Dissolved vanadium in rivers and estuaries

New measurements of dissolved vanadium in a variety of rivers and estuaries are presented here. The data indicate that the average concentration of dissolved vanadium in major rivers entering the ocean is 15 nmol/kg. Weathering rate and type of source rock, rather than solution chemistry or anthropogenic influences, appear to be the important factors in determining fluvial dissolved vanadium concentrations. Laboratory experiments suggest that in oxic waters vanadium is found predominantly in its most oxidized, anionic form (V(V)). Complexation with organic matter and formation of large colloidal species appear to be unimportant. Adsorption also appears to be a less important influence for vanadium than for some other trace elements such as zinc.In estuaries, vanadium behaves as a bioactive element, showing a close correspondence with the distribution of phosphate. The extent of estuarine vanadium removal is presently uncertain but may be low due to rapid remineralization of this element. Based on the river flux, the oceanic residence time for dissolved vanadium is estimated to be 100,000 years.     

Secondary flows and the pool-riffle unit: A case study of the processes of meander development

The major bedforms of gravel bed rivers, whether braided, meandering or straight, may be usefully resolved into pool-riffle units, each comprising a single scour pool together with an associated depositional shoal downstream. At low flow, the latter may be characterized by a single emergent bar-head and submerged riffle, or by a variety of remnant braid bars, depending upon the type of channel. Identification of pool-riffle units and observation of associated flow structures on a small meandering stream in northwest England has demonstrated important links between bedforms, flow patterns and channel change. Each unit appears to be associated with a systematic pattern of secondary flows, which are able to modify the bedforms and initiate meander development. Feedback links between plan morphology, flow patterns and erosive and depositional forces within these units ensure that each stage of meander growth has a characteristic style of channel change. Consequently, meanders tend to evolve by regular cycles of increasing curvature and complexity.     

Seasonal changes in surface level of a salt marsh creek

Nineteen surveys were carried out over a two-year period to determine the surface height of a salt marsh creek located on the north side of the River Esk, Cumbria, England. An AGA 112 electromagnetic distance measurer mounted on a Wild TI theodolite was used in conjunction with acrylic reflectors to follow the form of the ground. The results showed that there were no significant net trends in surface level, although seasonal variations of the order of 2 cm occurred. Vegetated areas responded in similar fashion to bare surfaces. It is thought that the elevational changes were attributable to the swelling of clay particles during the winter months rather than the effects of erosion and accretion.     

Effects of the Black River (Cape,South Africa) on the distribution and survival of marine psammofauna

The physicochemistry of the Black River and adjacent marine beach, in terms of tidal, daily and seasonal fluctuations of temperature and salinity, presents a highly stressed environment exacerbated by canalization of the river mouth. Riverine pollution further stresses this environment, producing low densities and diversities of marine infauna adjacent to the river. No fauna were found in the river mouth where typical estuarine conditions exist only during high tide. Tolerance of the dominant marine species, Cerebratulus fuscus, to temperature, salinity and river water combinations showed that mortality was more rapid after exposure to river water dilutions than after exposure to distilled water dilutions. Computer-generated models suggested that this species should survive conditions closer to the river than were observed. This confirmed additional stress due to pollution carried in the river from urban and industrial drainage. Lower river water temperatures during winter appear to ameliorate pollution stress, enhancing survivability of the infauna.     

Aliphatic components of Victorian brown coal lithotypes

Victorian brown coal occurs in five major lithotypes distinguishable by colour index, petrography and bulk chemical analyses. The distributions of solvent extractable (free) and base hydrolysable (bound) n-alkanes, n-monocar?ylic acids, n-?,ω-dicar?ylic acids, n-ω-hydroxycar?ylic acids and n-alcohols were determined for samples of each of the five lithotypes (lithotype profile) and for seven samples of identical lithotype classification spanning a 100 m interval (depth profile) taken from a continuous bore core. The distributions of free molecular components in all classes are indicative of the predominant higher plant origin of this immature coal and provide strong support for the view that different lithotypes have derived from different, yet fairly specific paleobotanical communities. Despite an overall similarity in the distributions of aliphatic components from samples of identical lithotype classification, changes in the absolute concentrations and carbon preference indices (CPIs) of specific functional classes are observed in response to catagenetic influences even across the very small rank interval of the depth profile samples. Molecular distributions of bound components are similar to those of their free counterparts except that CPIs are generally lower and the relative contributions of lower molecular weight homologues (i.e. <C₂₂) are higher. Thedistributions of bound dicar?ylic acids and hydroxycar?ylic acids appear to reflect variations in the oxic/anoxic nature of the depositional paleoenvironments.     

The Blithfield meteorite and the origin of sulfide-rich,metal-poor clasts and inclusions in brecciated enstatite chondrites

Blithfield (EL6) is one of five known enstatite chondrite breccias. It consists of troilite-rich clasts (35 ± 5vol.%) embedded in an extremely metallic Fe,Ni-rich matrix (65 ± 5 vol.%) that contains metal nodules up to 17 mm in size. Clasts and matrix agglomerated independently in the solar nebula under conditions of high and lowpS₂/pO₂ ratios, respectively. The matrix accreted to an EL chondrite planetesimal and was metamorphosed to～ 1000°C, above the FeNiS eutectic; chondrule textures were obliterated. The S-rich eutectic melt was lost from the matrix. The matrix material was buried to a depth of at least 3 km; accreting troilite-rich material was incorporated into the matrix as clasts. The breccia cooled through～ 500°C at 1000–10,000°C/Myr. After cooling below～ 500°C, Blithfield was quenched, possibly by impact excavation from depth and deposition onto the surface.Clasts or inclusions that are enriched in sulfide and depleted in metallic Fe,Ni are common in brecciated enstatite chondrites. Variations in thepS₂/pO₂ ratio in the nebular regions where these materials formed may explain many of their petrologic properties. The silica-rich clasts in Adhi Kot (EH4) formed at very highpS₂/pO₂ratios(> 10²⁷); niningerite, free silica and troilite were produced from the sulfurization of enstatite and metallic Fe. The troilite-rich clasts in Blithfield and Atlanta (EL6) as well as the troilite-rich regions of the Hvittis (EL6) matrix formed at somewhat lowerpS₂/pO₂ ratios where sulfurization of metalic Fe produced troilite. The Ni content of the residual metal increased, forming some metal of martensitic composition. The dark inclusions in Abee (EH 4), which contain up to 9 wt.% oldhamite, formed at highpS₂/pO₂ ratios in the presence of an additional Ca-rich component.     

Chemical and physical studies of type 3 chondrites—III. Chondrules from the Dhajala H3.8 chondrite

Fifty-eight chondrules were separated from the Dhajala H3.8 chondrite and their thermoluminescence properties were measured. Chips from 30 of the chondrules were examined petrographically and with electron-microprobe techniques; the bulk compositions of 30 chondrules were determined by the fused bead technique. Porphyritic chondrules, especially 5 which have particularly high contents of mesostasis, tend to have higher TL (mass-normalized) than non-porphyritic chondrules. Significant correlations between log(TL) and the bulk CaO, Al₂O₃ and MnO content of the chondrules, and between log(TL) and the CaO, Al₂O₃, SiO₂ and normative anorthite content of the chondrule glass, indicate an association between TL and the abundance and composition of mesostasis. Unequilibrated chondrules ( i.e. those whose olivine is compositionally heterogeneous and high in Ca) have low TL, whereas equilibrated chondrules have a wide range of TL, depending on their chemical and petrographic properties.We suggest that the TL level in a given chondrule is governed by its bulk composition (which largely determined the abundance and composition of constituent glass) and by metamorphism (which devitrfied the glass in those chondrules with high Ca glass to produce the TL phosphor). We also suggest that one reason why certain chondrules in type 3 ordinary chondrites are unequilibrated, while others are equilibrated, is that the mesostasis of the unequilibrated chondrules resisted the devitrification. This devitrification is necessary for the diffusive communication between chondrule grains and matrix that enables equilibration.     

A wind tunnel study of turbulent flow over model hills

Detailed wind tunnel measurements have been made of mean flow and turbulence over a two-dimensional ridge and a circular hill, both having cosine-squared cross-section and maximum slope about 15 °. The measurements were made in an artificially thickened neutrally stratified boundary layer, and have been compared with results from linear models and rapid distortion theory as appropriate.Our study shows that linear theory gives generally good predictions of the mean flow on the upwind side of the hills, and especially of the flow speedup at the hill top, but that the turbulence is less well predicted. In particular, the measurements show a major increase in the vertical component of turbulence and in the shear stress on the upwind slope of both the two- and three-dimensional hills which is not predicted by either equilibrium or isotropic rapid-distortion theories, although this may be partly due to the effect of streamline curvature. Rapid-distortion theory is successful only in describing the streamwise component of turbulence in the outer region of the flow, while in the upper part of the inner region of the flow, the turbulence measurements show disagreement with both the equilibrium and the rapid-distortion theories. Our experiments also confirm that the equilibrium region is a very thin layer close to the surface, while above this region and below the outer region, there is a transitional region where all terms in the stress equation are important.The measurements over the three-dimensional hill suggest that the mean flow and turbulence are broadly similar to those over the two-dimensional ridge, but with reduced perturbation amplitudes. The major differences between the two cases are found on the upwind slope and in the wake where, respectively, horizontal divergence and convergence of the three-dimensional flow are most pronounced.