Rare earth elements in metagabbros from the Mid-Atlantic Ridge and their possible implications for the genesis of alkali olivine basalts as well as the lizard peridotite

Two foliated metagabbros from the Mid-Atlantic Ridge near 30° N were analyzed for rare earth elements. The chondrite-normalized rare earth pattern for one of them is quite similar to those for abyssal tholeiites. The pattern for another sample, however, is somewhat different from the above one. A new set of bulk partition coefficients for rare earth elements has been estimated correspondingly. This set throws a new light on the interpretation that many alkali olivine basalts were produced by a zone melting or partial melting of primary-liquid-type material. Also the same partition coefficients lead us to an inference that the high-temperature peridotite intrusion in the Lizard area, Cornwall, England, is a secondary-solid-type material which was once in equilibrium with a primary-solid-type material, whereas the pyroxenite, Canyon Mountain, Oregon, is a primary-solid-type material.Both of the metagabbros studied show positive europium anomaly.     

Importance of geochemical transformations in determining submarine groundwater discharge-derived trace metal and nutrient fluxes

Seasonal (Spring and Summer 2002) concentrations of dissolved (<0.22 μm) trace metals (Ag, Al, Co, Cu, Mn, Ni, Pb), inorganic nutrients (NO₃, PO₄, Si), and DOC were determined in groundwater samples from 5 wells aligned along a 30 m shore-normal transect in West Neck Bay, Long Island, NY. Results show that significant, systematic changes in groundwater trace metal and nutrient composition occur along the flowpath from land to sea. While conservative mixing between West Neck Bay water and the groundwaters explains the behavior of Si and DOC, non-conservative inputs for Co and Ni were observed (concentration increases of 10- and 2-fold, respectively) and removal of PO₄ and NO₃ (decreases to about half) along the transport pathway. Groundwater-associated chemical fluxes from the aquifer to the embayment calculated for constituents not exhibiting conservative behavior can vary by orders of magnitude depending on sampling location and season (e.g. Co, 3.4 × 10²– 8.2 × 10³ μmol d⁻¹). Using measured values from different wells as being representative of the true groundwater endmember chemical composition also results in calculation of very different fluxes (e.g., Cu, 6.3 × 10³ μmol d⁻¹ (inland, freshwater well) vs. 2.1 × 10⁵ μmol d⁻¹(seaward well, S = 17 ppt)). This study suggests that seasonal variability and chemical changes occurring within the subterranean estuary must be taken into account when determining the groundwater flux of dissolved trace metals and nutrients to the coastal ocean.     

OSL dating of glacial deposits during the Last Glacial in the Terskey-Alatoo Range, Kyrgyz Republic

Optically stimulated luminescence (OSL) dating was applied to glacial and loess deposits in the north flank of the Terskey-Alatoo Range, Kyrgyz Republic, to elucidate the glacier chronology of the central Asian mountains during the Last Glacial. Moraines in five parts of study area were classified into four stages (Terskey Stages I–IV) based on their geographical position and elevation, and their moraine rock weathering. According to this classification, the oldest moraines (Terskey Stage I) were at 2100–2250 m a.s.l. and the second-oldest moraines (Terskey Stage II) were at 2400–2700 m a.s.l. Quartz samples from moraines of these two stages were used for OSL dating. The OSL ages of the quartz samples indicate that glacier expansion in the Terskey Stage II occurred between 21 and 29 ka BP.     

Petrographic and mineralogical study of hydrothermal alteration of the Rokko Granite at Hakusui-kyo and Horai-kyo along the Arima-Takatsuki Tectonic Line in western Japan

Field, hand specimen, and microscopic investigations alongside X-ray diffraction analyses revealed four types of hydrothermal alteration (Type-A, -B, -C, and -D) based on the mode of occurrence of altered rocks and alteration mineral assemblage at Hakusui-kyo and Horai-kyo along the Arima-Takatsuki Tectonic Line (ATTL) in western Japan. Type-A alteration locally occurred as gray alteration halos with sulfide minerals. Type-B and -C alterations were confined to fault gouge veins and occurred as greenish-gray veins and brown veins, respectively. Type-C alteration crosscut Type-B alteration. These alterations were associated with a number of granitic fragments including cohesive breccia and micrographic facies. Type-D alteration occurred locally in brown sediments. Different mineralogical features in the four alterations are summarized as (Type-A) illite; (Type-B) chlorite; (Type-C) limonite (Fe³⁺ hydroxides and goethite) and calcite; and (Type-D) limonite. We propose that the alterations can be broadly divided into Paleocene hydrothermal alteration (Type-A) and post-Late Miocene hydrothermal alteration (Type-B, -C, and -D): Type-A alteration occurred at approximately 200 °C during hydrothermal activity after a granitic intrusion in Late Cretaceous; Type-B, -C and -D alterations occurred under hydrothermal activity accompanying deep fluids with repeated ascents invoked by the seismicity of the ATTL after the Late Miocene. The fluids may have been the “Arima-type thermal waters” (i.e., mixtures of convective groundwater and Na-Ca-Cl-HCO₃-type fluids). Type-B alteration occurred in fractures at depths where the temperature was ≥150 °C. Type-C alteration overprinted Type-B alteration as a result of mixing of new deep fluids and descending oxidized meteoric water near the surface. Fe³⁺ hydroxides and calcite precipitated from the fluids due to the oxidation of Fe²⁺ and the degassing of CO₂, respectively, at ambient to near-boiling temperatures. When the ascending fluids gushed out from the fractures, they generated Type-D alteration at the surface under similar temperature conditions due to the oxidation of Fe²⁺.     

Crystallization of cosmic dust from highly supersaturated silicate vapor in a rapidly cooled environment

Growth conditions and the resultant morphology of cosmic forsterite and enstatite particles condensed from the vapor were investigated experimentally as a function of growth temperature and supersaturation using flash-heating by CO₂ laser irradiation. Forsterite particles grew dominantly, followed by a few pyroxenes. No silica minerals were observed. The forsterite morphology changed systematically depending on the temperature (T) and the vapor supersaturation (σ). As the temperature decreased and the vapor supersaturation increased, the forsterite morphology changed from a bulky type (T=1000-1450 °C, σ<97) to a platy type (T=700-1000 °C, σ=97-161), then to a columnar needle shape (T=500-820 °C, σ=131-230), and finally to a droplet type (T<500 °C, σ>230). Very thin polygonal growth steps, which suggest vapor-solid (VS) growth, were detected on the surface of the faceted bulky and platy forsterite particles. Transmission electron microscopic (TEM) observation showed that the tip of the columnar and needle-shaped forsterite was covered with an amorphous layer. This amorphous coverage illustrates that a liquid phase can be condensed from the vapor, even under the stable conditions where crystalline forsterite is stable. This amorphous layer plays a role in the vapor-liquid-solid (VLS) mechanism of the forsterite particles. The difference in the growth mechanism as a function of vapor supersaturation and temperature can be explained by metastable liquid condensation. The experimentally synthesized coexisting patterns of VS-grown and VLS-grown olivine particles resemble the pattern of matrix olivine or chondrule rims in primitive meteorites. Forsterite can crystallize more easily than either pyroxene or silica minerals, which is consistent with the dominance of forsterite in cometary dust particles, as suggested by its infrared spectrum.     

An empirical analysis of the impact of a bus rapid transit system on the concentration of secondary pollutants in the roadside areas of the TransJakarta corridors

A bus rapid transit (BRT) system began operation in Jakarta City, Indonesia, in January 2004 and led to a modal shift from private to public modes of transport. This modal shift from car and motorcycle to BRT reduced the emission intensity of primary pollutants, such as NO_x and CO. We applied a combined structural equation model and an artificial neural network to evaluate the impact of the BRT system on the concentration of secondary pollutants in the roadside areas in the BRT corridors. An empirical analysis was carried out using data collected at five continuous ambient air quality monitoring stations located near to the BRT TransJakarta corridors in 2005. The establishment of our structural equation model gives a better understanding of the cause–effect relationship among the factors influencing roadside ambient air pollution, and was useful in simplifying the complexity of our artificial neural network model for predicting the modal shift’s impact on the PM₁₀ values and concentration of O₃. The introduction of the BRT system, and the modal shift it produced, had a greater influence on rapidly decaying pollutants, such as PM₁₀, than on O₃ because of the exposure to near-source microenvironments, such as the roadside of the TransJakarta corridors.     

OSL and 14C chronologies of a Holocene sedimentary record (Garding‐2 core) from the German North Sea coast

The history of sea‐level change and sediment accumulation since the last deglaciation along the German North Sea coast is still controversial because of a limitation in the quantity and quality of chronological data. In the current study, the chronology of a 16‐ka coastal sedimentary record from the Garding‐2 core, retrieved from the Eiderstedt Peninsula in Schleswig‐Holstein, northern Germany, was established using OSL and AMS ¹⁴C dating techniques. The robust chronology using 14 radiocarbon and 25 OSL dates from the Garding‐2 core is the first long‐term record that covers the Holocene as well as the last deglaciation period in one succession in the German North Sea area. It provides a new insight into understanding the Holocene transgression and coastal accumulation histories. The combined evidence from the sedimentology and chronology investigations indicates that an estuarine environment dominated in Eiderstedt Peninsula from 16 to 13 ka, followed by a depositional hiatus between 13 and 8.3 ka, attributed to erosion caused by the Holocene transgression; the onset of the Holocene transgression at the core site occurred at around 8.3 ka. The sea level continued to rise with a decelerated rate until around 3 ka. Since 3 ka, the shoreline has begun to prograde. Foreshore (tidal flat) sediments have been deposited at the drilling site with a very high sedimentation rate of about 10 m ka^?1. At around 2 ka, a sandy beach deposit accumulated in the sedimentary succession, indicating that the coastline shifted landward, which may represent a small‐scale transgression in the late Holocene. At around 1.5 ka, terrestrial clastic sediment started to accumulate, indicating a retreat of the relative sea level in this area, which may be related to local diking activities undertaken since the 11th century.     

Rare-earth elements in matrix,inclusions, and chondrules of the Allende meteorite

Rare-earth elements in a whole-rock sample and in major components of the Allende meteorite were investigated; for a few samples, abundances of Ba, Sr, Ca, and Al were also determined. Of the materials investigated in the present work, CaAl-rich inclusions G and O seem to be of the greatest significance. In spite of the minor difference in mineralogy between them, the apparent chondrite-normalized RE pattern is much different between these two inclusions. (Yb and Eu in inclusion G appear exceptionally irregular). This observation is inferred to reflect a rather subtle difference in condition of condensation. It is also worthwhile to note that, while two portions (pink and white) of the inclusion G show similar aspects in the abundances of lithophile trace elements investigated, they show a remarkable difference at the same time. The white portion (G_w) of inclusion G can be considered to be a mixture of chondritic material and highly fractionated material like the faintly pink portion (G_p) picked from the same inclusion. This would suggest the possibility that the G_p-like material was produced from chondritic dust.The “matrix” separated from Allende was found to be fractionated with respect to the RE abundances relative to representative chondrite. It has also a very high value for the Ba abundance.     

The chronostratigraphy of the latest Middle Pleistocene aeolian and alluvial activity on the Island of Hvar,eastern Adriatic,Croatia

Pleistocene aeolian sands and alluvial deposits can frequently be traced along the Mediterranean coast. Such deposits also exist along the eastern Adriatic coast and the nearby islands. Four stratigraphical sections of these deposits were studied on the Island of Hvar with the purpose of establishing a chronological framework of the aeolian–alluvial depositional system, using luminescence dating and magnetic susceptibility stratigraphy. Luminescence dating was applied on coarse‐grained feldspar and quartz grains separated from the sands. Both quartz optically stimulated luminescence (OSL) and feldspar post‐IR infrared stimulated luminescence (pIRIR) age estimates are in good agreement, with values ranging between 167±24 to 120±12 ka (OSL) and 179±18 to 131±18 ka (pIRIR measured at 290 °C) after a fading correction for the pIRIR signal. The results can be clearly correlated to around the end of oxygen isotope stage (OIS) 6 and the beginning of OSI 5, indicating that the aeolian accumulation of sands was a result of the Penultimate Glacial and climate fluctuations at the beginning of the Last Interglacial. Variations in magnetic susceptibility (MS) data can be interpreted alongside these dating results; several stronger peaks detected at the very end of the Penultimate Glacial and the initial stage of the Last Interglacial cycle most probably indicates more intensive pedogenesis resulting from a more favourable climate, probably because of climate changes. Breccias related to major bounding surfaces in association with evidence of soil formation and bioturbation could be the result of more favourable climate conditions and changes during the transition from OIS 6 to OIS 5 (Penultimate Glacial–Last Interglacial). These results are in agreement with similar data from the wider Mediterranean area.     

Chondrites with peculiar rare-earth patterns

Rare-earth elements and Ba in Khohar, Abee, Indarch, Atlanta, Jajh deh Kot Lalu, and Nakhla were determined accurately by isotope dilution technique; for Atlanta only, Fe (total), Mg and Ca were also determined. Khohar shows in two aliquants a strikingly large, positive anomaly for Ce. A fragment of Abee is outstanding in having a large positive Yb anomaly and a zigzag RE pattern. It is considered that the Yb anomaly is not necessarily associated with the zigzaggedness in question. Anyway, these facts corroborate our previous observations that abundances of Ce and/or Yb could be sometimes anomalous in meteoritic and lunar materials.Atlanta also has a significant negative Eu anomaly, similar to the Eu depletions observed in lunar basalts and Ca-poor achondrites by other workers. Besides, this enstatite chondrite has a RE pattern which indicates that this meteorite is cumulate-type (solid-type) material separated perhaps from a considerably fractionated melt. Accordingly, it is suggested that it is not always appropriate to classify this type II enstatite chondrite as “chondrite”. Two fragments from Abee and Atlanta show different RE patterns. It is also observed that Ba abundances are sometimes sporadically and irregularly high.