Influence of Degree of Saturation in the Electric Resistivity–Hydraulic Conductivity Relationship

The relationship between aquifer hydraulic conductivity and aquifer resistivity, either measured on the ground surface by vertical electrical sounding (VES) or from resistivity logs, or measured in core samples have been published for different types of aquifers in different locations. Generally, these relationships are empirical and semi-empirical, and confined in few locations. This relation has a positive correlation in some studies and negative in others. So far, there is no potentially physical law controlling this relation, which is not completely understood. Electric current follows the path of least resistance, as does water. Within and around pores, the model of conduction of electricity is ionic and thus the resistivity of the medium is controlled more by porosity and water conductivity than by the resistivity of the rock matrix. Thus, at the pore level, the electrical path is similar to the hydraulic path and the resistivity should reflect hydraulic conductivity. We tried in this paper to study the effect of degree of groundwater saturation in the relation between hydraulic conductivity and bulk resistivity via a simple numerical analysis of Archie’s second law and a simplified Kozeny-Carmen equation. The study reached three characteristic non-linear relations between hydraulic conductivity and resistivity depending on the degree of saturation. These relations are: (1) An inverse power relation in fully saturated aquifers and when porosity equals water saturation, (2) An inverse polynomial relation in unsaturated aquifers, when water saturation is higher than 50%, higher than porosity, and (3) A direct polynomial relation in poorly saturated aquifers, when water saturation is lower than 50%, lower than porosity. These results are supported by some field scale relationships.     

Reconstruction of the layer anisotropic elastic parameters and high-resolution fracture characterization from P-wave data: a case study using seismic inversion and Bayesian rock physics parameter estimation

Wide-azimuth seismic data can be used to derive anisotropic parameters on the subsurface by observing variation in subsurface seismic response along different azimuths. Layer-based high-resolution estimates of components of the subsurface anisotropic elastic tensor can be reconstructed by using wide-azimuth P-wave data by combining the kinematic information derived from anisotropic velocity analysis with dynamic information obtained from amplitude versus angle and azimuth analysis of wide-azimuth seismic data. Interval P-impedance, S-impedance and anisotropic parameters associated with anisotropic fracture media are being reconstructed using linearized analysis assuming horizontal transverse anisotropy symmetry. In this paper it is shown how additional assumptions, such as the rock model, can be used to reduce the degrees of freedom in the estimation problem and recover all five anisotropic parameters. Because the use of a rock model is needed, the derived elastic parameters are consistent with the rock model and are used to infer fractured rock properties using stochastic rock physics inversion. The inversion is based on stochastic rock physics modelling and maximum a posteriori estimate of both porosity and crack density parameters associated with the observed elastic parameters derived from both velocity and amplitude versus angle and azimuth analysis. While the focus of this study is on the use of P-wave reflection data, we also show how additional information such as shear wave splitting and/or anisotropic well log data can reduce the assumptions needed to derive elastic parameter and rock properties.     

Climate impacts of environmental degradation in Sudan

There exists an impressive amount of work for Sudan showing the anthropogenic degradation of natural vegetation cover. However, there are few examples of consequent climatic changes in literature. This work, thus, seeks to assess such effects of environmental forcing on various climatic patterns over the past few decades. Within the frame of the present analysis, the results are quite striking and are in concordance with scientific contentions that such land degradation could result in climatic modification. Higher temperature and less rainfall, sunshine duration and global radiation have been noticed. Evapotranspiration has responded more to the warming and drying conditions, thus showed signs of increasing rates, especially during the wet season. However, the extent of increase seems to have been suppressed by the decrease in sunshine duration and solar radiation as well as the inconsistent behaviour of wind speed. Changes in the variability of the within-year monthly observations have also occurred, thus suggesting an increase in the occurrence of extremes. The observed climatic modification in the country has exaggerated the insidious drought conditions. The present findings are hoped to contribute to our understanding of the effects of environmental problem and assist in considering policy responses. This revised version was published online in July 2006 with corrections to the Cover Date.     

The ISO-SWS detectors: Performance trends and space radiation effects

We present a trend analysis of the ISO-SWS detector performance and a study of the space radiation effects on the SWS detectors. In particular, dark currents, dark current noise and detector responses have been checked as a function of time through the mission and as a function of time in arevolution. The results show that these parameters were stable during the mission in all bandsbut for band 3 (Si:As). Dark currents and responses were found to be higherin the first hours following the start of the science window,especially in band 2 (Si:Ga). We have studied the impacts of cosmic rays and radiation belt particles on the SWS detectors, as well as of the only large solar proton event on November 6, 1997,that occurred during the ISO mission (operated during solar minimum).The observed glitch rates in all SWS bands are found to be between 2 and4 times higher than the value predicted by the CREME96 model for the cosmic ray flux in the period considered. The bands that registered the highest glitch rates showed also a correlation with the electron fluxes measured on theGOES 9 spacecraft. From the distribution of glitchheights (voltage jumps in the detector signal), we have derived the deposited energy distributions of the particles hits. Our results lead to the conclusion that secondaryparticles produced in the shield and the detectors contributed at least as much as cosmic rays to the observed glitch rate. The effects on the detectors of the November 6, 1997 event, which caused that all observationsin a revolution were declared failed, are described in detail.     

Geology and Genesis of Barite Deposits of Lasbela and Khuzdar Districts, Balochistan, Pakistan

Abstract: Geology and genesis of the sediment-hosted barite deposits in the Lasbela and Khuzdar districts of Balochistan, Pakistan have been studied and described. Hot solutions generated in rifting environments during the initial stage of separation of the continental crustal block related to the Gondwanaland fragmentation subsequently reposed in Jurassic rocks, most probably played an important role on barite formation.
Paragenetic relationships indicate that the period of barite mineralization was distinctly later than that of zinc-lead sulphide mineralization in the Lasbela and Khuzdar districts. The barite deposits occur on top and in peripheral to the zinc-lead sulphides. The earliest barite mineralization took place in the clastic rock sequence of the lower Spingwar Formation as cross cutting veins. Younger mineralization as stratabound-replacement type occurred within the platform limestones of Loralai Formation, just above the Spingwar Formation. The youngest mineralization as stratiform is hosted within black shales, mudstones and argillaceous limestones of Anjira Formation at the top of Loralai Formation. In the light of the evidences gathered from field and laboratory investigations a genetic model has been deduced.     

Unexpectedly high-PGE chromitite from the deeper mantle section of the northern Oman ophiolite and its tectonic implications

Unusually high, platinum-group element (PGE) enrichments are reported for the first time in a podiform chromitite of the northern Oman ophiolite. The chromitite contains Б.5 ppm of total PGE, being highly enriched in the IPGE subgroup (Ir, Os and Ru) and strongly depleted in the PPGE subgroup (Rh, Pt and Pd). Its platinum-group minerals (PGMs) are classified into three types arranged in order of abundance: (1) sulphides (Os-rich laurite, laurite-erlishmanite solid solution and an unnamed Ir sulphide), (2) alloys (Os-Ir alloy and Ir-Rh alloy), and (3) sulpharsenides (irarsite and hollingworthite). The high PGE concentrations are observed only in a discordant chromitite deep in the mantle section, which has high-Cr# (>0.7) spinel with an olivine matrix. All the other types of chromitite (in the Moho transition zone (MTZ) and concordant pods in the deeper mantle section) are poor in PGEs and tend to have spinels with lower Cr# (up to 0.6). This diversity of chromitite types suggests two stages of magmatic activity were responsible for the chromitite genesis, in response to a switch of tectonic setting. The first is residual from lower degree, partial melting of peridotite, which produced low-Cr#, PGE-poor chromitites at the Moho transition zone and, to a lesser extent, within the mantle, possibly beneath a fast-spreading mid-ocean ridge. The second chromitite-forming event involves higher degree partial melting, which produced high-Cr#, PGE-rich discordant chromitite in the upper mantle, possibly in a supra-subduction zone setting.     

Late Proterozoic older granitoids from the North Eastern desert of Egypt: petrogenesis and geodynamic implications

Major, trace, and REE data for three localities of calc?Calkaline older granitoid rocks exposed in the north Eastern Desert of Egypt are presented. These rocks were selected to cover wide compositional spectrum of the Egyptian older granitoid varieties. They are petrographically represented by granodiorite, tonalite, quartz?Cdiorite, and quartz?Cmonzodiorite. The rocks are comparable with the peraluminous, unfractionated calc?Calkaline suites and fall within the volcanic arc and I-type granite fields. So, they can be regarded as belonging to the volcanic arc collision stage (665?C614?Ma). The granitoids are geochemically similar to other rocks recorded from continental margin arc-systems being exhibit light-REE enriched patterns with variable but chiefly positive Eu anomaly. The latter has reverse relationship with the ??REE, which was attributed to the fractionation of hornblende during partial melting. These patterns are comparable with models involving partial melting of amphibolitic source. This source must represent basalts, gabbros, or volcanics of an island arc system that were transformed to the level of the island arc crust during continental growth where the P?CT conditions are suitable for partial melting. Thus, it is plausible that the studied rocks were derived by partial melting of LREE-enriched, garnet-free, and amphibole-bearing (i.e., hydrated) mafic source. Wadi Milaha granitoids are consistent with the derivation by a high degree of partial melting (30?C40%) of amphibolite protolith in the deep crust. However, the two other localities (Wadi Umm Anab and West Gharib) are matching with 20?C30% partial melting. Within each locality, variation in rock types from granodiorite to tonalite is said to be dominated by variable degree of restite separation during magma ascent. The high water and volatile contents in Wadi Milaha granitoids allowed higher degree of partial melting (30?C40%). Moreover, the lower volatile contents in the other two localities (Wadi Umm Anab and West Gharib) gave lower degrees of partial melting (20?C30%). These processes may resemble important geodynamic features of the Arabo-Nubian Shield evolution in the north Eastern Desert of Egypt.     

Investigation of seasonal droughts and related large-scale atmospheric dynamics over the Potwar Plateau of Pakistan

As a result of climate change and unsustainable land use management in the recent past, droughts have become one of the most devastating climatic hazards whose impacts may prolong from months to years. This study presents analysis of droughts for two major cropping seasons, i.e., Kharif (May–September) and Rabi (October–April), over the Potwar Plateau of Pakistan. The analysis is performed using various datasets viz. observational, reanalysis, and Regional Climate Models (RCMs), for the past (1981–2010) and future (2011–2100) time periods. The following two methods for the identification of dry and wet years, also referred to as drought and wetness, are applied: (1) the percentile rank approach and (2) the drought indices, Standardized Precipitation Index (SPI) and Reconnaissance Drought Index (RDI). Future projections of droughts are investigated using RCM (RegCM4.4 and RCA4) outputs from CORDEX South Asia domain under two Representative Concentration Pathway (RCP) scenarios, RCP4.5 and RCP8.5. Generally, the indices show non-significant decreasing trends of drought severity in the recent past for all cases; however, significant increasing trends are observed for annual (0.006) and Kharif (0.007) cases under RCP4.5 scenario. The analysis of large-scale atmospheric dynamics suggests the significant role of low-level geopotential height anomalies over Tibetan Plateau (northwest of Pakistan) during Kharif (Rabi) season in controlling drought occurrence by transporting moisture from the Bay of Bengal (Arabian Sea). Moreover, composites of vertically integrated moisture transport, moisture flux convergence/divergence, and precipitable water anomalies show their marked contribution in maintaining the drought/wetness conditions over the Potwar region.     

Geochemistry and mineralogy of shallow alluvial aquifers in Daudkandi upazila in the Meghna flood plain, Bangladesh

The shallow alluvial aquifers of the delta plains and flood plains of Bangladesh, comprises about 70% of total land area are mostly affected by elevated concentrations of arsenic (As) in groundwater exposing a population of more than 35 million to As toxicity. Geochemical studies of shallow alluvial aquifer in the Meghna flood plain show that the uppermost yellowish grey sediment is low in As (1.03 mg/kg) compared to the lower dark grey to black sediment (5.24 mg/kg) rich in mica and organic matter. Sequential extraction data show that solid phase As bound to poorly crystalline and amorphous metal (Fe, Mn, Al)-oxyhydroxides is dominant in the grey to dark grey sediment and reaches its maximum level (3.05 mg/kg) in the mica rich layers. Amount of As bound to sulphides and organic matter also peaks in the dark grey to black sediment. Vertical distributions of major elements determined by X-ray fluorescence (XRF) show that iron (Fe₂O₃), aluminum (Al₂O₃) and manganese (MnO) follow the general trend of distribution of As in the sediments. Concentrations of As, Mn, Fe, HCO₃ ⁻, SO₄ ²⁻ and NO₃ ⁻ in groundwater reflect the redox status of the aquifer and are consistent with solid phase geochemistry. Mineralogical analysis by X-ray diffraction (XRD) and scanning electron microscopy (SEM) fitted with energy dispersive X-ray spectrometer (EDS) revealed dominance of crystalline iron oxides and hydroxides like magnetite, hematite and goethite in the oxidised yellowish grey sediment. Amorphous Fe-oxyhydroxides identified as grain coating in the mica and organic matter rich sediment suggests weathering of biotite is playing a critical role as the source of Fe(III)-oxyhydroxides which in turn act as sink for As. Presence of authigenic pyrite in the dark grey sediment indicates active reduction in the aquifer.