Trace metal contamination of Beaufort's Dyke, North Channel, Irish Sea: a legacy of ordnance disposal

Beaufort’s Dyke is a disused ordnance disposal ground within the North Channel of the Irish Sea. Over 1 million tonnes of ordnance were disposed of in the dyke over a 40 year period representing a substantial volume of trace metal pollutants introduced to the seabed. Utilising particle transport modelling software we simulated the potential transport of metal particles from Beaufort’s Dyke over a 3 month period. This demonstrated that Beaufort’s Dyke has the potential to act as a source for trace metal contamination to areas beyond the submarine valley. Trace metal analysis of sediments from the Dyke and surrounding National Marine Monitoring Programme areas demonstrate that the Dyke is not the most contaminated site in the region. Particle transport modelling enables the transport pathways of trace metal contaminants to be predicted. Implementation of the technique in other munitions disposal grounds will provide valuable information for the selection of monitoring stations.     

Alternative climate data sources for distributed hydrological modelling on a daily time step

Two major criteria in choosing climate data for use in hydrological modelling are the period of record of the data set and the proximity of the collection platform(s) to the basin under study. Conventional data sets are derived from weather stations; however, in many cases there are no weather stations sufficiently close to a basin to be representative of climate conditions in that basin. In addition, it is often the case either that the period of record for the weather station(s) does not cover the period of the proposed simulation or that there are gaps in the data. Therefore, the objectives of this study are to investigate alternative climate data sources for use in hydrological modelling and to develop a protocol for creating hydrological data sets that are spatially and temporally harmonized. The methods we used for constructing daily, spatially distributed, climatic data sets of precipitation, maximum and minimum temperature, wind speed, solar radiation, potential evapotranspiration, and relative humidity are described. The model used in this study was the Soil and Water Assessment Tool implemented on the Mimbres River Basin located in southwestern New Mexico, USA, for the period 2003–2006. Our hydrological simulations showed that two events in January and February 2005 were missed, while an event in August 2006 was well simulated. We have also investigated the usefulness of several other precipitation data sets and compared the simulation results. Copyright © 2010 John Wiley & Sons, Ltd.     

Tidal and wind-driven surface currents in the German Bight: HFR observations versus model simulations

Tidal and wind-driven surface currents in the German Bight between shallow mudflats of the North Frisian islands and the island of Helgoland are studied using coastal high-frequency radar (HFR) observations and hindcasts from a primitive equation numerical model. The setup of the observational system is described, and estimates of expected measurement errors are given. A quantitative comparison of numerical model results and observations is performed. The dominant tidal components are extracted from the two data sources using tidal harmonic analysis and the corresponding tidal ellipses are defined. Results show that the spatial patterns of different tidal ellipse parameters are consistent in the two data sets. Model sensitivity studies with constant and variable salinity and temperature distributions are used to study density-related mechanisms of circulation. Furthermore, the role of the surface wind field in driving the German Bight circulation is investigated using the complex correlation between wind and surface current vectors. The observed change of the respective correlation patterns from the coastal to open ocean is shown to be due to a combination of density effects, the coastline and topography. The overall conclusion is that HFR observations resolve the small-scale and rapidly evolving characteristics of coastal currents well in the studied area and could present an important component for regional operational oceanography when combined with numerical modelling. Some unresolved issues associated with the complex circulation and large instability of circulation in front of the Elbe River Estuary justify further considerations of this area using dedicated surveys and modelling efforts.     

Comparison between satellite and in situ sea surface temperature data in the Western Mediterranean Sea

A comparison between in situ and satellite sea surface temperature (SST) is presented for the Western Mediterranean Sea during 1999. Several international databases are used to extract in situ data (World Ocean Database, MEDAR/Medatlas, Coriolis Data Center, International Council for the Exploration of the Sea and International Comprehensive Ocean-Atmosphere Data Set). The in situ data are classified into different platforms or sensors (conductivity–temperature–depth, expendable bathythermographs, drifters, bottles, and ships), in order to assess the relative accuracy of these type of data with respect to Advanced Very High Resolution Radiometer SST satellite data. It is shown that the results of the error assessment vary with the sensor type, the depth of the in situ measurements, and the database used. Ship data are the most heterogeneous data set, and therefore present the largest differences with respect to in situ data. A cold bias is detected in drifter data. The differences between satellite and in situ data are not normally distributed. However, several analysis techniques, as merging and data assimilation, usually require Gaussian-distributed errors. The statistics obtained during this study will be used in future work to merge the in situ and satellite data sets into one unique estimation of the SST.     

Climate targets under uncertainty: challenges and remedies

We start from the observation that climate targets under uncertainty should be interpreted as safety constraints on the probability of crossing a certain threshold, such as 2??C global warming. We then highlight, by ways of a simple example, that cost-effectiveness analysis for such probabilistic targets leads to major conceptual problems if learning about uncertainty is taken into account and the target is fixed. Current target proposals presumably imply that targets should be revised in the light of new information. Taking this into account amounts to formalizing how targets should be chosen, a question that was avoided by cost-effectiveness analysis. One way is to perform a full-fledged cost-benefit analysis including some kind of monetary damage function. We propose multi-criteria decision analysis including a target-based risk metric as an alternative that is more explicite in its assumptions and more closely based on given targets.     

Chalcopyrite formation through the metathesis of pyrrhotite with aqueous copper

The heterogeneous chemical environment which develops in the heap leaching of some pyrrhotite-containing copper ores can promote covellite and chalcopyrite formation particularly in acid-depleted regions of a heap. In such circumstances, copper recovery will be delayed until the acid and oxidation fronts move through the bed of ore and these secondary copper sulfides are re-leached. The transition from pyrrhotite to chalcopyrite most probably follows the sequence, pyrrhotite to copper-pyrrhotite to unnamed mineral CuFe₃S₄ to isocubanite to chalcopyrite, with a major structural expansion occurring prior to CuFe₃S₄. The mechanism is one in which copper is incorporated into pyrrhotite, which maintains its NiAs-type structure up to a stability limit, above which the structure rearranges to a chalcopyrite-like structure followed by isomorphic substitution of copper for iron. The structural rearrangement proceeds with significant expansion in one of the hexagonal axis directions and contractions in the other directions. Depending on the orientation, this expansion induces different levels of strain in the product chalcopyrite. The level of strain subsequently impacts on the rate of chalcopyrite metathesis to covellite. The depth of chalcopyrite formation into the pyrrhotite varies with pyrrhotite orientation.     

Compositional diversity in insoluble organic matter in type 1, 2 and 3 chondrites as detected by infrared spectroscopy

Insoluble organic matter (IOM) isolated from 22 carbonaceous and ordinary chondrites spanning a wide range of groups and petrologic types were analyzed using Fourier transform infrared spectroscopy (FTIR). Based on common IR spectral features, it is observed that IOM falls into 4 molecularly distinct groups (designated here as A through D). Spectral group A includes type 1 and 2 chondrites and exhibits intense aliphatic C-H and carboxyl vibrational peaks. Spectral group B includes the least metamorphosed type 3 chondrites and Tagish Lake, and exhibits weaker aliphatic and carboxyl vibrational intensity. Spectral groups C and D include metamorphosed type ?3.1 chondrites and a heated CM chondrite. The carbonyl stretching features in spectral groups C and D differ from that in spectral groups A and B and from each other. In spectral group C, the carbonyl stretching is assigned to cyclic unsaturated lactones; in spectral group D carbonyl exists predominantly in the form of unsaturated ketone moieties. Both spectral groups C and D have a relatively narrow band structure around 1210 cm⁻¹ (assigned to aromatic skeletal modes) as compared with spectral groups A and B, which is consistent with the formation of more condensed aromatics by extensive thermal metamorphism. The differences in carbonyl structures in spectral groups C and D are not the result of different effective metamorphic temperatures, rather these differences likely result from variation in the activity of water and oxygen at different stages of parent body metamorphism. Such environmental variations must be local phenomena in the parent bodies as there is no correlation between spectral grouping and chondrite class or group.     

New genus and species of Cerophytidae (Insecta: Coleoptera) from the Lower Cretaceous of Baissa (Siberia)

One new genus and two new species of fossil Cerophytidae, Baissophytum convexus gen. et. sp. nov. and Baissophytum amplus sp. nov. are described and illustrated from Zaza Formation (Lower Cretaceous), Eravnensky (Bauntovsky) District, Buriatskay Autonomous Republic (Transbaikalia), Russia.     

Elasticity and equation of state of Li<Subscript>2</Subscript>B<Subscript>4</Subscript>O<Subscript>7</Subscript>

A single crystal X-ray diffraction study on lithium tetraborate Li₂B₄O₇ (diomignite, space group I4₁ cd) has been performed under pressure up to 8.3 GPa. No phase transitions were found in the pressure range investigated, and hence the pressure evolution of the unit-cell volume of the I4₁ cd structure has been described using a third-order Birch–Murnaghan equation of state (BM-EoS) with the following parameters: V ₀  = 923.21(6) ų, K ₀  = 45.6(6) GPa, and K′ = 7.3(3). A linearized BM-EoS was fitted to the axial compressibilities resulting in the following parameters a ₀  = 9.4747(3) Å, K _0a  = 73.3(9) GPa, K′ _a  = 5.1(3) and c ₀  = 10.2838(4) Å, K _0c  = 24.6(3) GPa, K′ _c  = 7.5(2) for the a and c axes, respectively. The elastic anisotropy of Li₂B₄O₇ is very large with the zero-pressure compressibility ratio β _0c /β _0a  = 3.0(1). The large elastic anisotropy is consistent with the crystal structure: A three-dimensional arrangement of relatively rigid tetraborate groups [B₄O₇]²⁻ forms channels occupied by lithium along the polar c–axis, and hence compression along the c axis requires the shrinkage of the lithium channels, whereas compression in the a direction depends mainly on the contraction of the most rigid [B₄O₇]²⁻ units. Finally, the isothermal bulk modulus obtained in this work is in general agreement with that derived from ultrasonic (Adachi et al. in Proceedings-IEEE Ultrasonic Symposium, 228–232, 1985; Shorrocks et al. in Proceedings-IEEE Ultrasonic Symposium, 337–340, 1981) and Brillouin scattering measurements (Takagi et al. in Ferroelectrics, 137:337–342, 1992).