Middle Paleolithic occupation on a Marine Isotope Stage 5 lakeshore in the Nefud Desert,Saudi Arabia

Major hydrological variations associated with glacial and interglacial climates in North Africa and the Levant have been related to Middle Paleolithic occupations and dispersals, but suitable archaeological sites to explore such relationships are rare on the Arabian Peninsula. Here we report the discovery of Middle Paleolithic assemblages in the Nefud Desert of northern Arabia associated with stratified deposits dated to 75,000 years ago. The site is located in close proximity to a substantial relict lake and indicates that Middle Paleolithic hominins penetrated deeply into the Arabian Peninsula to inhabit landscapes vegetated by grasses and some trees. Our discovery supports the hypothesis of range expansion by Middle Paleolithic populations into Arabia during the final humid phase of Marine Isotope Stage 5, when environmental conditions were still favorable.     

Pattern and chronology of glacial Lake Peace shorelines and implications for isostacy and ice‐sheet configuration in northeastern British Columbia,Canada

Recognition of positions of glacial lakes along the margin of continental ice sheets is critical in reconstructing ice configuration during deglaciation. Advances in remote sensing technology (e.g. LiDAR) have enabled the generation of accurate digital‐elevation models (DEMs) that reveal unprecedented geomorphic detail. Combined with geographical information systems, these tools have considerably advanced the mapping and correlation of geomorphic features such as relict shorelines. Shorelines of glacial Lake Peace (GLP) developed between the Laurentide and Cordilleran ice sheets in northeastern British Columbia and northwestern Alberta. Shoreline mapping from high resolution DEMs produced more than 55 500 elevation data points from 3231 shorelines, enabling the identification of four major phases of GLP: Phase I (altitude 960–990 m a.s.l.); Phase II (890–915 m a.s.l.); Phase III (810–865 m a.s.l.); and Phase IV (724–733 m a.s.l.). The timing of Phase II of GLP is estimated by two optical ages of <16.0±2.5 and 14.2±0.5 ka BP. Extensive mapping of the shorelines allows for measuring of glacial isostatic adjustment as ice retreated. Shorelines currently dip to the northeast at around 0.4–0.5 m km^?1. This slope reflects the asynchronous retreat of the Cordilleran (CIS) and Laurentide (LIS) ice sheets. The relative uplift in the southwest of the study area within the Rocky Mountains and foothills suggests that the Late Wisconsinan (MIS 2) CIS persisted in the foothill after the LIS lost mass and retreated, or that the Late Wisconsinan CIS was very thick and caused deep crustal loading, which resulted in more uplift in the southwest before reaching equilibrium during, or shortly after deglaciation.     

Significance of post‐peak metamorphic reaction microstructures in the ultrahigh temperature Eastern Ghats Province,India

Ultrahigh temperature (UHT) granulites in the Eastern Ghats Province (EGP) have a complex P–T–t history. We review the P–T histories of UHT metamorphism in the EGP and use that as a framework for investigating the P–T–t history of Mg–Al‐rich granulites from Anakapalle, with the express purpose of trying to reconcile the down‐pressure‐dominated P–T path with other UHT localities in the EGP. Mafic granulite that is host to Mg–Al‐rich metasedimentary granulites at Anakapalle has a protolith age of c. 1,580 Ma. Mg–Al‐rich metasedimentary granulites within the mafic granulite at Anakapalle were metamorphosed at UHT conditions during tectonism at 960–875 Ma, meaning that the UHT metamorphism was not the result of contact metamorphism from emplacement of the host mafic rock. Reworking occurred during the Pan‐African (c. 600–500 Ma) event, and is interpreted to have produced hydrous assemblages that overprint the post‐peak high‐T retrograde assemblages. In contrast to rocks elsewhere in the EGP that developed post‐peak cordierite, the metasedimentary granulites at Anakapalle developed post‐peak, generation ‘2’ reaction products that are cordierite‐absent and nominally anhydrous. Therefore, rocks at Anakapalle offer the unique opportunity to quantify the pressure drop that occurred during so‐called M2 that affected the EGP. We argue that M2 is either a continuation of M1 and that the overall P–T path shape is a complex counter‐clockwise loop, or that M1 is an up‐temperature counter‐clockwise deviation superimposed on the M2 path. Therefore, rather than the rocks at Anakapalle having a metamorphic history that is apparently anomalous from the rest of the EGP, we interpret that other previously studied localities in the EGP record a different part of the same P–T path history as Anakapalle, but do not preserve a significant record of pressure decrease. This is due either to the inability of refractory rocks to extensively react to produce a rich mineralogical record of pressure decrease, or because the earlier high‐P part of the rocks history was erased by the M1 loop. Irrespective of the specific scenario, models for the tectonic evolution of the EGP must take the substantial pressure decrease during M2 into account, as it is probable the P–T record at Anakapalle is a reflection of tectonics affecting the entire province.     

Validation of MODIS Vegetation Continuous Fields for monitoring deforestation and forest degradation: two cases in Mexico

This study assesses whether MODIS Vegetation Continuous Fields percent tree cover (PTC) data can detect deforestation and forest degradation. To assess the usefulness of PTC for detecting deforestation, we used a data set consisting of eight forest and seven non-forest categories. To evaluate forest degradation, we used data from two temperate forest types in three conservation states: primary (dense), secondary (moderately degraded) and open (heavily degraded) forest. Our results show that PTC can differentiate temperate forest from non-forest categories (p = 0.05) and thus suggests PTC can adequately detect deforestation in temperate forests. In contrast, single-date PTC data does not appear to be adequate to detect forest degradation in temperate forests. As for tropical forest, PTC can partially discriminate between forest and non-forest categories.     

Evaluation of Strength Characteristics of Tropical Black Clay Treated with Locust Bean Waste Ash

An expansive tropical black clay (also known as black cotton soil because the cotton plant thrives well on it) was treated with up to 15 % locust bean waste ash (LBWA) to assess its soil improvement potential. Samples were subjected to index, compaction using three energy levels (British Standard light, BSL, West African Standard, WAS or ‘Intermediate’ and British Standard heavy, BSH), shear strength (unconfined compressive strength, UCS), California bearing ratio, CBR and durability tests. Results obtained show that the natural soil is not suitable for road construction. The maximum dry density (MDD) and optimum moisture content (OMC) decreased and increased, respectively. Regardless of the compactive effort and curing period, strength and durability properties increased with higher LBWA content with the BSL effort recording the best improvement. However, based on durability results, the optimal 12.5 % LBWA treatment of black cotton soil did not satisfy criteria for its use in road construction as a stand alone additive. Also, significant improvement in soil properties was obtained using the BSL compactive effort, which is easily achieved in the field. The benefits of the application include reduction in the cost of soil improvement and the adverse environmental impact of locust bean waste.     

Bioerosion and encrustation rates in recent mollusk death assemblages on a supratidal siliciclastic setting,Playa Norte,Veracruz State,Mexico

This study presents both qualitative and quantitative data regarding marine mollusk (gastropods and bivalves) shell bioerosion and encrustation based on death assemblages obtained from a recent supratidal environment in Playa Norte, Veracruz State. The objectives of this study were to assess the nature of bioerosion and encrustation processes and to investigate the role of these taphonomic features contributing to the deterioration of natural shell accumulations within a tropical siliciclastic tidal environment. The assemblage comprises 31 species: 13 gastropods and 18 bivalves. The bioerosion and encrustation degrees were low to moderate for both types. The most abundant traces were predatory gastropod structures (Oichnus paraboloides and O. simplex), whereas sponge borings (Entobia isp.), polychaete dwellings (Caulostrepsis taeniola), and echinoid raspings (Gnatichnus isp.) were less frequent. The encrusting organisms include polychaete serpulids, bryozoans, and rare foraminifers (Homotrema rubrum). Because of the low bioerosion and encrustation degrees occurring in this area, accumulation is expected to predominate over biotic destruction. As deposition conditions (richly fossiliferous carbonate sandstone beds) were similar to those prevailing in the Tuxpan Formation during the Miocene (Langhian), it is suggested that this study provides an equivalent reference to interpret mollusk fossil assemblages located in this site.     

Tellurium,selenium and cobalt enrichment in Neoproterozoic black shales,Gwna Group,UK: Deep marine trace element enrichment during the Second Great Oxygenation Event

Black shales of the late Neoproterozoic Gwna Group (570–580 Ma), UK, contain enrichments of tellurium (Te), selenium (Se) and cobalt (Co) relative to average shale compositions. The Te and Co enrichments bear comparison with those of ferromanganese crusts in the modern deep ocean. Gwna Group deposition coincides with the Second Great Oxidation Event, which had a significant effect on trace element fixation globally. Selenium and Te concentrations within these black shales indicate increased continental weathering rates, high biological productivity and corresponding increases in atmospheric O₂ concentrations. Cobalt, nickel (Ni) and arsenic (As) enrichments in this succession are secondary mineralisation phases. Demand for many of the trace elements found enriched in the Gwna Group black shales make their mechanisms of accumulation, and variations through the geological record, important to understand, and suggests that new resources may be sought based on black shale protoliths from this period.     

Evidence for centennial-scale Lateglacial and early Holocene climatic complexity from Quoyloo Meadow,Orkney, Scotland

The influence of the North Atlantic on the margins of Europe means the region is particularly sensitive to changes in the ocean–atmospheric system. During the Last Glacial–Interglacial Transition (16–8 cal ka bp ) this system was repeatedly disrupted, leading to a series of abrupt and short-lived shifts in climate. Despite much research, the number and magnitude of these ‘centennial-scale’ events is not well understood. To address this, we expand upon investigations at Quoyloo Meadow, Orkney, Scotland, one of the best chronologically constrained palaeoclimate records in northern Britain. By coupling stable isotope and chironomid fossil analyses with existing data, this study identifies multiple phases of centennial-scale disturbance at: c. 14.0, 11.1, 10.8, 10.5, 10.45 and 10.3 cal ka bp , with the events at 14.0 and 10.3 exhibiting a particularly pronounced cold-climate signature. During the Holocene, the strongest response to climate forcing was at c. 10.3–10.0 cal ka bp , expressed as a two-stage drop in mean July temperatures, a shift in pollen spectra indicative of ‘less-stable’ climatic regimes, and a depletion in δ¹⁸O values. We interpret this as the first reliably dated incidence of the ‘10.3-ka event’ in the British Isles and consider the wider impact of this climatic reversal in other Holocene records.     

Nanophase iron carbides in fine‐grained rims in CM2 carbonaceous chondrites: Formation of organic material by Fischer–Tropsch catalysis in the solar nebula

Transmission electron microscope studies of fine‐grained rims in three CM2 carbonaceous chondrites, Y‐791198, Murchison, and ALH 81002, have revealed the presence of widespread nanoparticles with a distinctive core–shell structure, invariably associated with carbonaceous material. These nanoparticles vary in size from ~20 nm up to 50 nm in diameter and consist of a core of Fe,Ni carbide surrounded by a continuous layer of polycrystalline magnetite. These magnetite shells are 5–7 nm in thickness irrespective of the diameter of the core Fe,Ni carbide grains. A narrow layer of amorphous carbon a few nanometers in thickness is present separating the carbide core from the magnetite shell in all the nanoparticles observed. The Fe,Ni carbide phases that constitute the core are consistent with both haxonite and cohenite, based on electron diffraction data, energy dispersive X‐ray analysis, and electron energy loss spectroscopy. Z‐contrast scanning transmission electron microscopy shows that these core–shell magnetite‐carbide nanoparticles can occur as individual isolated grains, but more commonly occur in clusters of multiple particles. In addition, energy‐filtered transmission electron microscopy (EFTEM) images show that in all cases, the nanoparticles are embedded within regions of carbonaceous material or are coated with carbonaceous material. The observed nanostructures of the carbides and their association with carbonaceous material can be interpreted as being indicative of Fischer–Tropsch‐type (FTT) reactions catalyzed by nanophase Fe,Ni metal grains that were carburized during the catalysis reaction. The most likely environment for these FTT reactions appears to be the solar nebula consistent with the high thermal stability of haxonite and cohenite, compared with other carbides and the evidence of localized catalytic graphitization of the carbonaceous material. However, the possibility that such reactions occurred within the CM parent body cannot be excluded, although this scenario seems unlikely, because the kinetics of the reaction would be extremely slow at the temperatures inferred for CM asteroidal parent bodies. In addition, carbides are unlikely to be stable under the oxidizing conditions of alteration experienced by CM chondrites. Instead, it is most probable that the magnetite rims on all the carbide particles are the product of parent body oxidation of Fe,Ni carbides, but this oxidation was incomplete, because of the buildup of an impermeable layer of amorphous carbon at the interface between the magnetite and the carbide phase that arrested the reaction before it went to completion. These observations suggest that although FTT catalysis reactions may not have been the major mechanism of organic material formation within the solar nebula, they nevertheless contributed to the inventory of complex insoluble organic matter that is present in carbonaceous chondrites.