The effect of coherency stress on the mechanism of the reaction albite+K+⇌K-feldspar+Na+ and on the mechanical state of the resulting feldspar

Coherency stress and coherency strain energy generated by Na⁺?K⁺ ion exchange in alkali feldspars are calculated using an isotropic model, and deformation of single crystals of alkali feldspars exposed to molten alkali chlorides at \(P_{H_2 O} \) < 1 bar is described. Coherency stress in alkali feldspars can reach 10–20 kb. When it is large, partial relaxation by fracture and/or plastic deformation takes place under anhydrous conditions, but temporary build-up of stress is unavoidable even under hydrothermal conditions. Because of coherency strain energy, a thin layer of an end-member alkali feldspar produced by cation exchange on a grain of the other end-member alkali feldspar would be unstable with respect to dissolution. Therefore, under hydrothermal conditions one end-member alkali feldspar replaces the other by dissolution and precipitation. The mechanism of the reaction $$Na_x K_{1 - x} AlSi_3 O_{8_{(feld.)} } + yK^ + \rightleftharpoons Na_{x - y} K_{1 + y - x} AlSi_3 O_{8_{(feld.)} } + yNa^ + $$ is primarily controlled by \(P_{H_2 O} \) and by ΔK/(Na + K), the difference between the equilibrium value and the initial value of the atomic K/(Na + K) ratio of the feldspar. When ¦ΔK/(Na + K)¦ is small, the reaction proceeds by cation exchange. When ¦ΔK/(Na + K)¦ is large, cation exchange still occurs if \(P_{H_2 O} \) is very low, but under hydrothermal conditions replacement by dissolution and precipitation occurs.     

A multidisciplinary investigation of deep-seated landslide reactivation triggered by an extreme rainfall event: a case study of the Monesi di Mendatica landslide,Ligurian Alps

Landslides - In November 2016, an extreme rainfall event affected the Ligurian Alps (NW Italy). Consequently, several landslides and debris flows occurred in the upper Tanarello stream basin. In...     

Analysis of the Saharan dust regional transport

Summary The Balkan Peninsula is situated in the impact zone of Saharan dust storms. The case of Saharan dust transport to Belgrade in the period of 14–17 April 1994 is analyzed using the Eta model for synoptic and meso scale processes. Air back trajectories are calculated at six model levels from 434 up to 5129m with horizontal grid resolutions of 1°×1° and 10×10. Following cyclonic circulation the dust was picked up from North Africa, and transported over Mediterranean. Simultaneously, according to the analysis of the three lowest trajectories, transport of trace metals from Macedonia and southern Serbia by the Koshava wind might be dominant in the observed episode. Turbulent flow enhanced the coagulation process of initially clean dust particles with particles containing Pb and Cd. The coagulation and scavenging processes below and in clouds increased deposition rates of Pb and Cd in Belgrade in the course of wet removal, and consequently trough resuspension processes. Dry deposition samples contained characteristic particles up to 30µm in diameter with Fe content of 11 to 15 atomic% and significant ratio Si/Fe of 3 to 5, determined for selected single particles by the SEM/EDX method. Following dry and wet deposition of Cd and Pb, a residual effect of dustfall is noticed throughout the vegetational period.     

Towards a spatio-temporal multicriteria evaluation method: A suitability analysis of residential units in a 3D urban environment

Spatial multi-criteria evaluation (MCE) techniques aid urban planning management by analyzing decision problem alternatives for solutions to help inform decision-making. However, there is a lack of such methods that incorporate the temporal dimension, an important factor when analyzing the dynamic urban landscape and decisions surrounding its changes. A novel spatio-temporal MCE approach is proposed that operates in three-dimensional (3D) space and time to identify changing suitability values of decision alternatives. This space–time method is implemented to evaluate the suitability of residential units over a 15-year period in part of downtown City of Vancouver, Canada. The results indicate that the majority of units exhibit a decrease in suitability with time due to depreciation and reduction of assets like view and privacy from the construction of new buildings. The proposed method can be used by urban planners and developers to assist in long-term assessments of proposed development scenarios and their impact on existing urban infrastructure.     

A modeling study of the physical processes affecting the development of seasonal hypoxia over the inner Louisiana-Texas shelf: Circulation and stratification

The physical processes affecting the development of seasonal hypoxia over the Louisiana-Texas shelf were examined using a high-resolution, three-dimensional, unstructured-grid, Finite Volume Coastal Ocean Model (FVCOM). The model was forced with the observed freshwater fluxes from the Mississippi and Atchafalaya Rivers, surface winds, heat fluxes, tides and offshore conditions. The simulations were carried out over a six-month period, from April to September 2002, and the model performance was evaluated against several independent series of observations that included tidal gauge data, Acoustic Doppler Current Profiler (ADCP) data, shipboard measurements of temperature and salinity, vertical salinity and sigma-t profiles, and satellite imagery. The model accurately described the offshore circulation mode generated over the Louisiana-Texas shelf by the westerly winds during summer months, as well as the prevalent westward flow along the coast caused by the easterly winds during the rest of the study period. The seasonal cycle of stratification also was well represented by the model. During 2002, the stratification was initiated in early spring and subsequently enhanced by the intensity and phasing of riverine freshwater discharges. Strong stratification persisted throughout the summer and was finally broken down in September by tropical storms. The model simulations also revealed a quasi-permanent anticyclonic gyre in the Louisiana Bight region formed by the rotational transformation of the Mississippi River plume, whose existence during 2002 was supported by the satellite imagery and ADCP current measurements. Model simulations support the conclusion that local wind forcing and buoyancy flux resulting from riverine freshwater discharges were the dominant mechanisms affecting the circulation and stratification over the inner Louisiana-Texas shelf.     

Line Shape Variability in a Sample of AGN with Broad Lines

The spectral variability of active galactic nuclei (AGN) is one of the key features that enables us to study in more detail, the structure of AGN emitting regions. Especially, the broad line profiles that vary both in flux and shape, give us invaluable information about the kinematics and geometry of the broad line region (BLR) where these lines are originating from. We give here a comparative review of the line shape variability in a sample of five type 1 AGNs, those with broad emission lines in their spectra, of the data obtained from the international long-term optical monitoring campaign coordinated by the Special Astrophysical Observatory of the Russian Academy of Science. The main aim of this campaign is to study the physics and kinematics of the BLR on a uniform data set, focusing on the problems of the photoionization heating of the BLR and its geometry, where, in this paper, we give for a first time, a comparative analysis of the variabilty of five type 1 AGNs, discussing their complex BLR physics and geometry in the framework of the estimates of the supermassive black hole mass in AGN.     

Asteroid long-periodic perturbations: The second order Hamiltonian

The Hamiltonian of the second order with respect to the disturbing mass, as defined in the higher order-higher degree theory of asteroid secular perturbations by Yuasa (1973), is expressed in the heliocentric, ecliptic coordinate system. Errors found in the original paper with terms coming from the principal part of the disturbing function are removed, and corrected values of the coefficients are computed. The importance of second-order perturbations and the improvement in the accuracy of proper element determination, achieved by using the newly-obtained coefficients, are demonstrated. Finally, a table of the secular frequencies as functions of the semimajor axis is given, and compared with the analogous one by Kozai (1979).     

The Kyoto Protocol Emission Allocations: Windfall Surpluses for Russia and Ukraine

The emission targets adopted in the Kyoto Protocol¹ far exceed thelikely level of emissions from Russia and Ukraine. These countries could selltheir surplus if the Protocol is followedand industrialized countries establish an international emission tradingsystem. Critics have condemned the potentialsale and dubbed the surplus hot air because it does not represent anyreduction in emissions below the level thatwould have occurred anyway. Using the most recent, comprehensive regionalscenarios² for the emissions of carbon dioxide from the energysystem, we estimate that during the Protocol's2008–2012 budget period the surplus will range from 9 MtC (milliontons of carbon) to 900 MtC for Russia andfrom 3 MtC to 200 MtC for Ukraine. Even scenarios with high economic growthand carbon-intensive technologies donot exhaust the surplus before the budget period. In the central (middlecourse) scenario, the total carbon surplusexceeds 1000 MtC and is worth 22 to 170 billion U.S. dollars (4 to 34 billionU.S. dollars per year). This flow ofrevenues, which could exceed Russian earnings from natural gas exports($10 billion in 1997³), is comparable with the projectedtotal investmentsof the Russian energy system for 2008–2012. If directed towardslow-carbon infrastructure investments (e.g., gaspipelines), surplus transfers could reinforce and partially lock-indecarbonization of the world energy system.