Molecular and isotopic characteristics of gas hydrate-bound hydrocarbons in southern and central Lake Baikal

We investigated the molecular composition (methane, ethane, and propane) and stable isotope composition (methane and ethane) of hydrate-bound gas in sediments of Lake Baikal. Hydrate-bearing sediment cores were retrieved from eight gas seep sites, located in the southern and central Baikal basins. Empirical classification of the methane stable isotopes (δ¹³C and δD) for all the seep sites indicated the dominant microbial origin of methane via methyl-type fermentation; however, a mixture of thermogenic and microbial gases resulted in relatively high methane δ¹³C signatures at two sites where ethane δ¹³C indicated a typical thermogenic origin. At one of the sites in the southern Baikal basin, we found gas hydrates of enclathrated microbial ethane in which ¹³C and deuterium were both highly depleted (mean δ¹³C and δD of –61.6‰ V-PDB and –285.4‰ V-SMOW, respectively). To the best of our knowledge, this is the first report of C₂ δ¹³C–δD classification for hydrate-bound gas in either freshwater or marine environments.     

Field survey of the East Java earthquake and tsunami of June 3, 1994

A field survey of the June 3, 1994 East Java earthquake tsunami was conducted within three weeks, and the distributions of the seismic intensities, tsunami heights, and human and house damages were surveyed. The seismic intensities on the south coasts of Java and Bali Islands were small for an earthquake with magnitudeM 7.6. The earthquake caused no land damage. About 40 minutes after the main shock, a huge tsunami attacked the coasts, several villages in East Java Province were damaged severely, and 223 persons perished. At Pancer Village about 70 percent of the houses were swept away and 121 persons were killed by the tsunami. The relationship between tsunami heights and distances from the source shows that the Hatori's tsunami magnitude wasm=3, which seems to be larger for the earthquake magnitude. But we should not consider this an extraordinary event because it was pointed out byHatori (1994) that the magnitudes of tsunamis in the Indonesia-Philippine region generally exceed 1–2 grade larger than those of other regions.     

Quaternary vertical offset and average slip rate of the Nojima Fault on Awaji Island, Japan

Abstract Drilling was carried out to penetrate the Nojima Fault where the surface rupture occurred associated with the 1995 Hyogo-ken Nanbu earthquake. Two 500 m boreholes were successfully drilled through the fault zone at a depth of 389.4 m. The drilling data show that the relative uplift of the south-east side of the Nojima Fault (south-west segment) was approximately 230 m. The Nojima branch fault, which branches from the Nojima Fault, is inferred to extend to the Asano Fault. From the structural contour map of basal unconformity of the Kobe Group, the vertical component of displacement of the Nojima branch–Asano Fault is estimated to be 260–310 m. Because the vertical component of displacement on the Nojima Fault of the north-east segment is a total of those of the Nojima Fault of the south-west segment and of the Nojima branch–Asano Fault, it is estimated to total to 490–540 m. From this, the average vertical component of the slip rate on the Nojima Fault is estimated to be 0.4–0.45 m/10³ years for the past 1.2 million years.     

Fast Oxidation Reaction of Nitrite by Dissolved Oxygen in the Freezing Process in the Tropospheric Aqueous Phase

Nitrite oxidation in the tropospheric aqueous phase by freezing was evaluated by freezing a field sample. Nitrite oxidation by dissolved oxygen in the freezing process is much faster than by other oxidation processes, such as reactions with ozone, hydrogen peroxide or dissolved oxygen in an aqueous solution at pHs 3 to –6. At pH 4.5 and 25°C, the lifetime of nitrite in the aqueous phase is ca. 1 hr in oxidation by ozone (6×10^-10 mol dm^-3), ca. 10 hr in oxidation by H₂O₂ (2×10^-4 mol dm^-3), and 7.5 hr (Fischer and Warneck, 1996) in photodissociation at midday in summer. Under the same conditions at a temperature below 0°C, the lifetime of nitrite in the freezing process is estimated as ca. 2 sec when the droplets are frozen within a second. The reaction by freezing is affected by the presence of salts, such as NaCl or KCl, or orgnaic compounds, such as methanol or acetone. The results of freezing a field rain or fog sample showed that nitrite oxidation proceeds below pH 6, and the conversion ratio of nitrate from nitrite increases with decreasing pH. The oxidation of nitrite by freezing was also observed in freezing fog particles generated by an ultrasonic humidifier. The ratios of the concentrations of ions in the winter sample to those in the summer sample (or those in the fog sample) were almost the same values. However, the concentration of nitrite in the winter sample was lower than that estimated by the ratios of other ions. From the present study, it seems that the freezing process plays an important role in the nitrite sink process in the tropospheric aqueous phase.     

Amino acid precursors in lunar fines: limits to the contribution of jet exhaust

A sample of lunar fines collected at a maximum distance, 6.5 km, from the descent engine on Apollo 17 has been analyzed for total amino acids obtainable by hydrolysis of aqueous extracts. The minimum amounts of amino acids, calculated for a disc of 6 km radius are 10⁴–10⁵ times those which could be contributed by the lunar module jet exhaust, on the basis of conservatively limiting assumptions. The amino acids thus obtained are not explainable as due to chemical or biological contamination; their source is accordingly inferred as lunar. Under the conditions of hydrolysis of lunar extracts, cyanide is found to be converted, almost exclusively to glycine, to an extent of 10^?4.     

Microbial responses using denaturing gradient gel electrophoresis to oil and chemical dispersant in enclosed ecosystems

Microbial responses to the addition of oil with or without a chemical dispersant were examined in mesocosm and microcosm experiments by using denaturing gradient gel electrophoresis of bacterial ribosomal DNA and direct cell counting. When a water-soluble fraction of oil was added to seawater, increases in cell density were observed in the first 24h, followed by a decrease in abundance and a change in bacterial species composition. After addition of an oil-dispersant mixture, increases in cell density and changes in community structure coincided, and the amount of bacteria remained high. These phenomena also occurred in response to addition of only dispersant. Our results suggest that the chemical dispersant may be used as a nutrient source by some bacterial groups and may directly or indirectly prevent the growth of other bacterial groups.     

Slab-fluid metasomatism in the Early Paleozoic forearc mantle deduced from the Motai serpentinites,South Kitakami Belt,northeast Japan

The present study examines the petrology and geochemistry of the Early Paleozoic Motai serpentinites, the South Kitakami Belt, northeast Japan, to reveal the subduction processes and tectonics in the convergent margin of the Early Paleozoic proto-East Asian continent. Protoliths of the serpentinites are estimated to be harzburgite to dunite based on the observed amounts of bastite (orthopyroxene pseudomorph). Relic chromian spinel Cr# [=Cr/(Cr + Al)] increases with decreasing amount of bastite. The compositional range of chromian spinel is similar to that found in the Mariana forearc serpentinites. This fact suggests that the protoliths of the serpentinites are depleted mantle peridotites developed beneath the forearc regions of a subduction zone. The Motai serpentinites are divided into two types, namely, Types 1 and 2 serpentinites; the former are characterized by fine-grained antigorite and lack of olivine, and the latter have coarse-grained antigorite and inclusion-rich olivine. Ca-amphibole occurs as isolated crystals or vein-like aggregates in the Type 1 serpentinites and as needle-shaped minerals in the Type 2 serpentinites. Ca-amphibole of the Type 1 serpentinites is more enriched in LILEs and LREEs, suggesting the influence of hydrous fluids derived from slabs. By contrast, the mineral assemblage, mineral chemistry, and field distribution of the Type 2 serpentinites reflect the thermal effect of contact metamorphism by Cretaceous granite. The Ca-amphibole of the Type 1 serpentinites is different from that of the Hayachine–Miyamori Ophiolite in terms of origin; the latter was formed by the infiltration of melts produced in an Early Paleozoic arc–backarc system. Chemical characteristics of the Ca-amphibole in the ultramafic rocks in the South Kitakami Belt reflect the tectonics of an Early Paleozoic mantle wedge, and the formation of the Motai metamorphic rocks in the forearc region of the Hayachine–Miyamori subduction zone system, which occurred at the Early Paleozoic proto-East Asian continental margin.     

The δ13C–δ18O variations in marble in the Hida Belt,Japan

Marble has a great potential to understand a history of various geological events occurring during tectonic processes. In order to decode metamorphic–metasomatic records on C–O isotope compositions of marble at mid-crustal conditions, we conducted a C–O–Sr isotope study on upper amphibolite-facies marbles and a carbonate–silicate rock from the Hida Belt, which was once a part of the crustal basement of the East Asian continental margin. Carbon and oxygen isotope analyses of calcite from marbles (Kamioka area) and a carbonate–silicate rock (Wadagawa area) show a large variation of δ¹³C [VPDB] and δ¹⁸O [VSMOW] values (from −4.4 to +4.2 ‰ and +1.6 to +20.8 ‰, respectively). The low δ¹³C values of calcites from the carbonate–silicate rock (from −4.4 to −2.9 ‰) can be explained by decarbonation (CO₂ releasing) reactions; carbon–oxygen isotope modeling suggests that a decrease of δ¹³C strongly depends on the amount of silicate reacting with carbonates. The occurrence of metamorphic clinopyroxene in marbles indicates that all samples have been affected by decarbonation reactions. All δ¹⁸O values of calcites are remarkably lower than the marine-carbonate values. The large δ¹⁸O variation can be explained by the isotope exchange via interactions between marble, external fluids, and/or silicates. Remarkably low δ¹⁸O values of marbles that are lower than mantle value (~+5 ‰) suggest the interaction with meteoric water at a later stage. Sr isotope ratios (⁸⁷Sr/⁸⁶Sr = 0.707255–0.708220) might be close to their protolith values. One zircon associated with wollastonite in a marble thin-section yields a U–Pb age of 222 ± 3 Ma, which represents the timing of the recrystallization of marble, triggered by H₂O-rich fluid infiltration at a relatively high-temperature condition. Our isotope study implies that the upper amphibolite-facies condition, like the Hida Belt, might be appropriate to cause decarbonation reactions which can modify original isotope compositions of marble if carbonates react with silicates.     

A comparison of neighbourhood relations based on ordinary Delaunay diagrams and area Delaunay diagrams: an application to define the neighbourhood relations of buildings

ABSTRACT

The aim of this article is to describe a convenient but robust method for defining neighbourhood relations among buildings based on ordinary Delaunay diagrams (ODDs) and area Delaunay diagrams (ADDs). ODDs and ADDs are defined as a set of edges connecting the generators of adjacent ordinary Voronoi cells (points representing centroids of building polygons) and a set of edges connecting two centroids of building polygons, which are the generators of adjacent area Voronoi cells, respectively. Although ADDs are more robust than ODDs, computation time of ODDs is shorter than that of ADDs (the order of their computation time complexity is O(nlogn)). If ODDs can approximate ADDs with a certain degree of accuracy, the former can be used as an alternative. Therefore, we computed the ratio of the number of ADD edges to that of ODD edges overlapping ADDs at building and regional scales. The results indicate that: (1) for approximately 60% of all buildings, ODDs can exactly overlap ADDs with extra ODD edges; (2) at a regional scale, ODDs can overlap approximately 90% of ADDs with 10% extra ODD edges; and (3) focusing on judging errors, although ADDs are more accurate than ODDs, the difference is only approximately 1%.     

Short term variability of Particle fluxes and its relation to variability in sea surface temperature and chlorophylla field detected by Ocean Color and Temperature Scanner (OCTS) off Sanriku, northwestern North Pacific in the spring of 1997

A sediment trap experiment was carried out in conjunction with an over flight of Ocean Color Temperature Scanner (OCTS) on board Advanced Earth Observing Satellite (ADEOS) at 40°N, 143°E off Sanriku in April to May 1997. Short term variability of particle fluxes was examined at depths of 450 m and 600 m from April 6 to May 1 with a sampling interval of two days, and at 450 m with one day interval from 2nd to 10th May. Daily averaged mass flux at 450 m and 600 m was 815 mg m⁻²d⁻¹ and 862 mg m⁻²d⁻¹, respectively. A sharp increase in mass flux was observed during the period from April 26 to April 29 with the highest mass flux of 8 g m⁻²d⁻¹. About 85% of the total mass flux for the entire duration (26 days) was collected within these 4 days. Trapped material during the peak flux period was mainly composed of diatoms dominated byThalassiosira spp. and resting spores ofChaetoceros spp. This suggested that the peak flux was the result of (a) diatom bloom(s) in the euphotic column. Current meter records at 420 m showed that on April 26 and 27, the period when the peak flux was observed, the southwestward current had diminished in strength and changed its direction northwestward. Low current speeds appeared to have enhanced trap efficiency to help form the peak flux. A time series of OCTS Intensive-LAC (Local Area Coverage: Region B) images from mid-March to early May was examined todetect phytoplankton bloom(s). In the March 26th Chl image, high concentration region was restricted to the southwest off Cape Erimo, but spread around the warm core ring (WCR) 93A by April 10. East of the WCR93A, high Chl concentration remained steady until May, but to the west of the WCR93A, Chl decreased rapidly before the 19th of April. From this observation we suspect that the peak flux observed at the end of April originated from a bloom, which ceased on the 17th or 18th of April, in the region north of 40°N and west of 143°E. Taking the current meter records into account, the source region for the trapped material is most likely around southwest of the Cape Erimo.