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51.
Alfonso Hernández-Laguna Elizabeth Escamilla-Roa Vicente Timón Martin T. Dove C. Ignacio Sainz-Díaz 《Physics and Chemistry of Minerals》2006,33(10):655-666
Quantum mechanical calculations based on the density functional theory (DFT) are used to study the crystal structures of dioctahedral 2:1 phyllosilicates. The isomorphous cation substitution is investigated by exploring different substitutions of octahedral Al3+ by Mg2+ or Fe3+, tetrahedral substitution of Si4+ by Al3+, and different interlayer cations (IC) (Na+, K+, Ca2+, and Mg2+). Samples with different kinds of layer charges are studied: only tetrahedrally charged, only octahedrally charged, or mixed octahedral/tetrahedral charged. The effect of the relative arrangements of these substitutions on the lattice parameters and total energy is studied. The experimental observation of segregation tendency of Fe3+ and dispersion tendency of Mg2+ in the octahedral sheet is reproduced and explained with reference to the relative energies of the octahedral cation arrangements. These energies are higher than those due to the IC/tetrahedral and IC/octahedral relative arrangements. The tetrahedral and octahedral substitutions that generate charged layers also tend to be dispersed. The octahedral cation exchange potentials change with the IC-charge/ionic radius value. 相似文献
52.
Christian Pin Eladio Lin Emilio Pascual Teodosio Donaire Alfonso Valenzuela 《Tectonophysics》2002,352(1-2)
Because the Hercynian overprint was extremely weak, the Sierra de Córdoba (southeastern Ossa-Morena Zone, OMZ) provides an excellent opportunity to study the tectonic evolution of sequences deposited close to the Late Neoproterozoic–Early Palaeozoic boundary. In order to put constraints on the sources and geodynamic significance of the Late Proterozoic magmatism, a representative set of 18 igneous rocks, and 3 interbedded sedimentary rocks from the San Jerónimo Formation have been studied for major and trace element geochemistry and for the Sm–Nd isotopic systematics. The igneous rocks are generally porphyritic to microporphyritic andesites, with abundant plagioclase (±amphibole) phenocrysts. With the exception of two intrusive rocks, possibly not related to the Late Proterozoic episode, all the samples display positive Nd550 Ma values, ranging from +2.9 to +7.6. Most of them, with +4<Nd550 Ma<+6, exhibit LREE enrichment, high La/Nb ratios, and elevated Zr/Nb ratios ranging from 21 to 32. There is no obvious correlation between the shape of REE patterns, La/Nb ratios and Nd550 Ma values, precluding simple models of late-stage interaction with typical crustal components having low Nd and high LREE/HREE and La/Nb ratios. Based on their major element composition and enriched, continental crust-like trace element characteristics, combined with distinctly positive Nd initial values, the Córdoba andesites document an episode of crustal growth through the addition of calc-alkaline magmas, extracted from a mantle reservoir which was strongly depleted in LREE on a time-integrated basis. The occurrence of interlayered sediments of continental provenance (negative Nd values) does not favour a purely ensimatic arc setting, remote from continental land masses, for this subduction-related magmatism, but the geochemical data suggest an active margin environment located on relatively juvenile crust. In any case, the Córdoba andesites document the addition of materials chemically similar to the bulk continental crust which were extracted from mantle sources with strong time-integrated LREE depletion. Therefore, they provide evidence for crustal growth related to Cadomian orogenic events during Late Proterozoic times. 相似文献
53.
Enzo Rizzo Alfonso Santoriello Luigi Capozzoli Gregory De Martino Cristiano Benedetto De Vita Daniela Musmeci Felice Perciante 《Surveys in Geophysics》2018,39(6):1201-1217
The use of geophysical methods in metrology is a significant tool within the wide research topic of landscape archaeology context. Since 2011, the Ancient Appia Landscapes Project aims to recognize dynamics, shapes and layout of the ancient settlement located along the Appia road east of Benevento, and cyclical elements and human activities that influenced the choice of landscapes. The integration of geophysical data with an archaeological infra-site analysis allowed us to investigate the area of Masseria Grasso, about 6 km from Benevento (Campania region, Italy). In this framework, an archaeogeophysical approach (Geomagnetic and Ground Penetrating Radar) was adopted for detecting anomalies potentially correlated with buried archaeological evidences. The geomagnetic results have given a wide knowledge of buried features in a large survey highlighting significant anomalies associated with the presence of buildings, roads and open spaces. These geophysical results permitted us to define the first archaeological excavations and, successively, a detailed Ground Penetrating Radar approach has been provided highlighting the rooms and paved spaces. The overlap between archaeological dataset and geophysical surveys has also allowed recognizing the path of the ancient Appia road near the city of Benevento and hypothesize the settlement organization of the investigated area, which has been identified with the ancient Nuceriola. 相似文献
54.
We discuss a new method for inferring the stellar mass of a distant galaxy of known redshift based on the combination of a near-IR luminosity and multiband optical photometry. The typical uncertainty for field galaxies with I<22 in the redshift range 0相似文献
55.
Denis Lacelle Alfonso F. Davila Wayne H. Pollard Dale Andersen Jennifer Heldmann Margarita Marinova Christopher P. McKay 《Earth and Planetary Science Letters》2011,301(1-2):403-411
To date, studies of the stability of subsurface ice in the McMurdo Dry Valleys of Antarctica have been mainly based on climate-based vapor diffusion models. In University Valley (1800 m), a small glacier is found at the base of the head of the valley, and adjacent to the glacier, a buried body of massive ice was uncovered beneath 20–40 cm of loose cryotic sediments and sandstone boulders. This study assesses the origin and stability of the buried body of massive ice by measuring the geochemistry and stable O–H isotope composition of the ice and applies a sublimation and molecular diffusion model that accounts for the observed trends. The results indicate that the buried massive ice body represents an extension of the adjacent glacier that was buried by a rock avalanche during a cold climate period. The contrasting δ18O profiles and regression slope values between the uppermost 6 cm of the buried massive ice (upward convex δ18O profile and SD-18O = 5.1) and that below it (progressive increase in δ18O and SD-18O = 6.4) suggest independent post-depositional processes affected the isotope composition of the ice. The upward convex δ18O profile in the uppermost 6 cm is consistent with the ice undergoing sublimation. Using a sublimation and molecular diffusion model, and assuming that diffusion occurred through solid ice, the sublimation rate needed to fit the measured δ18O profile is 0.2 ? 10? 3 mm yr? 1, a value that is more similar to net ice removal rates derived from 3He data from cobbles in Beacon Valley till (7.0 ? 10? 3 mm yr? 1) than sublimation rates computed based on current climate (0.1–0.2 mm yr?1). We suggest that the climate-based sublimation rates are offset due to potential ice recharge mechanisms or to missing parameters, particularly the nature and thermo-physical properties of the overlying sediments (i.e., temperature, humidity, pore structure and ice content, grain size). 相似文献
56.
David Sanz Santiago Casta?o Eduardo Cassiraga Andr��s Sahuquillo Juan Jos�� G��mez-Alday Salvador Pe?a Alfonso Calera 《Hydrogeology Journal》2011,19(2):475-487
The Mancha Oriental System (MOS, 7,260?km2) is one of the largest aquifers within Spain, and is encompassed by the Jucar River Basin. Over the past 30?years, socioeconomic development within the region has been largely due to intensive use of groundwater resources for irrigating crops (1,000?km2). Groundwater pumping (406 million m3/year) has provoked a steady drop in the groundwater level and a reduction of MOS discharge to the Jucar River. The study aims to characterize the river?Caquifer relationship, to determine the influence that groundwater abstraction has on the river discharge. This research has advanced a three-dimensional large-scale numerical groundwater-flow model (MODFLOW 2000) in order to spatially and temporally evaluate, quantify and predict the river?Caquifer interactions that are influenced by groundwater abstraction in MOS. It is demonstrated that although groundwater abstraction increased considerably from the early 1980s to 2000, the depletion of water stored in the aquifer was lower than might be expected. This is mainly due to aquifer recharge from the Jucar River, induced by groundwater abstraction. The area of disconnection between the river and the water table (i.e. where groundwater head is lower than the riverbed) is found to have spread 20?km downstream from its position before pumping started. 相似文献
57.
58.
Adolfo L. Méndez Berhondo Ramón E. Rodríguez Taboada Liliana Alfonso Larralde 《Astrophysics and Space Science》2006,302(1-4):213-216
The waiting time distribution of emissions in Coronal Mass Ejections (CMEs) with several emissions is examined. We define
the waiting time as the time interval between the commencement of an emission and the commencement of the next emission considered
as parts of a unique CME. The distribution seems to follow a power-law. Two classes of CMEs several emissions are considered:
“close” and “separate” depending on angular distance between emissions. 相似文献
59.
60.
In the galaxy, Jeans' critical length for the interstellar gas is appreciably smaller than the critical length for the stars, a necessary condition for the gravitational instability of the former to have a local character. An accurate discussion of the orders of magnitude involved leads to the establishment of a well defined limiting procedure and to simplified equations in which the effect of stars occurs only through the equilibrium, but disappears from the perturbations. The equations are spatially local, but their coefficients are time-dependent, in that they describe the evolution of a small wave packet dragged along by the supersonic gas motion. They have been solved in several interesting cases by the introduction of an effective, time-dependent wave vector, which describes the deformation of a wave profile due to the velocity gradients. The ordinary Jeans' instability is recovered only when the velocity gradient is a skew tensor; otherwise we find a stabilizing effect in accelerated and sheared flows, a destabilizing effect in a decelerated flow. Possible connections of this model with the observed turbulent structure of the interstellar gas are discussed. 相似文献