Effects of natural and calcined poultry waste on Cd, Pb and As mobility in contaminated soil

The reuse of waste materials as soil additives could be a welcome development in soil remediation. The mobility of Cd, Pb and As in a contaminated soil was investigated using natural and calcined poultry wastes (eggshell and chicken bone), CaCO₃ and CaO at different application rates (0, 1, 3 and 5 %). The chemical composition accompanied with mineralogical composition indicated that CaCO₃ and CaO were the major components in natural and calcined eggshells, respectively, while hydroxyapatite (HAP) dominated the natural and calcined chicken bones. The results showed that soil pH tended to increase in response to increasing application rates of all soil additives. The effectiveness of the additives in reducing Cd, Pb and As mobility was assessed by means of chemical extractions with 0.1 N HCl for Cd and Pb or 1 N HCl for As, according to Korean Standard Test (KST) method. Both calcined eggshell and chicken bone were equally effective with CaO or CaCO₃ in reducing the concentration of 0.1 N HCl-extractable Cd from 6.17 mg kg^?1 to below warning level of 1.5 mg kg^?1, especially at the highest application rate. The application of calcined eggshell, CaO and CaCO₃ also decreased the concentration of 0.1 N HCl-extractable Pb from 1,012 mg kg^?1 to below warning level of 100 mg kg^?1. The Pb concentration decreased significantly with an increasing application rate of chicken bone, but remained above warning level even at the highest application rate. On the contrary, natural and calcined chicken bones led to a significant increase in the mobility of As when compared with the control soil. These findings illustrate that calcined eggshell in particular is equally effective as pure chemical additives in stabilizing Cd and Pb in a contaminated agricultural soil. The presence of As in metal-contaminated soils should be taken into consideration when applying phosphate-containing materials as soil additives, because phosphate can compete with arsenate on adsorption sites and result in As mobilization.     

Temporal change of glaciers area and geomorphometric parameters in Parbati valley,Himachal Pradesh,India

Temporal change in the glacier coverage is analyzed for the period between 1962 and 2003 in Parbati valley, Himachal Pradesh. It is observed that the total glacier cover has been decreased by 17% ranging between 8 and 100% for individual glacier. The pattern of de-glaciation shows a high degree of shrinkage in outer zone of Parbati valley, while least shrinkage is observed in the inner valley. The present study is conducted to establish relationship between glacio-geomorphic parameters and glaciers shrinkage pattern to predict the future glacier cover in warming scenario. A systematic change is observed for glacio-geomorphic parameters associated with temporal change in glacier cover. It is observed that mean and minimum elevation, slope, relief and duration of insolation have changed substantially. Maximum elevation, plan/profile curvatures and aspect have shown less change from 1962 to 2003. A correlation matrix between glacio-geomorphic parameters for glaciers between 1962 and 2003 shows that the recent glaciers are much more controlled by terrain characteristics than that in the recent past.     

Flood risk perception and its determinants among rural households in two communities in Khyber Pakhtunkhwa,Pakistan

Natural Hazards - Risk perception plays a vital part in flood risk management and mitigation strategies. Therefore, this study aims at first to measure the risk perception of the vulnerable...     

Fluxes of Sr into the headwaters of the Ganges

Himalayan weathering is recognized as an important agent in modifying sea water chemistry, but there are significant uncertainties in our understanding of Himalayan riverine fluxes. This paper examines causes of the variability, including that of the seasons, by analysis of downstream variations in Sr, ⁸⁷Sr, and major ions in the mainstream, in relation to the composition of tributary streams from subcatchments with differing geologic substrates.Water samples were collected over four periods spanning the premonsoon, monsoon, and postmonsoon seasons. Uncertainties in the relative fluxes have been estimated, using Monte Carlo techniques, from the short-term variability of mainstream chemistry and the scatter of tributary compositions. The results show marked seasonal variations in the relative inputs related to high monsoon rainfall in the High and Lesser Himalaya, contrasting with the major contribution from glacial melt waters from the Tibetan Sedimentary Series (TSS) at times of low rainfall. Much of the spread in previously published estimates of the sources of Sr in Himalayan rivers may result from these seasonal variations in Sr fluxes.The annual fluxes of Sr into the headwaters of the Ganges are derived from the three main tectonic units in the proportions 35 ± 1% from the TSS, 27 ± 3% from the High Himalayan Crystalline Series (HHCS), and 38 ± 8% from the Lesser Himalaya. The particularly elevated ⁸⁷Sr/⁸⁶Sr ratios characteristic of the HHCS and the Lesser Himalaya enhance their influence on seawater Sr-isotope composition. The TSS contributes 13 ± 1%, the HHCS 30 ± 3%, and the Lesser Himalaya 57 ± 11% of the ⁸⁷Sr flux in excess of the seawater ⁸⁷Sr/⁸⁶Sr ratio of 0.709.     

Artificial groundwater recharge to a semi-arid basin: case study of Mujib aquifer,Jordan

Mujib watershed is an important groundwater basin which is considered a major source for drinking and irrigation water in Jordan. Increased dependence on groundwater needs improved aquifer management with respect to understanding deeply recharge and discharge issues, planning rates withdrawal, and facing water quality problems arising from industrial and agricultural contamination. The efficient management of this source depends on reliable estimates of the recharge to groundwater and is needed in order to protect Mujib basin from depletion. Artificial groundwater recharge was investigated in this study as one of the important options to face water scarcity and to improve groundwater storage in the aquifer. A groundwater model based on the MODFLOW program, calibrated under both steady- and unsteady-state conditions, was used to investigate different groundwater management scenarios that aim at protecting the Mujib basin. The scenarios include variations of abstraction levels combined with different artificial groundwater recharge quantities. The possibilities of artificial groundwater recharge from existing and proposed dams as well as reclaimed municipal wastewater were investigated. Artificial recharge options considered in this study are mainly through injecting water directly to the aquifer and through infiltration from reservoir. Three scenarios were performed to predict the aquifer system response under different artificial recharge options (low, moderate, and high) which then compared with no action (recharge) scenario. The best scenario that provides a good recovery for the groundwater table and that can be feasible is founded to be by reducing current abstraction rates by 20% and implementing the moderate artificial recharge rates of 26 million(M)m³/year. The model constructed in this study helps decision makers and planners in selecting optimum management schemes suitable for such arid and semi-arid regions.     

Anomalous optical variations in the grossular garnet from the Eden Mills,Belvidere Mountain (Vermont,USA)

The optical anomalies, and surface and lamellar textures of a birefringent grossular garnet crystal from the Eden Mills, Belvidere Mountain, Vermont, USA, have been investigated by optical polarizing microscope, electron-probe micro-analyzer, back-scattered electron imaging, infrared spectroscopy, and single-crystal X-ray diffractometer from the standpoint of crystal growth. This grossular shows one-to-one correlation between natural surface features and its internal textures under crossed polarizers. Electron-probe micro-analyzer (EPMA) gave average chemical composition in (110) thin section, of bright lamella {Ca_2.97Mn_0.06}_∑3.03 [Al_1.59Fe_0.37Ti_0.01]_∑1.97(Si_3.00)_∑3.00 (Gros_79.5And_18.9Sps_1.6) and of dark host {Ca_2.99Mn _0.06}_∑3.05 [Al_1.73Fe_0.26 Ti_0.01]_∑2.00(Si_2.97OH_0.03)_∑3.00 (Gros_85.4And₁₃Sps_1.6). The correspondence of surface features and the internal textures with spiral or pyramidal growth mechanism suggest that the internal textures of the Eden Mills grossular are formed during growth process. The optical vibrational orientations and the growth steps inclination along [001] and \( \left[\overset{-}{1}10\right] \) directions predict monoclinic symmetry. With X-ray diffractometer (XRD) method, pseudocubic parameters are a = 11.839(2) Å, b = 11.855(1) Å, and c = 11.868(2) Å with interaxial angles α = 90.00(1)°, β = 89.99(1)°, and γ = 90.02(2)° that show orthorhombic symmetry of this crystal. Lamellar texture of Al³⁺-rich host with Fe³⁺-rich lamella infers cation ordering at octahedral site of the garnet structure. IR data favors the non-cubic orientation of [(OH) ₄] at tetrahedral position in this grossular structure.     

The geoaccumulation index and enrichment factor of mercury in mangrove sediment of Port Klang, Selangor, Malaysia

Mangrove areas are important to the ecosystem. One of its crucial functions is as a sink of pollutants, especially metal ions. However, the accumulation of metals in mangrove sediment can generate negative impacts on plant growth, microbial activity, and soil fertility. Apart from that, the severity of the impact is highly influenced by the type of metal found in the sediment and the quality of sediment itself. One of the metals that have adverse effects on the environment is mercury. The objectives of this study are to determine the concentration and distribution of mercury and to assess the enrichment of mercury in Port Klang mangrove sediment by using geoaccumulation index and enrichment factor. Sediment samples were collected from 30 sampling points that cover Langat River and Klang River estuaries, Lumut Straits, Pulau Klang, and Pulau Indah. During sampling, water parameters such as pH, salinity, electrical conductivity, and total dissolved solids were measured in situ, whereas the total mercury in sediment samples was determined at the laboratory using inductively coupled plasma mass spectrometry. In this study, mercury was found to be concentrated along Lumut Strait especially in the mixing zone near the confluence of Langat River and at the jetty to Pulau Ketam. The geoaccumulation index and enrichment factor (calculated using logarithmized data of the reference element) found that three stations were enriched with mercury. In addition, geoaccumulation index was also observed to be more objective compared to enrichment factor whose results were influenced by the concentration of reference element used.     

Hydrogeochemical assessment of groundwater in Kashmir Valley,India

Groundwater samples (n = 163) were collected across Kashmir Valley in 2010 to assess the hydrogeochemistry of the groundwater in shallow and deep aquifers and its suitability for domestic, agriculture, horticulture, and livestock purposes. The groundwater is generally alkaline in nature. The electrical conductivity (EC) which is an index to represent the total concentration of soluble salts in water was used to measure the salinity hazard to crops as it reflects the TDS in groundwater ranging from 97 to 1385 μS/cm, except one well in Sopore. The average concentration of major ions was higher in shallow aquifers than in deeper aquifers. In general, Ca²⁺ is the dominant cation and HCO \(_{3}^{-}\) the dominant anion. Ca–HCO₃, Mg–HCO₃, Ca–Mg–HCO₃, Na–HCO₃ were the dominant hydrogeochemical facies. High concentration of HCO₃ and pH less than 8.8 clearly indicated that intense chemical weathering processes have taken place in the study area. The groundwater flow pattern in the area follows the local surface topography which not only modifies the hydrogeochemical facies but also controls their distribution. The groundwater in valley flows into four directions, i.e., SW–NE, NE–W, SE-NW and SE–NE directions. The results suggest that carbonate dissolution is the dominant source of major ions followed by silicate weathering and ion-exchange processes. The concentrations of all the major ions determined in the present study are within the permissible limits of WHO and BIS standards. The results of Total Hardness, SAR, Na%, Kelly Index, USDA classification, Magnesium absorption ratio, residual sodium carbonate, and PI suggested that groundwater is good for drinking, livestock, and irrigation purposes.     

Reliability Based Assessment of Shallow Foundations Using Mathcad

A reliability based method was used to design and analyse shallow foundations using first-order Taylor series approximation. The computer program Mathcad was used to facilitate all mathematical and computional efforts. This method is an effective tool to assist the foundation designers and analyists to investigate how reliable their designs or analyses are in relation to the ultimate bearing capacity of the foundations. The approach presented in this paper provides a reliable alternative for design and analysis of shallow foundations, rather than the conventional design methods, which employs the assumptions of a specified saftey factor. Several examples were presented for design and analysis of strip footings embedded in sandy soil, and rectangular and square footings analysis embedded in clayey soils. The program input and output of each example are also presented and discussed.