Cation exchange capacity of loess and overlying soil in the non-carbonate loess sections, North-Western Croatia

The adsorption properties in terms of cation exchange capacity and their relation to the soil and sediment constituents (clay minerals, Fe-, Mn-, and Al-oxyhydroxides, organic matter) were investigated in loess, soil-loess transition zone, and soil at four loess-soil sections in North-Western Croatia. Cation exchange capacity of the bulk samples, the samples after oxalate extraction of Fe, Mn and Al, and after removal of organic matter, as well as of the separated clay fraction, was determined using copper ethylenediamine. Cation exchange capacity (pH～7) of the bulk samples ranges from 5 to 12 cmol _c /kg in soil, from 7 to 15 cmol _c /kg in the soil-loess transition zone, and from 12 to 20 cmol _c /kg in loess. Generally, CEC values increase with depth. Oxalate extraction of Fe, Mn, and Al, and removal of organic matter cause a CEC decrease of 3–38% and 8–55%, respectively, proving a considerable influence of these constituents to the bulk CEC values. In the separated clay fraction (<2 μm) CEC values are up to several times higher relative to those in the bulk samples. The measured CEC values of the bulk samples generally correspond to the clay mineral content identified. Also, a slight increase in muscovite/illite content with depth and the vermiculite occurrence in the loess horizon are concomitant with the CEC increase in deeper horizons, irrespective of the sample pretreatment.     

Height transformation models from ellipsoidal into the normal orthometric height system for the territory of the City of Zagreb

The paper presents the testing of the possibility of determining the heights of GPS points in the homogeneous field in the new Croatian Height Reference System (HVRS71) by using the method of height transformation. The testing was made in the area of Zagreb. As part of the field works, normal orthometric heights of 27 GPS points were determined according to the new height system, by transferring the benchmark heights using the geometric levelling method, thus obtaining GPS/levelling points of known ellipsoidal and normal orthometric heights. The GPS/levelling points served as the basis for determining the transformation models that enabled the computation of normal orthometric heights from ellipsoidal heights of any GPS point in the observed area. The empirical data used for modelling were reduced undulation dN values of GPS/levelling points. As part of the dN modelling with parametric functions, the approximation surfaces were obtained on the basis of three polynomials: FN310, FN312 and FN318. The transformation models were also tested using non-parametric Watson and Loess algorithms. The FN318 and Loess models yielded the best results.     

Deep water ventilation traced by <Emphasis Type="Italic">Synechococcus</Emphasis> cyanobacteria

The paper describes a finding of photoautotroph cyanobacteria Synechococcus in deep Adriatic waters during the spring of 2006. The maximum abundance in early May was positioned at 800 m, being of order of the values referred for the surface waters in the Adriatic Sea. The deep abundance maximum has been associated to the fast ventilation of deep Adriatic waters, usually occurring during wintertime strong cooling events. Two processes were detected: (1) deep convection in the South Adriatic Pit (SAP) and (2) density current going downslope. The first process was responsible for bringing the cyanobacteria down to 600-m depth in the area of convection, and the second one triggered the downslope transport of the cyanobacteria to the SAP very bottom. The depletion rate of Synechoccocus cyanobacteria in an extremely hostile environment has been computed to equal about 1 month.     

A parallel mesh-free contaminant transport model based on the Analytic Element and Streamline Methods

This paper introduces a new method for simulating large-scale subsurface contaminant transport that combines an Analytic Element Method (AEM) groundwater flow solution with a split-operator Streamline Method for modeling reactive transport. The key feature of the method is the manner in which the vertically integrated AEM flow solution is used to construct three-dimensional particle tracks that define the geometry of the Streamline Method. The inherently parallel nature of the algorithm supports the development of reactive transport models for spatial domains much larger than current grid-based methods. The applicability of the new approach is verified for cases with negligible transverse dispersion through comparisons to analytic solutions and existing numerical solutions, and parallel performance is demonstrated through a realistic test problem based on the regional-scale transport of agricultural contaminants from spatially distributed sources.     

Azimuthal anisotropy of the Pg-wave velocity in hypocentral volumes of NW Croatia

Based on a large set of arrival times of the Pg phase reported by local and regional stations, we estimate azimuthal anisotropy of the Pg-wave velocity in focal volumes of the upper crust in NW Croatia. The method is based on analyses of the azimuthal dependence of ratios of cumulative differences of arrival times and travel paths between foci of earthquake pairs, computed for rays propagating within narrow azimuthal windows. The results clearly indicate the presence of anisotropy of 3.3% with the direction of fast velocity (approximately NNE-SSW) coinciding with the direction of the maximum tectonic pressure as revealed by 23 available focal mechanisms and previous geological investigations. Although a large part of observed anisotropy can be explained assuming that focal volumes are pervaded by a system of vertical extensive-dilatancy anisotropy (EDA) cracks aligned under the influence of local tectonic stress field, there is indication that — to a smaller extent — some role was also played by alignment of structural features in the region.     

Changes in Components of the Water Balance in the Croatian Lowlands

Summary ?This paper deals with variations and trends in some components of the water balance: the soil water content; evaporation loss from the soil (from the surface and underlying layers); transpiration; ground water recharge and runoff. These components are calculated by means of the Palmer procedure. This analysis is based on data from Osijek, Croatia from this century (1900–1995). Besides the meteorological input parameters necessary for the water balance calculations, i.e. precipitation, temperature and relative humidity, the pedological characteristics of this area have also been taken into account. Fluctuations have been considered by means of the 11-year binomial filtered series and linear trends were tested by means of the Mann-Kendall rank test. For a closer look on the trends of water balance components, a progressive analysis of the time series was performed, too. The results show a significant increase in potential evapotranspiration and evapotranspiration and decrease in runoff and soil water content has occurred during the century. Received February 22, 1999/Revised August 3, 1999     

Automatic grid azimuth by hour angle of the sun,a star or a planet using an electronic theodolite Kern E2

The paper deals with the automatic grid azimuth determination of an object on the earth using the electronic theodolite Kern E2 by observing the sun, a star, or a planet. The observation time and the readings of horizontal and vertical circles of the electronic theodolite enter automatically the electronic calculator Hewlett-Packard HP41CX. The calculator computes the grid azimuth of the terrestrial object and directs the observer what to do. Therefore, even a personnel without specific high education can make observations. For the solar observations it is not necessary to have an astronomical almanac, because the program computes the solar coordinates. The general input data, together with the measured ones, can be stored on a magnetic cassette and later on, if necessary, one can correct the general data and recalculate the azimuth. The method proved to be very practical in the field work.     

An analysis of close binaries (CB) based on photometric measurements (VIII)

The author considers current problems in the determination of the orbital and physical parameters for active close binaries (CB) of W Ser type based on the interpretation of photometric observations (Djuraevi, 1991). In this particular case, one analyses the light curves of CB SX Cas in the framework of the accretion-disc model explained in the second paper of this series (Djuraevi, 1992a). The light curve is analysed by applying the inverse-problem method described in the third paper of the series (Djuraevi, 1992b). On the basis of the observational material in theB andV filters (Shao, 1967), the light curves, the fundamental orbital and physical parameters of the system are estimated. In the paper a graphical illustration of the obtained solutions is also given. The obtained results confirm the general picture about the active processes in CB of W Ser type.     

Bioremediation perspective of historically contaminated sediment with polycyclic aromatic hydrocarbons

The purpose of the current study is to compare the influence of different aerobic conditions(biostimulation(BS),bioaugmentation(BA),and a combination of biostimulation and bioaugmentation(BB))on polycyclic aromatic hydrocarbons(PAH)degradation and compare the degraded amount with single step XAD-4 extraction as a new tool for bioavailability assessment for chronically contaminated sediment samples obtained from territory of Autonomous Province Vojvodina of Serbia(S1,S2,and S3).A great number of papers dealing with biodegradation of PAHs in spiked sediment or soil have been published,but to the authors’knowledge,a limited number of papers studied aged,historically polluted sediment and a sum of chosen U.S.Environmental Protection Agency(USEPA)PAHs.A significant reduction(up to67%)in PAH concentration was observed,while the percentage of reduction varied depending on the sediment sample and treatment used.BS treatment successfully stimulated growth of indigenous bacteria.Further,PAH-degrading strain Sphingomonas paucimobilis F8 inoculated in BA and BB treatment survived for up to 7 weeks after it was suppressed by unfavorable conditions or native microbes.Degraded amounts generally showed good correlation with results obtained from XAD-4 extraction.Results obtained in the current study represent a good start for standardizing a XAD-4 extraction technique as a simplified,easier,and lower cost method for bioavailability assessment.