A New Method for Low‐Temperature Decomposition of Chromites and Dichromium Trioxide using Bromic Acid Evaluated by Chromium Isotope Measurements

In recent years, routine application of the stable isotope determination of chromium (Cr) in environmental and health protection research has led to the search for simpler chromite decomposition techniques. As the range of Cr isotope abundance ratios in nature is very narrow, conventional chromite decomposition techniques are no longer suitable, due to the relatively high risk of contamination during laboratory procedures. We have developed a protocol for the decomposition of chromites based on oxidation by bromic acid at room temperature. The procedure takes 15 d and requires two doses of bromic acid during the reaction period (day 1 and 8), due to the limited stability of the reagent. Chromium extracted by alkaline oxidative fusion and by bromic acid decomposition yielded statistically indistinguishable δ⁵³Cr values, measured by multi‐collector inductively coupled plasma‐mass spectrometry following addition of a ⁵⁰Cr‐⁵⁴Cr double‐spike.     

SWAT模型在斯里兰卡河流径流预测中的运用

本文运用SWAT模型和新安江模型对斯里兰卡卡鲁河流域上游地区日径流进行了预测.卡鲁河是斯里兰卡的第二大河,由于流域的降雨量很大,上游地区河流沿峡谷流下,中下游平原地区河床平坦.卡鲁河流域的洪水变的很正常.应用SWAT模型来对卡鲁河的日径流量进行预测,并同应用新安江模型所得到的结果做对比.研究表明,新安江模型要比SWAT (分布式水文模型)模型在卡鲁河日径流量预测上稍微好一些.实际上,或许数据质量不高或不恰当是部分原因,因为SWAT的输出成果严格取决于其输入的数据质量.此外,在斯里兰卡,许多人的日常用水是靠井水.当把流域看作一个整体,通常都是一个很大的范围,那样的话就不可能详尽的记录所有各个小规模的水利用,例如:小灌溉、小规模的家畜管理和工业水利用.这些水利用累积起来或许就很可观.这些数据的缺失对分布式水文模型在水平衡的应用有着独特的影响.但是概念水文模型(如新安江模型)可以根据实际情况在校正中调节它的参数,因为这些参数并没有实质的物理含义.因此,在流域特征和模型输入数据有限或不完整的情况下,概念水文模型比分布式水文模型更具优势.     

Metavolcanic host rocks,mineralization, and gossans of the Shaib al Tair and Rabathan volcanogenic massive sulphide deposits of the Wadi Bidah Mineral District,Saudi Arabia

The Wadi Bidah Mineral District of Saudi Arabia contains more than 16 small outcropping stratabound volcanogenic Cu–Zn–(Pb) ± Au-bearing massive sulphide deposits and associated zones of hydrothermal alteration. Here, we use major and trace element analyses of massive sulphides, gossans, and hydrothermally altered and least altered metamorphosed host rock (schist) from two of the deposits (Shaib al Tair and Rabathan) to interpret the geochemical and petrological evolution of the host rocks and gossanization of the mineralization. Tectonic interpretations utilize high-field-strength elements, including the rare earth elements (REE), because they are relatively immobile during hydrothermal alteration, low-grade metamorphism, and supergene weathering and therefore are useful in constraining the source, composition, and physicochemical parameters of the primary igneous rocks, the mineralizing hydrothermal fluid and subsequent supergene weathering processes. Positive Eu anomalies in some of the massive sulphide samples are consistent with a high temperature (>250°C) hydrothermal origin, consistent with the Cu contents (up to 2 wt.%) of the massive sulphides. The REE profiles of the gossans are topologically similar to nearby hydrothermally altered felsic schists (light REE (LREE)-enriched to concave-up REE profiles, with or without positive Eu anomalies) suggesting that the REE experienced little fractionation during metamorphism or supergene weathering. Hydrothermally altered rocks (now schists) close to the massive sulphide deposits have high base metals and Ba contents and have concave-up REE patterns, in contrast to the least altered host rocks, consistent with greater mobility of the middle REE compared to the light and heavy REE during hydrothermal alteration. The gossans are interpreted to represent relict massive sulphides that have undergone supergene weathering; ‘chert’ beds within these massive sulphide deposits may be leached wall-rock gossans that experienced silicification and Pb–Ba–Fe enrichment from acidic groundwaters generated during gossan formation.     

Spatial distribution and general population characteristics of mysid shrimps in the Westerschelde estuary (SW Netherlands)

The distribution and general population characteristics of five mysid shrimps were investigated in the period 2003–2005 in the Westerschelde estuary, a tidal temperate estuary situated along the Dutch–Belgian border. Multivariate analyses revealed that salinity predominantly governs the spatial distribution of Neomysis integer, Gastrosaccus spinifer, Schistomysis kervillei and Schistomysis spiritus while temperature, and to a lesser extent turbidity, control the distribution of Mesopodopsis slabberi. N. integer is a resident species in the mesohaline zone of the estuary, i.e. all life stages of the species are present in the estuary throughout the year. For the first time since decades N. integer inhabits the oligohaline zone of the estuary supposedly as a consequence of improved oxygen conditions in the upstream reaches. M. slabberi, the most abundant mysid in the Westerschelde, dominates the hyperbenthos of the mesohaline zone of the estuary. The polyhaline zone of the estuary is, most abundantly inhabited by M. slabberi, G. spinifer, S. kervillei and to a lesser extent by S. spiritus. The abundance of the latter four species is low in winter, probably due to a migration towards coastal waters to avoid colder temperatures in the estuary combined with an increased mortality after breeding. The sex ratio of all the mysid populations corresponds to the expected 1:1 female:male ratio and no salinity governed segregation is found between the different life stages of each mysid population. A seasonal variation exists in brood size in the N. integer population regardless of the body size, with a larger number of broods during winter and spring compared to the summer. In the other mysid populations the brood sizes vary only with the length of the ovigerous females.     

Biomass Size Spectra of Near-Shore Shallow-Water Benthic Communities in the Gulf of Gdańsk Southern Baltic Sea

The concept of size spectra, developed by S heldon & P arsons 1967 and S heldon et al. 1972, seeks to describe community structure by evoking the distribution of biomass over a sequence of equal intervals of the logarithm of body size. In this study, biomass size spectra were prepared for benthic macro- and meiobenthos communities at 5 stations, differing in their sediment characteristics, located in the shallow, coastal area of the Gulf of Gdańsk Southern Baltic Sea. The purpose of this study was to determine whether the community spectra would allow distinct separation of ecological categories of the benthos and whether habitat differences between stations would significantly affect benthic size spectra.
Benthic biomass at the stations sampled depended mainly on nematodes and oligochaetes among the meiobenthos and on hydrobiid snails and M. edulis among the macrobenthos. Regardless of habitat, size spectra peaked initially at the meiofaunal range weight class 25 1. 19–501.19 ng C, identical to that reported in other studies. The separation between meio- and macrobenthic peaks, however, was not as pronounced as that found in other studies. Normalized size spectra demonstrated that most of the variations in the spectra between stations was introduced by macrobenthos, which differed between the coarse- and fine-grained sediments. Nonetheless, those differences were not strong enough to significantly affect the spectra. In consequence, the benthic biomass spectra of all the stations were found to conform to a common pattern and could be represented by a single, average spectrum.     

Cenozoic alongslope processes and sedimentation on the NW European Atlantic margin

Based on studies of sediment accumulations deposited from-and erode by-alongslope flowing ocean currents on the European continental margin from Porcupine (Ireland) to Lofoten (Norway), the evolution of the Cenozoic paleocirculation was reconstructed as part of the STRATAGEM project. There is evidence of ocean current-controlled erosion and deposition in the Rockall Trough, in the Faeroe-Shetland Channel and on the Vøring Plateau since the late Eocene, although the circulation pattern remains ambiguous. The late Palaeogene flow in the Rockall Trough was almost probably driven by southerly-derived Tethyan Outflow Water. The extent and strength of any northerly-derived flow is uncertain. From the early Neogene (early-mid-Miocene), there was a massive regional expansion of contourite drift development both in the North Atlantic and in the Norwegian-Greenland Sea. This was most probably related to the development of the Faroe Conduit, the opening of the Fram Strait and the general subsidence of the Greenland-Scotland Ridge. These may have combined to cause a considerable acceleration in the exchange and overflow of deep waters between the Arctic and Atlantic Oceans. An early late Neogene (late early Pliocene) regional erosional event has been ascribed to a vigorous pulse of bottom-current activity, most probably the result of a global reorganisation of ocean currents associated with the closure of the Central American Seaway. During the late Neogene, contourites and sediment drifts developed in deep-water basins, between units of glacigenic sediments as well as infill of several paleo-slide scars. These sediments were derived from areas of bottom-current erosion as well as from the development of Plio-Pleistocene prograding sediment wedges, incorporating the extensive sediment supply derived from shelf-wide ice sheets. Presently a profound winnowing prevails along the shelf and upper slope due to the inflowing currents of Atlantic water. Depocentres of sediments derived from the winnowing are located (locally) in lower slope embayments and in slide scars.