Concentrations of 222 Rn, Its Short-Lived Daughters And 212 Pb And Their Ratios Under Complex Atmospheric Conditions And Topography

Atmospheric activity concentrations of ²¹²Pb and short-lived ²²²Rndaughters, together with meteorological elements, have been observed continuously atthree sites at Kamisaibara Village in Japan. In addition, atmospheric activity concentrationof ²²²Rn, equilibrium-equivalent concentration of ²²²Rn and conditionsof the lower atmosphere were observed for three intensive observation periods at Akawase,one of the three sites in Kamisaibara Village. The equilibrium-equivalent concentration of²²²Rn is almost the same as the atmospheric activity concentration of short-lived²²²Rn daughters.The activity concentrations of ²¹²Pb and the short-lived ²²²Rn daughtersand their ratio were low in the daytime owing to convective mixing, and high at nightowing to the surface-based inversion during periods of no precipitation. Their variationshave several patterns corresponding to the scale of the drainage wind or weak mixing.Mechanical mixing due to strong winds through both day and night during the first andsecond observation periods made the atmospheric activity concentrations of ²¹²Pb and the short-lived ²²²Rn daughters continuously low. However, their ratios werecontinuously high during the first period yet continuously low during the second period.This difference can be explained by the effect ofextraction of ²²⁰Rn and ²²²Rndue to strong winds and snow cover. There were also cases in which the ratio of theatmospheric activity concentration of ²¹²Pb to that of the short-lived ²²²Rndaughters at night was equal to or less than the ratio in the daytime. Thisinverse trend, asin the periods of no precipitation mentioned above, is considered to be due to near-neutralconditions on these nights.We find a difference in the ratio of the equilibrium-equivalent concentration of²²²Rn (the activity concentration of short-lived ²²²Rn daughters) tothe activity concentration of ²²²Rn during the first observation period and thatduring the second. The difference can be explained by snow cover on the ground. Wealso find differences among the ratios of the activity concentration of the short-lived²²²Rn daughters to that of ²²²Rn during the three observation periods.These differences can be explained by the submergence of paddy fields.     

Geochemical Features of Vein Anhydrite from the Kakkonda Geothermal System, Northeast Japan

Abstract. Cathodoluminescence (CL) color, rare earth element (REE) content, sulfur and oxygen isotopes and fluid inclusions of anhydrite, which frequently filled in hydrothermal veins in the Kakkonda geothermal system, were investigated to elucidate the spatial, temporal and genetical evolution of fluids in the deep reservoir. The anhydrite samples studied are classified into four types based on CL colors and REE contents: type-N (no color), type-G (green color), type-T (tan color) and type-S (tan color with a high REE content). In the shallow reservoir, only type-N anhydrite is observed. In the deep reservoir, type-G anhydrite occurs in vertical veins whereas type-T and -N in lateral veins. Type-S anhydrite occurs in the heat-source Kakkonda Granite. The CL textures revealed that type-G anhydrite deposited earlier than type-T in the deep reservoir, implying that fracture system was changed from predominantly vertical to lateral.
Studies of fluid inclusions and δ³⁴S and δ¹⁸O values of the samples indicate that type-N anhydrite deposited from diluted fluids derived from meteoric water, whereas type-G, -T and -S anhydrites deposited from magmatic brines derived from the Kakkonda Granite with the exception of some of type-G with recrystallization texture and no primary fluid inclusion, which deposited from fossil seawater preserved in the sedimentary rocks. Type-G, -T and -S anhydrites exhibit remarkably different chondrite-normalized REE patterns with a positive Eu anomaly, with a convex shape (peak at Sm or Eu) and with a negative Eu anomaly, respectively. The difference in the patterns might result from the different extent of hydrothermal alteration of the reservoir rocks and contribution of the magmatic fluids.     

青藏高原草甸下垫面湍流强度相似性关系分析

利用“全球能量水循环之亚洲季风青藏高原试验(GAME／Tibet)”1998年加强期(IOP)的观测资料，分析研究了青藏高原草甸下垫面上的无量纲风速、温度及湿度方差相似性，并与HEIFE戈壁沙漠和绿洲及海洋下垫面作了比较，得到了一些有关青藏高原草甸下垫面上动力及热力学参数的有益的结论。     

Rare earth element distribution in the Melrose-b howardite: Pre-terrestrial negative Ce anomaly

In order to investigate the genetic nature of the polymict breccia howardite Melrose-b, a whole-rock sample was separated into four fractions after pulverization and the rare earth element (REE) abundances were precisely determined by isotopic dilution in those fractions. Such an investigation shows that the three precipitated fine-particle fractions are depleted in Ce by the same factor (0.62 ～ 0.64) in spite of differences in mineralogy, while the corresponding factor of Ce depletion for the suspended-matter fraction is 0.462; the smaller value indicates a greater depletion in Ce.The weight fraction values of four fractions calculated from the REE abundances are in satisfactory agreement with the actual values. The concentration ratios between plagioclase and mainly pigeonite fractions accord with those observed in similar phases of the Juvinas eucrite [1]. Moreover, the bulk pattern synthesized from the three fine-particle fractions is similar in absolute level to that for the Zmenj howardite [1]. It is concluded that the negative Ce anomaly reflects the effect predating the igneous activity in the parent planetary body.     

High resolution OSL dating back to MIS 5e in the central Sea of Okhotsk

Marine sediments contain important archives of past ocean and climate changes, but at high latitudes the absence of carbonate has prevented the construction of accurate chronological models. We have begun a study to (1) determine the accuracy of luminescence ages in deep-sea marine sediments, e.g. by comparison with marine oxygen isotope stratigraphy where possible, (2) describe changes in sedimentation rate through time, and (3) test whether it is possible to date back to marine isotope stage 5e (MIS 5e). We show here that optical dating of fine grains of quartz from the central Sea of Okhotsk is able to provide an accurate and precise chronology for the reconstruction of the palaeoceanic and palaeoclimatic environment at our site. The upper 6.5 m of the 18.42 m long core MR0604-PC07A is believed, based on its magnetic susceptibility and the oxygen isotope (δ¹⁸O) records to contain the last ～150 ka. Forty OSL samples were taken from this upper part of the core. The single-aliquot regenerative-dose (SAR) procedure is used for equivalent dose (D_e) determination. The luminescence characteristics of fine-grained quartz (4–11 μm) extracted from the core are described. The OSL signal is dominated by the fast component and a dose recovery test shows that we can accurately measure a known dose given in the laboratory prior to any heat treatment. Dose rates were determined using high-resolution gamma spectrometry, and vary between 0.4 and 1.6 Gy/ka. The OSL ages from this section lie between ～140 ka and ～15 ka and are in very good agreement with the δ¹⁸O stratigraphy up to MIS 5e. A clear change in sedimentation rate is identified: between ～139 and 110 ka, the sedimentation rate was ～0.09 m/ka, but then from ～110 to 15 ka, the sedimentation rate decreases to a constant value of ～0.04 m/ka. Our data confirm that OSL dating using widely distributed fine-grain quartz has great potential for dating deep-sea sediments. Because luminescence methods use clastic materials, they do not depend on the presence of biogenic carbonate. As a result it is now likely that we can establish a chronology in regions of the ocean that were previously undatable.     

Optical dating of a Japanese marker tephra using plagioclase

The luminescence characteristics of volcanic plagioclase from an andesitic tephra (Hakone-Tokyo pumice, Hk-TP) from Japan were studied in order to assess if optical dating of plagioclase could be applied to Quaternary tephra. The tephra was shown to contain two kinds of plagioclase grains, labradorite which had a smooth surface and bytownite with a rough surface. The aliquots consisting of smaller grains contained more bytownite; these showed higher luminescence sensitivity and a higher fading rate compared to the larger-grained aliquots containing only labradorite. The fading rates of both OSL and IRSL signals were similar for each grain size. However, the OSL signal showed severe thermal transfer which made it difficult to use for dating. Using the IRSL signal from grains ranging from 150 to 212 μm, an age was obtained in agreement with the independent evidence, once a small fading correction had been applied.     

Diurnal and inter-monthly variation of land surface heat fluxes over the central Tibetan Plateau area

Summary The energy and water cycle over the Tibetan Plateau play an important role in the Asian monsoon system, which in turn is a major component of both the energy and water cycles of the global climate system. Using field observational data observed from the GAME/Tibet (GEWEX (Global Energy and Water cycle Experiment) Asian Monsoon Experiment on the Tibetan Plateau) and the CAMP/Tibet (CEOP (Coordinated Enhanced Observing Period) Asia-Australia Monsoon Project (CAMP) on the Tibetan Plateau), some results on the local surface energy partitioning (diurnal variation, inter-monthly variation and vertical variation etc.) are presented in this study.The study on the regional surface energy partitioning is of paramount importance over heterogeneous landscape of the Tibetan Plateau and it is also one of the main scientific objectives of the GAME/Tibet and the CAMP/Tibet. Therefore, the regional distributions and their inter-monthly variations of surface heat fluxes (net radiation flux, soil heat flux, sensible heat flux and latent heat flux) are also derived by combining NOAA-14/AVHRR data with field observations. The derived results were validated by using the ground truth, and it shows that the derived regional distributions and their inter-monthly variations of land surface heat fluxes are reasonable by using the method proposed in this study. Further improvement of the method and its applying field were also discussed.     

Rhenium and osmium systematics on iron and stony iron meteorites

Abstract— Re and Os abundances and ¹⁸⁷Os/¹⁸⁶Os isotopic ratios in 12 iron meteorites of various groups and five stony iron meteorites have been determined by an inductively coupled plasma mass spectrometry (ICP-MS). The series of iron meteorites studied have Re and Os concentrations ranging from 0.004 to 3.3 ppm and 0.03 to 41 ppm, respectively. The ¹⁸⁷Re/¹⁸⁶Os ratios in these meteorites fall between 3.0 and 6.1 and the ¹⁸⁷Os/¹⁸⁶Os between 1.0 and 1.2, giving an initial ¹⁸⁷Os/¹⁸⁶Os isotopic ratio of 0.790 and a Re-Os age of iron meteorites of 4.30 ± 0.28 Ga when employing the decay constant of 1.64 × 10^?11 yr^?1. The observed Re-Os age for iron meteorites appears somewhat younger than that for chondrites. The resultant younger age might be due either to a very slow cooling of the parental planetesimals or due to a secondary “shock” event. However, for definite conclusions about the Re-Os age, higher precisions of the Re and Os isotopic measurements and of the decay constant of ¹⁸⁷Re are required. Furthermore, the clear elucidation of the mechanisms for the fractionation of the Re/Os abundance ratios are related to the understanding of the meaning of the Re-Os age. The Re and Os abundances in pallasite stony iron meteorites are extremely low compared with those for most iron meteorites. On the other hand, the Re and Os abundances in mesosiderite stony iron meteorites show values comparable with those observed in most iron meteorites. The difference in Re and Os abundances in pallasite and mesosiderite stony iron meteorites strongly suggests that these stony iron meteorites are different in origin or history of chemical evolution. Re and Os abundances in the series of iron and stony iron meteorites were found to have a wide variation covering nearly four orders of magnitude, with a very high correlation coefficient (0.996), and a slope very slightly less than unity. The regression line observed here covers various groups of iron meteorites, stony iron meteorites and also chondrites. Masuda and Hirata (1991) suggested the possible direct mixing process of particles of most refractory metallic elements with gaseous clouds of less refractory matrix elements, since the Re and Os were predicted theoretically to be the first elements to condense as a solid phase from the high temperature solar nebula. The aims of this paper are to present a reliable technique for the Re-Os chronology and to study the cosmochemical sequences of the meteoritic metals.     

Quartz and polymineral luminescence dating of Japanese loess over the last 0.6 Ma: Comparison with an independent chronology

There are only a few luminescence dating studies of loess sediments in Japan, but interleaved with these deposits are many well-described tephras of known age based on ¹⁴C and fission track analysis; these independent age controls provide an opportunity to test the reliability of loess luminescence ages. This study provides such a comparison at two sites in central Honshu, the largest island in the Japanese archipelago. Samples were collected from sequences of interleaved volcanic tephra and loess deposited on a Middle Pleistocene river terrace in the Niigata Prefecture and on an Early to Middle Pleistocene dissected fluvial surface at in the Tochigi Prefecture, Honshu. Equivalent doses (D_e) were estimated from fine grains (4–11 μm) using both polymineral IR-OSL and (post-IR) blue-OSL, and quartz blue-OSL. The blue-stimulated luminescence signals could be represented by up to three exponentially decaying components; only the most light sensitive of these components was used in the final D_e estimation. Almost all the estimates of D_e from polymineral IR-OSL are smaller than those from polymineral (post-IR) blue-OSL and quartz blue-OSL, whereas the latter two are in good agreement. The blue-light stimulated luminescence ages using the most light sensitive component are shown to be in good agreement with the independent control, up to 500 ka. Although the IR-OSL signals underestimate the known age, a simple laboratory fading test is found empirically to correct for this underestimation. We conclude that the most rapidly blue-stimulated luminescence signals from quartz extracted from our loess samples give reliable ages, and that future loess dating studies should concentrate on these signals.