study demonstrate that both Model VI and SHM can provide reliable estimates of REE speciation in organic-rich waters. However, it is essential to know the proportion of DOM that can actively complex REE before running these two speciation models.     

Diatom-based transfer functions for western Quebec lakes (Abitibiand Haute Mauricie): the possible role of epilimnetic CO2 concentration in influencing diatom assemblages

Surficial sediments from 76 lakes from two western Quebec regions(Abitibi and Haute Mauricie) were sampled to identify the relationships betweendiatoms and environmental variables. Because the two regions containedradically different diatom communities, we then investigated which factors maybe responsible for the large community discrepancies in the two nearbygeographical areas. Standard lake chemistry variables showed little differencesbetween the regions, although epilimnetic light regimes were slightly lower inAbitibi. Nevertheless, lakes of the two regions with similar light regimes andchemistry still showed a clear separation in their diatoms, implying that otherimportant factors are influencing assemblages. We found that the calculatedconcentration of CO₂ in the open water can explain some of thediscrepancy in diatom assemblages. A pCCA constrained to the concentration ofCO₂ with alkalinity and pH as covariables explained 12.5% of speciesvariance and was significant. Given the lack of a relationship between DOC andCO₂, and because the lakes are heavily supersaturated withCO₂ in the calibration set, lake-to-lake variations inCO₂ concentrations are likely due to groundwater inputs; thepossibility that this environmental variable may be influencing diatomcommunities might allow, in some cases, the reconstruction of historicalchanges in groundwater inputs to lakes. Finally, new calibration models werebuilt in Quebec by using weighted averaging partial least square(WA-PLS) techniques in order to infer pH, CO₂, TP, TN, and, DOC fromdiatom assemblages preserved in the surface sediments.     

A Compilation of Silicon and Thirty One Trace Elements Measured in the Natural River Water Reference Material SLRS-4 (NRC-CNRC)

The natural river water certified reference material SLRS-4 (NRC-CNRC, National Research Council-Conseil National de Recherches Canada) has been routinely analysed for major and trace elements by six French laboratories. Most measurements were made using inductively coupled plasma-mass spectrometry. For silicon and thirty one trace elements (rare earth elements, Ag, B, Br, Cs, Ga, Ge, Li, P, Pd, Rb, Se, Th, Ti, Tl, W, Y and Zr), no certified values are assigned by NRC-CNRC. We propose some compilation values and related uncertainties according to the results obtained by the different laboratories.     

Le guidage des whistlers par le champ magnetique

In this paper the question is examined of how the v.l.f. radio-waves are guided along the magnetic field. Energy passes through the magnetic field under two sets of conditions. Corresponding to the “nose-whistlers” explained by Helliwell, the first one occurs when the wave-normal itself is in the direction of the magnetic field. This does not happen in the second case when the remarkable property is also shown that all frequencies are propagated at the same velocity V₀ = cƒ_H/2ƒ₀ (ƒ_H gyrofrequency, ƒ₀ frequency of the plasma). Considerations of energy point out that, if such a propagation is not easily observable in the case of an isotropic emission, it is not the same thing for an emission produced by erenkov effect, which is able to produce all energy by this mode of propagation, provided the particle's velocity has a low fixed value (˜ 10,000 km/sec in the exosphere). All frequencies being emitted at the same time and following the same path wtih the same velocity, we can explain the broadband noise observed during the reception of whistlers. The required velocity of particles is exactly the velocity V₀. This coincidence is explained in an appendix, and extended to other anisotropic media.