Stability of phlogopite in ultrapotassic kimberlite-like systems at 5.5–7.5 GPa

Hydrous K-rich kimberlite-like systems are studied experimentally at 5.5–7.5 GPa and 1200–1450?°C in terms of phase relations and conditions for formation and stability of phlogopite. The starting samples are phlogopite–carbonatite–phlogopite sandwiches and harzburgite–carbonatite mixtures consisting of Ol?+?Grt?+?Cpx?+?L (±Opx), according to the previous experimental results obtained at the same P–T parameters but in water-free systems. Carbonatite is represented by a K- and Ca-rich composition that may form at the top of a slab. In the presence of carbonatitic melt, phlogopite can partly melt in a peritectic reaction at 5.5 GPa and 1200–1350?°C, as well as at 6.3–7.0 GPa and 1200?°C: 2Phl?+?CaCO₃ (L)?Cpx?+?Ol?+?Grt?+?K₂CO₃ (L)?+?2H₂O (L). Synthesis of phlogopite at 5.5 GPa and 1200–1350?°C, with an initial mixture of H₂O-bearing harzburgite and carbonatite, demonstrates experimentally that equilibrium in this reaction can be shifted from right to left. Therefore, phlogopite can equilibrate with ultrapotassic carbonate–silicate melts in a?≥?150?°C region between 1200 and 1350?°C at 5.5 GPa. On the other hand, it can exist but cannot nucleate spontaneously and crystallize in the presence of such melts in quite a large pressure range in experiments at 6.3–7.0 GPa and 1200?°C. Thus, phlogopite can result from metasomatism of peridotite at the base of continental lithospheric mantle (CLM) by ultrapotassic carbonatite agents at depths shallower than 180–195 km, which creates a mechanism of water retaining in CLM. Kimberlite formation can begin at 5.5 GPa and 1350?°C in a phlogopite-bearing peridotite source generating a hydrous carbonate–silicate melt with 10–15 wt% SiO₂, Ca# from 45 to 60, and high K enrichment. Upon further heating to 1450?°C due to the effect of a mantle plume at the CLM base, phlogopite disappears and a kimberlite-like melt forms with SiO₂ to 20 wt% and Ca#?=?35–40.     

Holocene hydrological variability of Lake Ladoga,northwest Russia,as inferred from diatom oxygen isotopes

This article presents a new comprehensive assessment of the Holocene hydrological variability of Lake Ladoga, northwest Russia. The reconstruction is based on oxygen isotopes of lacustrine diatom silica (δ¹⁸O_diatom) preserved in sediment core Co 1309, and is complemented by a diatom assemblage analysis and a survey of modern isotope hydrology. The data indicate that Lake Ladoga has existed as a freshwater reservoir since at least 10.8 cal. ka BP. The δ¹⁸O_diatom values range from +29.8 to +35.0‰, and relatively higher δ¹⁸O_diatom values around +34.7‰ between c. 7.1 and 5.7 cal. ka BP are considered to reflect the Holocene Thermal Maximum. A continuous depletion in δ¹⁸O_diatom since c. 6.1 cal. ka BP accelerates after c. 4 cal. ka BP, indicating Middle to Late Holocene cooling that culminates during the interval 0.8–0.2 cal. ka BP, corresponding to the Little Ice Age. Lake‐level rises result in lower δ¹⁸O_diatom values, whereas lower lake levels cause higher δ¹⁸O_diatom values. The diatom isotope record gives an indication for a rather early opening of the Neva River outflow at c. 4.4–4.0 cal. ka BP. Generally, overall high δ¹⁸O_diatom values around +33.5‰ characterize a persistent evaporative lake system throughout the Holocene. As the Lake Ladoga δ¹⁸O_diatom record is roughly in line with the 60°N summer insolation, a linkage to broader‐scale climate change is likely.     

Kinematical characteristics of the factorized velocity model

The factorized velocity model that incorporates both vertical heterogeneity and constant anisotropy is one of the complicated analytical models used in seismic data processing and interpretation. In this paper, I derive the analytic equations for offset, traveltime and relative geometrical spreading for the quasi‐compressional (qP‐) waves that can be used for modelling and inversion of the traveltime parameters. I show that the presence of anelliptic anisotropy usually dominates over the vertical heterogeneity with respect to the non‐hyperbolicity of the factorized velocity model.     

The increase in the magnetic flux from the polar regions of the Sun over the last 120 years

The latitudes of the zonal boundaries of the global magnetic field of the Sun are determined from the magnetic neutral lines on synoptic Hα maps obtained during 1878–1999. The area of the polar zone occupied by magnetic field of a single polarity at solar minima has doubled over the last 120 years. This provides an explanation for the secular increase in heliospheric characteristics, which differs from the two-fold increase of the magnetic field strength predicted for this period. The temporal variations of the magnetic flux from the polar regions and their role in global changes of the Earth’s climate are discussed in connection with secular variations in the structure of the internal magnetic field of the Sun.     

Structural–formational interpretation tools for seismic stratigraphy

In the framework of a structural-and-formational interpretation (SFI) approach to seismic data processing and geological interpretation, specific software/technology tools were created to facilitate sequence stratigraphy analysis and reservoir characterization. The most important tools are two types of time–frequency representation of seismic data: the first is spectrum-time analysis (STAN), which presents a seismic trace as a series of very narrow frequency band traces, while the second tool converts an initial seismic section into a set of sections ranked with preselected frequency bands, narrower than those of the initial section, but wider than those related to STAN traces. Jointly, these two representations reflect both general trends and local temporal and spatial variations of seismic data frequency content. The use of these tools, developed in Russia in the 1980s, facilitates detection of sedimentation cycles and their depositional environments, identification of hierarchies within faulting patterns, and delineation of geological anomalies on seismic sections. This, in turn, provides reliable starting points for palaeotectonic restoration and basin modelling. In many regions, these tools have helped to clarify obscure formation structures under study and to estimate the hydrocarbon potential of these formations.     

Geomorphological Holocene events as deduced from lithological records of the fluvial basins of Dauria

A conjugate analysis of the processes of morphogenesis and sedimentation within small fluvial basins of Dauria revealed a rhythmic character of change of the Holocene processes which are combined into cycles of a different hierarchical level. It is shown that each cycle begins with an extreme phase of intense fluvial drift and delivery of matter from the system. The fluvial horizons comprise the lower part of deposits of the Holocene macrocycle in the Vesnyanka pad’ (a valley without a permanent watercourse). A disastrous fluvial drift was recorded repeatedly for the period 7–8.5 cal. ka and at the transition time from the Atlantic to Subboreal time. A normal zonal phase of integration of matter within the basins is exhibited by buried humus horizons of soils which give clear evidence of 1800-year cycles. A regional development in Dauria is recorded for the soils with the age of about 8, 6.4 and 4.6 as well as 1.2–1.4 cal. ka. The upper part of the deposits of each cycle is characterized by aeolian horizons of extreme arid phases. The profiles of proluvial trails are indicative of 130-year cycles. Based on results from studying buried soils, data of pollen analysis and radiocarbon dating of the deposits, we determined an enhancement in climate aridization for the last 10 ka and, in general, a decreased of the sedimentation and morphogenesis rate.     

冰力学参数的超声波测试研究

利用非线性高能超声测试设备及超声波(纵波、横波)波速与物体力学参数的关系,对人造冰样进行了冰样力学参数(杨氏模量、泊松比、剪切模量、体积模量)随温度变化的研究。通过MATLAB进行所测数据曲线拟合,得到超声波波速在人造冰样中随温度的变化规律,进而由理论公式推导所测人造冰样力学参数随温度的变化规律。结果表明:冰样中超声波波速随温度降低而升高,冰样的杨氏模量、泊松比、剪切模量、体积模量也都随温度降低而升高。本研究有助于超声波检测法在冰样物理力学性质测量中的应用,为开展南极冰盖、海冰以及终年冻土等力学及流动特性研究提供理论模型和实验数据。     

Amplitude—Phase Characteristics of the Annual Cycle of Surface Air Temperature in the Northern Hemisphere

The amplitude-phase characteristics(APC)of surface air temperature(SAT)annual cycle(AC)in the Northern Hemisphere are analyzed.From meteorological observations for the 20th century and meteorological reanalyses for its second half,it is found that over land negative correlation of SAT ACamplitude with annual mean SAT dominates.Nevertheless,some exceptions exist.The positive correlationbetween these two variables is found over the two desert regions:in northern Africa and in Central America.Areas of positive correlations are also found for the northern Pacific and for the tropical Indian and PacificOceans.Southward of the characteristic annual mean snow-ice boundary (SIB) position,the shape ofthe SAT AC becomes more sinusoidal under climate warming.In contrast,northward of it,this shapebecomes less sinusoidal.The latter iS also found for the above-mentioned two desert regions.In theFar East(southward of about 50°N),the SAT AC shifts as a whole:here its spring and autumn phasesoccur earlier if the annual     

The large-scale solar magnetic field and 11-year activity cycles

Magnetic Hα synoptic maps of the Sun for 1915–1999 are analyzed and the intensities of spherical harmonics of the large-scale solar magnetic field computed. The possibility of using these Hα maps as a database for investigations of long-term variations of solar activity is demonstrated. As an example, the magnetic-field polarity distribution for the Hα maps and the analogous polarity distribution for the magnetographic maps of the Stanford observatory for 1975–1999 are compared. An activity index A(t) is introduced for the large-scale magnetic field, which is the sum of the magnetic-moment intensities for the dipole and octupole components. The 11-year cycle of the large-scale solar magnetic field leads the 11-year sunspot cycle by, on average, 5.5 years. It is concluded that the observed weak large-scale solar magnetic field is not the product of the decay of strong active-region fields. Based on the new data, the level of the current (23rd) solar-activity cycle and some aspects of solar-cycle theory are discussed.     

Remote sensing and surface POC concentration in the South Atlantic

Several SeaWiFS products have been compared with shipboard data to assess the possibility of using remote sensing to estimate particulate organic carbon (POC) concentration in surface waters. Transmissometer data were collected during six South Atlantic Ventilation Experiment (SAVE) hydrographic expeditions conducted between November 1987 and March 1989 from R/V Knorr, and Melville. A total of 361 beam attenuation profiles were made with a SeaTech transmissometer interfaced with a CTD/rosette. In order to calculate the POC concentration from transmissometer profiles, a regression between beam attenuation and POC for open Atlantic Ocean waters derived from our research in the North Atlantic (North Atlantic Bloom Experiment, NABE) and enhanced by data from the Bermuda Atlantic Time Series Station (BATS) was applied. The profiles were processed and examined as vertical sections of the surface 250 m. The data were collected in two successive years, during the same season, which allowed us to compile a combined data set over the austral summer for examination. Beam attenuation/POC concentrations were integrated down to one attenuation depth with the intent of making comparisons with satellite optical data. No satellite optical data were available for 1987–1989, so the only option was to compare our integrated data with SeaWiFS-derived variables from later years averaged over the same season as SAVE data. Analysis of four SeaWiFS products acquired from 1997 to 2002 demonstrated very low variations from year to year for seasonally averaged data, suggesting that making comparisons of the beam attenuation/POC fields with averaged satellite optical products from later years is a valid (though not optimal) approach for this area. The highest correlation between beam attenuation/POC concentration and remotely derived products was found with normalized water-leaving radiance at 555 nm. Other SeaWiFS-derived variables—chlorophyll concentration, diffuse attenuation coefficient at 490 nm and integral chlorophyll (integrated over one attenuation depth)—were also compared but showed a slightly less satisfactory correlation.