Sub-micron scale distributions of trace elements in zircon

Sub-micron scale zoning of Ti concentrations and correlations between concentrations of Ti and other trace elements (P, Ce, and Y) and cathodoluminescent (CL) banding is observed in natural zircons. Ion images were made using the Caltech Microanalysis Center’s CAMECA NanoSIMS 50L with an O⁻ primary beam focused to ~300 nm on the sample surface. The high spatial resolution of this technique allows for interrogation of chemical variations at or below the scale of CL banding in natural zircons. Images produced in this manner display two types of correlations among Ti, P, Ce, and Y (which appears to be a proxy for CL intensity): strong (correlation coefficients >0.8) and subtle (correlation coefficients ~0.15–0.4). Strongly correlated images, which display Ti variations of ca. a factor of 3 between adjacent CL bands and overall elevated trace element concentrations in CL-dark bands, were found within an oscillatory-zoned, trace element enriched sector of a CL sector-zoned zircon. Three possible causes for such correlations include: temperature-dependent equilibrium partitioning, trace element partitioning limited by diffusion in the host melt and surface-controlled, non-equilibrium growth. Comparison of our data with the expected results of these processes suggests that: (1) Ti partitioning in zircon is dependent upon non-equilibrium effects in addition to temperature and/or (2) the incorporation of elements that co-vary with Ti in zircon (e.g., Y, P and Ce) is also temperature-dependent. Sub-micron scale, high-Ti regions are also found within Proterozoic Adirondack and >4 Ga Jack Hills zircons as well as trace element enrichments (including Ti) along cracks within Jack Hills zircons.     

Morphology of step-pools in a wilderness headwater stream: The importance of standardizing geomorphic measurements

The morphology of step-pools and cascades reflect the geological and climatic factors affecting channels in mountain watersheds. This study uses longitudinal and cross-section surveys to describe a headwater stream in the Boston Mountains of the Ozarks Plateau region in Arkansas and develop morphological relationships for comparisons with other regions. In the Bowers Hollow Creek watershed (3.5 km²), located within the boundaries of the Upper Buffalo Wilderness Area, step height and wavelength relationships are generally similar to those reported from other regions. Step-pool reaches were widely distributed in a discontinuous manner throughout the watershed. Average values of the sampled reaches are: reach slopes, 0.105 m/m; width, 6.10 m; crest particle sizes, 440 mm; step heights, 0.87 m; and step wavelengths, 6.62 m. The mean step steepness for the watershed was 0.13, whereas the mean length of a reach step to height ratio was 9:1. A comparison of morphological definitions found that the values of step height and steepness can vary by > 30% according to how step parameters are defined. Step height is particularly sensitive; thus, comparison of step height-based relationships from published data requires great care.     

Rivers turned to rock: Late Quaternary alluvial induration influencing the behaviour and morphology of an anabranching river in the Australian monsoon tropics

Late Quaternary alluvial induration has greatly influenced contemporary channel morphology on the anabranching Gilbert River in the monsoon tropics of the Gulf of Carpentaria. The Gilbert, one of a number of rivers in this region, has contributed to an extensive system of coalescing low-gradient and partly indurated riverine plains. Extensive channel sands were deposited by enhanced flow conditions during marine oxygen isotope (OI) Stage 5. Subsequent flow declined, probably associated with increased aridity, however, enhanced runoff recurred again in OI Stages 4–3 (65–50 ka). Aridity then capped these plains with 4–7 m of mud. A widespread network of sandy distributary channels was incised into this muddy surface from sometime after the Last Glacial Maximum (LGM) to the mid Holocene during a fluvial episode more active than the present but less so than those of OI Stages 5 and 3. This network is still partly active but with channel avulsion and abandonment now occurring largely proximal to the main Gilbert flow path.A tropical climate and reactive catchment lithology have enhanced chemical weathering and lithification of alluvium along the river resulting in the formation of small rapids, waterfalls and inset gorges, features characteristic more of bedrock than alluvial systems. Thermoluminescence (TL) and comparative optically stimulated luminescence (OSL) ages of the sediments are presented along with U/Th ages of pedogenic calcrete and Fe/Mn oxyhydroxide/ oxide accumulations. They show that calcrete precipitated during the Late Quaternary at times similar to those that favoured ferricrete formation, possibly because of an alternating wet–dry climate. Intense chemical alteration of the alluvium leading to induration appears to have prevailed for much of the Late Quaternary but, probably due to exceptional dryness, not during the LGM. The result has been restricted channel migration and a reduced capacity for the channel to adjust and accommodate sudden changes in bedload. Consequent avulsions have caused local stream powers to increase by an order of magnitude, inducing knickpoint erosion, local incision and the sudden influx of additional bedload that has triggered further avulsions. The Gilbert River, while less energetic than its Pleistocene ancestors, is clearly an avulsive system, and emphasizes the importance in some tropical rivers of alluvial induration for reinforcing the banks, generating nickpoints, reworking sediment and thereby developing and maintaining an indurated and anabranching river style.     

Emerging coral diseases: a temperature‐driven process?

In the last few decades there has been a surge in research focusing on coral disease. While climate change, specifically rising sea surface temperature, has been proposed as a major and growing driver of the emergence of marine diseases, to date a solid connection between disease epizootics and elevated sea surface temperature has not been established. However, a wealth of data now exists, compiled from many different perspectives, that may support such a connection. In this work we provide a comprehensive review targeting one coral disease, black band disease, that spans the infection process, pathobiology, and epizootiology, and links specific mechanisms of the disease process to increasing temperatures. This temperature‐driven pattern of infection can be expanded to include similar processes associated with other temperature‐related coral diseases. The conclusions presented here are based upon the results of many studies using a diverse suite of approaches that have been synthesized to argue that the emergence and continuing spread of black band disease is linked to warming sea surface temperatures. In summary, as global ocean temperatures increase seasonally and over decades, the environment shifts to become more favorable for the growth of potentially pathogenic microorganisms endemic to the immediate environment of the reef. The increase in the relative number of potential pathogens in the microbial community produces microenvironments conducive to the growth of other potential pathogens, leading to infection by a polymicrobial consortium. This consortium is easily perturbed by a (seasonal) temperature decrease, but remains associated with the coral host and can be reactivated with a subsequent seasonal increase in temperature, resulting in a cycle of temperature‐dependent disease emergence.     

Detection of rovibrationally excited H2 formed through the heterogeneous recombination of H atoms on a cold HOPG surface

This paper reports results from an experiment designed to measure the nascent rovibrational population of H₂ molecules that have formed through the heterogeneous recombination of H atoms on the surface of cosmic dust analogues under conditions approaching those of the interstellar medium (ISM). H₂ that has formed on a highly oriented pyrolytic graphite (HOPG) surface has been detected, using laser induced resonance-enhanced multi-photon ionization (REMPI), in the v = 1 (J= 0–3) rovibrational states at surface temperatures of 30 K and 50 K. These excited product molecules display rotational temperatures significantly higher than the target surface temperature. These first results suggest that a considerable proportion of the binding energy released on formation of the H₂ is deposited in the surface, in addition to internal excitation of the product molecules. This revised version was published online in July 2006 with corrections to the Cover Date.     

Evidence for MTBE in Heating Oil

"Contamination of heating oil with MTBE could result in increasing the environmental impact of subsurface heating oil releases."     

A sediment budget for a grazed semi-arid catchment in the Burdekin basin, Australia

In catchments adjacent to the Great Barrier Reef World Heritage Area in Queensland, Australia, there is a growing concern that sediments and nutrients being exported from the land are having a detrimental effect on coral reef communities. There is a need to determine the processes and rates of erosion from the major land use types, so that management intervention can be initiated to reduce sediment yields where required. This paper presents a sediment budget for Weany Creek, a 13.5 km² grazed semi-arid sub-catchment of the Burdekin River catchment, Australia. A range of field methods was used to measure erosion from hillslopes, gullies and stream banks, as well as identify the amount of sediment being deposited and remobilised on the bed of gullies and the stream network. The data suggests that at least during drought conditions, the primary erosion source in this catchment is gully erosion. However, the largest source of sediment in the budget is actually associated with the remobilisation of in-channel sediment stores. Overall, the sediment budget is comprised of  81% coarse material and 19% fine sediment and an agreement between the fine sediment yield estimated in the sediment budget and the yield measured at the catchment outlet is within 10%. The total sediment yield estimated for this catchment is  4205 t yr^− 1 and is much lower than expected for a catchment of this size. This may reflect the drought conditions during the measurement period; however, there is also the possibility that the primary erosion sources have been exhausted, and the rates of sediment loss may be much lower now than they may have been in the past. Nonetheless, the results show that stored sediment, which may have been deposited in the channel many decades ago, is an important contributor to end of catchment sediment yields and warrants further investigation.     

Shocked quartz in polymict impact breccia from the Upper Cretaceous Yallalie impact structure in Western Australia

Yallalie is a ~12 km diameter circular structure located ~200 km north of Perth, Australia. Previous studies have proposed that the buried structure is a complex impact crater based on geophysical data. Allochthonous breccia exposed near the structure has previously been interpreted as proximal impact ejecta; however, no diagnostic indicators of shock metamorphism have been found. Here we report multiple (27) shocked quartz grains containing planar fractures (PFs) and planar deformation features (PDFs) in the breccia. The PFs occur in up to five sets per grain, while the PDFs occur in up to four sets per grain. Universal stage measurements of all 27 shocked quartz grains confirms that the planar microstructures occur in known crystallographic orientations in quartz corresponding to shock compression from 5 to 20 GPa. Proximity to the buried structure (~4 km) and occurrence of shocked quartz indicates that the breccia represents either primary or reworked ejecta. Ejecta distribution simulated using iSALE hydrocode predicts the same distribution of shock levels at the site as those found in the breccia, which supports a primary ejecta interpretation, although local reworking cannot be excluded. The Yallalie impact event is stratigraphically constrained to have occurred in the interval from 89.8 to 83.6 Ma based on the occurrence of Coniacian clasts in the breccia and undisturbed overlying Santonian to Campanian sedimentary rocks. Yallalie is thus the first confirmed Upper Cretaceous impact structure in Australia.     

A search for amino acids and nucleobases in the Martian meteorite Roberts Massif 04262 using liquid chromatography‐mass spectrometry

The investigation into whether Mars contains signatures of past or present life is of great interest to science and society. Amino acids and nucleobases are compounds that are essential for all known life on Earth and are excellent target molecules in the search for potential Martian biomarkers or prebiotic chemistry. Martian meteorites represent the only samples from Mars that can be studied directly in the laboratory on Earth. Here, we analyzed the amino acid and nucleobase content of the shergottite Roberts Massif (RBT) 04262 using liquid chromatography‐mass spectrometry. We did not detect any nucleobases above our detection limit in formic acid extracts; however, we did measure a suite of protein and nonprotein amino acids in hot‐water extracts with high relative abundances of β‐alanine and γ‐amino‐n‐butyric acid. The presence of only low (to absent) levels of several proteinogenic amino acids and a lack of nucleobases suggest that this meteorite fragment is fairly uncontaminated with respect to these common biological compounds. The distribution of straight‐chained amine‐terminal n‐ω‐amino acids in RBT 04262 resembled those previously measured in thermally altered carbonaceous meteorites (Burton et al. 2012; Chan et al. 2012). A carbon isotope ratio of ?24‰ ± 6‰ for β‐alanine in RBT 04262 is in the range of reduced organic carbon previously measured in Martian meteorites (Steele et al. 2012). The presence of n‐ω‐amino acids may be due to a high temperature Fischer‐Tropsch‐type synthesis during igneous processing on Mars or impact ejection of the meteorites from Mars, but more experimental data are needed to support these hypotheses.